New cloud chamber experiments on the heterogeneous ice nucleation ability of oxalic acid in the immersion mode

The heterogeneous ice nucleation ability of oxalic acid in the immersion mode has been investigated by controlled expansion cooling runs with airborne, ternary solution droplets composed of, (i), sodium chloride, oxalic acid, and water (NaCl/OA/H₂O) and, (ii), sulphuric acid, oxalic acid, and water (H₂SO₄/OA/H₂O). Polydisperse aerosol populations with median diameters ranging from 0.5–0.7 μm and varying solute concentrations were prepared. The expansion experiments were conducted in the AIDA aerosol and cloud chamber of the Karlsruhe Institute of Technology at initial temperatures of 244 and 235 K. In the ternary NaCl/OA/H₂O system, solid inclusions of oxalic acid, presumably nucleated as oxalic acid dihydrate, were formed by temporarily exposing the ternary solution droplets to a relative humidity below the efflorescence point of NaCl. The matrix of the crystallised NaCl particulates triggered the precipitation of the organic crystals which later remained as solid inclusions in the solution droplets when the relative humidity was subsequently raised above the deliquescence point of NaCl. The embedded oxalic acid crystals reduced the critical ice saturation ratio required for the homogeneous freezing of pure NaCl/H₂O solution droplets at a temperature of around 231 K from 1.38 to about 1.32. Aqueous solution droplets with OA inclusions larger than about 0.27 μm in diameter efficiently nucleated ice by condensation freezing when they were activated to micron-sized cloud droplets at 241 K, i.e., they froze well above the homogeneous freezing temperature of pure water droplets of about 237 K. Our results on the immersion freezing potential of oxalic acid corroborate the findings from a recent study with emulsified aqueous solutions containing crystalline oxalic acid. In those experiments, the crystallisation of oxalic acid diyhdrate was triggered by a preceding homogeneous freezing cycle with the emulsion samples. The expansion cooling cycles with ternary H₂SO₄/OA/H₂O solution droplets were aimed to analyse whether those findings can be transferred to ice nucleation experiments with airborne oxalic acid containing aerosol particles. Under our experimental conditions, the efficiency by which the surface of homogeneously nucleated ice crystals triggered the precipitation of oxalic acid dihydrate was very low, i.e., less than one out of a hundred ice crystals that were formed by homogeneous freezing in a first expansion cooling cycle left behind an ice-active organic crystal that acted as immersion freezing nucleus in a second expansion cooling cycle

Probing ice clouds by broadband mid-infrared extinction spectroscopy: case studies from ice nucleation experiments in the AIDA aerosol and cloud chamber

International audienceSeries of infrared extinction spectra of ice crystals were recorded in the 6000?800 cm-1 wavenumber regime during expansion cooling experiments in the large aerosol and cloud chamber AIDA of Forschungszentrum Karlsruhe. Either supercooled sulphuric acid solution droplets or dry mineral dust particles were added as seed aerosols to initiate ice formation after having established ice supersaturated conditions inside the chamber. The various ice nucleation runs were conducted at temperatures between 237 and 195 K, leading to median sizes of the nucleated ice particles of 1?15 µm. The measured infrared spectra were fitted with reference spectra from T-matrix calculations to retrieve the number concentration as well as the number size distribution of the generated ice clouds. The ice particles were modelled as finite circular cylinders with aspect ratios ranging from 0.5 to 3.0. Benefiting from the comprehensive diagnostic tools for the characterisation of ice clouds which are available at the AIDA facility, the infrared retrieval results with regard to the ice particle number concentration could be compared to independent measurements with various optical particle counters. This provided a unique chance to quantitatively assess potential errors or solution ambiguities in the retrieval procedure which mainly originate from the difficulty to find an appropriate shape representation for the aspherical particle habits of the ice crystals. Based on these inter-comparisons, we demonstrate that there is no standard retrieval approach which can be routinely applied to all different experimental scenarios. In particular, the concept to account for the asphericity of the ice crystals, the a priori constraints which might be imposed on the unknown number size distribution of the ice crystals (like employing an analytical distribution function), and the wavenumber range which is included in the fitting algorithm should be carefully adjusted to each single retrieval problem

