4 research outputs found
Glassy magnetic phase driven by short range charge and magnetic ordering in nanocrystalline LaSrFeO: Magnetization, Mossbauer, and polarised neutron studies
The charge ordered LaSrFeO (LSFO) in bulk and
nanocrystalline forms are investigated using ac and dc magnetization,
M\"{o}ssbauer, and polarised neutron studies. A complex scenario of short range
charge and magnetic ordering is realized from the polarised neutron studies in
nanocrystalline specimen. This short range ordering does not involve any change
in spin state and modification in the charge disproportion between Fe
and Fe compared to bulk counterpart as evident in the M\"{o}ssbauer
results. The refinement of magnetic diffraction peaks provides magnetic moments
of Fe and Fe are about 3.15 and 1.57 for bulk, and
2.7 and 0.53 for nanocrystalline specimen, respectively. The
destabilization of charge ordering leads to magnetic phase separation, giving
rise to the robust exchange bias (EB) effect. Strikingly, EB field at 5 K
attains a value as high as 4.4 kOe for average size 70 nm, which is zero
for the bulk counterpart. A strong frequency dependence of ac susceptibility
reveals cluster-glass like transition around 65 K, below which EB
appears. Overall results propose that finite size effect directs the complex
glassy magnetic behavior driven by unconventional short range charge and
magnetic ordering, and magnetic phase separation appears in nanocrystalline
LSFO.Comment: 10 pages, 9 figures. Fig. 1 available upon request or in
http://www.ffn.ub.es/oscar/Articles.html. Accepted in Phys. Rev.
Exchange bias effect in alloys and compounds
The phenomenology of exchange bias effects observed in structurally
single-phase alloys and compounds but composed of a variety of coexisting
magnetic phases such as ferromagnetic, antiferromagnetic, ferrimagnetic,
spin-glass, cluster-glass and disordered magnetic states are reviewed. The
investigations on exchange bias effects are discussed in diverse types of
alloys and compounds where qualitative and quantitative aspects of magnetism
are focused based on macroscopic experimental tools such as magnetization and
magnetoresistance measurements. Here, we focus on improvement of fundamental
issues of the exchange bias effects rather than on their technological
importance
Size effect on magnetic phase coexistence in Pr<sub>0.5</sub>Sr<sub>0.5</sub>Mn<sub>1-x</sub>Cr<sub>x</sub>O<sub>3</sub>
Magnetic and transport properties are investigated in Pr<sub>0.5</sub>Sr<sub>0.5</sub>Mn<sub>1-x</sub>Cr<sub>x</sub>O<sub>3</sub> (0 ⩽ x ⩽ 0.05) focusing on the effect of Cr substitution and particle size dependence. The studies demonstrate that magnetic and transport properties are significantly different for nanocrystalline compound from the bulk. Neutron depolarization and diffraction studies confirm that different fractions of magnetic phase separation between antiferromagnetic and ferromagnetic components, and ferromagnetic domain size give rise to the different magnetic and transport properties. Intriguingly, nanocrystalline compound with x = 0.05 shows apparent signature of arrested state in magnetization and magnetoresistance both in thermal and magnetic field variations which is absent in the bulk counterpart. A spin-glass like state is identified for nano at low temperature, which is argued to be correlated with the arrested or pinning mechanism
Glassy magnetic phase driven by short range charge and magnetic ordering in nanocrystalline La1/3Sr2/3FeO3-δ: Magnetization, Mössbauer, and polarized neutron studies
The charge ordered La1/3Sr2/3FeO3−δ (LSFO) in bulk and nanocrystalline forms are investigated using ac and dc magnetization, M¨ossbauer, and polarized neutron studies. A complex scenario of short-range charge and magnetic ordering is realized from the polarized neutron studies in nanocrystalline specimen. This short-range ordering does not involve any change in spin state and modification in the charge disproportion between Fe3+ and Fe5+ compared to bulk counterpart as evident in the M¨ossbauer results. The refinement of magnetic diffraction peaks provides magnetic moments of Fe3+ and Fe5+ are about 3.15 μB and 1.57 μB for bulk, and 2.7 μB and 0.53 μB for nanocrystalline specimen, respectively. The destabilization of charge ordering leads to magnetic phase separation, giving rise to the robust exchange bias (EB) effect. Strikingly, EB field at 5 K attains a value as high as 4.4 kOe for average size ∼70 nm, which is zero for the bulk counterpart. A strong frequency dependence of ac susceptibility reveals cluster-glass-like transition around ∼65 K, below which EB appears. Overall results propose that finite-size effect directs the complex glassy magnetic behavior driven by unconventional short-range charge and magnetic ordering, and magnetic phase separation appears in nanocrystalline LSFO