Precision spectroscopy of the 3s-3p fine structure doublet in Mg+

We apply a recently demonstrated method for precision spectroscopy on strong transitions in trapped ions to measure both fine structure components of the 3s-3p transition in 24-Mg+ and 26-Mg+. We deduce absolute frequency reference data for transition frequencies, isotope shifts and fine structure splittings that are in particular useful for comparison with quasar absorption spectra, which test possible space-time variations of the fine structure constant. The measurement accuracy improves previous literature values, when existing, by more than two orders of magnitude

Precision Spectroscopy at Heavy Ion Ring Accelerator SIS300

Unique spectroscopic possibilities open up if a laser beam interacts with relativistic lithium-like ions stored in the heavy ion ring accelerator SIS300 at the future Facility for Antiproton and Ion Research FAIR in Darmstadt, Germany. At a relativistic factor gamma = 36 the 2P 1/2 level can be excited from the 2S 1/2 ground state for any element with frequency doubled dye-lasers in collinear geometry. Precise transition energy measurements can be performed if the fluorescence photons, boosted in forward direction into the X-ray region, are energetically analyzed with a single crystal monochromator. The hyperfine structure can be investigated at the 2P 1/2 - 2S 1/2 transition for all elements and at the 2P 3/2 - 2S 1/2 transition for elements with Z < 50. Isotope shifts and nuclear moments can be measured with unprecedented precision, in principle even for only a few stored radioactive species with known nuclear spin. A superior relative line width in the order of 5E-7 may be feasible after laser cooling, and even polarized external beams may be prepared by optical pumping

NEW FRICTION DURABLE ADDITIVE TECHNOLOGY AND ITS APPLICATION IN AUTOMATIC TRANSMISSIONS

Ovaj rad prikazuje razvoj tehnologije novih aditiva koja omogućuje formulaciju fluida za automatske prijenosnike (ATF-Automatic Transmission Fluids) na osnovi mineralnih ulja sa značajno poboljšanom otpornošću na trenje. U radu se uspoređuju performance trenja tehnologije novih aditiva kod komercijalno dostupnih ATF-a u Europi, Aziji i Sjevernoj Americi pri industrijski standardnim testovima trenja kao što su SAE No’2 rig (SAE No\u272 mjerna oprema) i Low Velocity Friction Apparatus (aparatura za ispitivanje trenja pri niskim brzinama). Isto tako, u radu se razmatraju primjeri još većih tehničkih izazova koje postavljaju posljednje ATF specifikacije u uvjetima još naglašenije oksidacije, trošenja, ekstremnih pritisaka, otpornosti na trenje, kapaciteta okretnog momenta i antikorozijskih zahtjeva, te se performance nove tehnologije aditiva otpornih na trenje uspoređuju s ostalim dostupnim ATF tehnologijama na nekim od spomenutih područja. Performance fluida otpornih na trenje koje su omogućene pomoću tehnologije novih aditiva mogu se primijeniti kod čitavog niza automatskih prijenosnika, npr. mokrih spojki za pokretanje, spojki pretvarača okretnog momenta, prijenosnika s dvostrukim spojkama i posljednje generacije automatskih prijenosnika sa šest, sedam, i osam stupnjeva prijenosa.This paper reports the development of a new additive technology allowing formulation of mineral oil based Automatic Transmission Fluids (ATFs) with significantly improved friction durability. The paper compares friction performance of the new additive technology with commercially available European, Asian and North American style ATFs in industry standard friction tests such as the SAE No’2 rig and the Low Velocity Friction Apparatus. The paper also considers examples of the broader technical challenges posed by the latest ATF specifications in terms of more stringent oxidation, wear, extreme pressure, friction durability, torque capacity and anti-corrosion requirements, and compares the performance of the new friction durable ATF technology with other commercially available ATFs in some of these areas. The fluid friction durability performance offered by this new additive technology is applicable in a variety of automatic transmission hardware, e.g. wet starting clutches, torque converter clutches, dual clutch transmissions and the latest generation six-, seven- and eight-speed step type automatic transmissions

Clinical Evaluation of a Line-Probe Assay for Tuberculosis Detection and Drug-Resistance Prediction in Namibia.

Treatment of tuberculosis requires rapid information about Mycobacterium tuberculosis (Mtb) drug susceptibility to ensure effective therapy and optimal outcomes. At the tuberculosis referral hospital in Windhoek, Namibia, a country of high tuberculosis incidence, we evaluated the diagnostic accuracy of a line-probe-assay (LPA), GenID, for the molecular diagnosis of Mtb infection and drug resistance in patients with suspected tuberculosis (cohort 1) and confirmed rifampin (RIF)-resistant tuberculosis (cohort 2). GenID test results were compared to Xpert MTB/RIF and/or Mtb culture and antimicrobial suceptibilty testing. GenID LPA was applied to 79 and 55 samples from patients in cohort 1 and cohort 2, respectively. The overall sensitivity of GenID LPA for the detection of Mtb DNA in sputum from patients with detectable and undetectable acid-fast bacilli by sputum smear microscopy was 93.3% (56/60; 95% confidence interval = 83.8-98.2) and 22.7% (5/22; 7.8-45.4). The sensitivity/specificity for the detection of drug resistance was 84.2% (32/38; 68.7-94.0)/100% (19/19; 82.4-100.0) for RIF, 89.7% (26/29; 72.6-97.8)/91.7% (22/24; 73.0-99.0) for isoniazid, and 85.7% (6/7; 42.1-99.6)/94.7% (18/19; 74.0-99.9) for fluoroquinolones; 23.6% of tests for second-line injectable resistance were invalid despite repeat testing. The diagnosis of tuberculosis by detection of Mtb DNA in sputum by GenID LPA depends strongly on the detection of acid-fast bacilli in sputum specimen. Prediction of drug resistance by GenID did not reach the World Health Organization (WHO) target product profile. IMPORTANCE Mycobacterium tuberculosis (Mtb) drug-resistance detection is crucial for successful control of tuberculosis. Line-probe assays (LPA) are frequently used to detect resistance to rifampin, isoniazid, fluoroquinolones (FQs), and second-line injectables (SLIs). GenID RIF/isoniazid (INH), FQ, and SLI LPA have not been widely tested and used so far. This study tested the diagnostic performance of the GenID LPA in a high-incidence TB/HIV, real-world setting in Namibia. The LPA demonstrates only an acceptable diagnostic performance for Mtb and drug-resistance detection. The diagnostic sensitivity and specificity fall short of the WHO suggested target product profiles for LPA

A comprehensive parameterization of heterogeneous ice nucleation of dust surrogate: laboratory study with hematite particles and its application to atmospheric models

A new heterogeneous ice nucleation parameterization that covers a wide temperature range (-36 to -78 °C) is presented. Developing and testing such an ice nucleation parameterization, which is constrained through identical experimental conditions, is important to accurately simulate the ice nucleation processes in cirrus clouds. The ice nucleation active surface-site density (ns) of hematite particles, used as a proxy for atmospheric dust particles, were derived from AIDA (Aerosol Interaction and Dynamics in the Atmosphere) cloud chamber measurements under water subsaturated conditions. These conditions were achieved by continuously changing the temperature (T) and relative humidity with respect to ice (RHice) in the chamber. Our measurements showed several different pathways to nucleate ice depending on T and RHice conditions. For instance, almost T-independent freezing was observed at -60 °C < T < -50 °C, where RHice explicitly controlled ice nucleation efficiency, while both T and RHice played roles in other two T regimes: -78 °C < T < -60 °C and -50 °C < T < -36 °C. More specifically, observations at T lower than -60 °C revealed that higher RHice was necessary to maintain a constant ns, whereas T may have played a significant role in ice nucleation at T higher than -50 °C. We implemented the new hematite-derived ns parameterization, which agrees well with previous AIDA measurements of desert dust, into two conceptual cloud models to investigate their sensitivity to the new parameterization in comparison to existing ice nucleation schemes for simulating cirrus cloud properties. Our results show that the new AIDA-based parameterization leads to an order of magnitude higher ice crystal concentrations and to an inhibition of homogeneous nucleation in lower-temperature regions. Our cloud simulation results suggest that atmospheric dust particles that form ice nuclei at lower temperatures, below -36 °C, can potentially have a stronger influence on cloud properties, such as cloud longevity and initiation, compared to previous parameterizations