1,968 research outputs found
Unification of bulk and interface electroresistive switching in oxide systems
We demonstrate that the physical mechanism behind electroresistive switching
in oxide Schottky systems is electroformation, as in insulating oxides.
Negative resistance shown by the hysteretic current-voltage curves proves that
impact ionization is at the origin of the switching. Analyses of the
capacitance-voltage and conductance-voltage curves through a simple model show
that an atomic rearrangement is involved in the process. Switching in these
systems is a bulk effect, not strictly confined at the interface but at the
charge space region.Comment: 4 pages, 3 figures, accepted in PR
Hole mobility in organic single crystals measured by a "flip-crystal" field-effect technique
We report on single crystal high mobility organic field-effect transistors
(OFETs) prepared on prefabricated substrates using a "flip-crystal" approach.
This method minimizes crystal handling and avoids direct processing of the
crystal that may degrade the FET electrical characteristics. A chemical
treatment process for the substrate ensures a reproducible device quality. With
limited purification of the starting materials, hole mobilities of 10.7, 1.3,
and 1.4 cm^2/Vs have been measured on rubrene, tetracene, and pentacene single
crystals, respectively. Four-terminal measurements allow for the extraction of
the "intrinsic" transistor channel resistance and the parasitic series contact
resistances. The technique employed in this study shows potential as a general
method for studying charge transport in field-accumulated carrier channels near
the surface of organic single crystals.Comment: 26 pages, 7 figure
Self-consistent model of unipolar transport in organic semiconductor diodes: accounting for a realistic density-of-states distribution
A self-consistent, mean-field model of charge-carrier injection and unipolar
transport in an organic semiconductor diode is developed utilizing the
effective transport energy concept and taking into account a realistic
density-of-states distribution as well as the presence of trap states in an
organic material. The consequences resulting from the model are discussed
exemplarily on the basis of an indium tin oxide/organic semiconductor/metallic
conductor structure. A comparison of the theory to experimental data of a
unipolar indium tin oxide/poly-3-hexyl-thiophene/Al device is presented.Comment: 6 pages, 2 figures; to be published in Journal of Applied Physic
Ga-induced atom wire formation and passivation of stepped Si(112)
We present an in-depth analysis of the atomic and electronic structure of the
quasi one-dimensional (1D) surface reconstruction of Ga on Si(112) based on
Scanning Tunneling Microscopy and Spectroscopy (STM and STS), Rutherford
Backscattering Spectrometry (RBS) and Density Functional Theory (DFT)
calculations. A new structural model of the Si(112)6 x 1-Ga surface is
inferred. It consists of Ga zig-zag chains that are intersected by
quasi-periodic vacancy lines or misfit dislocations. The experimentally
observed meandering of the vacancy lines is caused by the co-existence of
competing 6 x 1 and 5 x 1 unit cells and by the orientational disorder of
symmetry breaking Si-Ga dimers inside the vacancy lines. The Ga atoms are fully
coordinated, and the surface is chemically passivated. STS data reveal a
semiconducting surface and show excellent agreement with calculated Local
Density of States (LDOS) and STS curves. The energy gain obtained by fully
passivating the surface calls the idea of step-edge decoration as a viable
growth method toward 1D metallic structures into question.Comment: Submitted, 13 pages, accepted in Phys. Rev. B, notational change in
Fig.
Self consistent theory of unipolar charge-carrier injection in metal/insulator/metal systems
A consistent device model to describe current-voltage characteristics of
metal/insulator/metal systems is developed. In this model the insulator and the
metal electrodes are described within the same theoretical framework by using
density of states distributions. This approach leads to differential equations
for the electric field which have to be solved in a self consistent manner by
considering the continuity of the electric displacement and the electrochemical
potential in the complete system. The model is capable of describing the
current-voltage characteristics of the metal/insulator/metal system in forward
and reverse bias for arbitrary values of the metal/ insulator injection
barriers. In the case of high injection barriers, approximations are provided
offering a tool for comparison with experiments. Numerical calculations are
performed exemplary using a simplified model of an organic semiconductor.Comment: 21 pages, 8 figure
Thermionic charge transport in CMOS nano-transistors
We report on DC and microwave electrical transport measurements in
silicon-on-insulator CMOS nano-transistors at low and room temperature. At low
source-drain voltage, the DC current and RF response show signs of conductance
quantization. We attribute this to Coulomb blockade resulting from barriers
formed at the spacer-gate interfaces. We show that at high bias transport
occurs thermionically over the highest barrier: Transconductance traces
obtained from microwave scattering-parameter measurements at liquid helium and
room temperature is accurately fitted by a thermionic model. From the fits we
deduce the ratio of gate capacitance and quantum capacitance, as well as the
electron temperature
Polarity control of carrier injection at ferroelectric/metal interfaces for electrically switchable diode and photovoltaic effects
We investigated a switchable ferroelectric diode effect and its physical
mechanism in Pt/BiFeO3/SrRuO3 thin-film capacitors. Our results of electrical
measurements support that, near the Pt/BiFeO3 interface of as-grown samples, a
defective layer (possibly, an oxygen-vacancy-rich layer) becomes formed and
disturbs carrier injection. We therefore used an electrical training process to
obtain ferroelectric control of the diode polarity where, by changing the
polarization direction using an external bias, we could switch the transport
characteristics between forward and reverse diodes. Our system is characterized
with a rectangular polarization hysteresis loop, with which we confirmed that
the diode polarity switching occurred at the ferroelectric coercive voltage.
Moreover, we observed a simultaneous switching of the diode polarity and the
associated photovoltaic response dependent on the ferroelectric domain
configurations. Our detailed study suggests that the polarization charge can
affect the Schottky barrier at the ferroelectric/metal interfaces, resulting in
a modulation of the interfacial carrier injection. The amount of
polarization-modulated carrier injection can affect the transition voltage
value at which a space-charge-limited bulk current-voltage (J-V) behavior is
changed from Ohmic (i.e., J ~ V) to nonlinear (i.e., J ~ V^n with n \geq 2).
This combination of bulk conduction and polarization-modulated carrier
injection explains the detailed physical mechanism underlying the switchable
diode effect in ferroelectric capacitors.Comment: Accepted for publication in Phys. Rev.
Evidence of environmental strains on charge injection in silole based organic light emitting diodes
Using d. functional theory (DFT) computations, the authors demonstrated a
substantial skeletal relaxation when the structure of
2,5-bis-[4-anthracene-9-yl-phenyl]-1,1-dimethyl-3,4-diphenyl-silole (BAS) is
optimized in the gas-phase comparing with the mol. structure detd. from
monocrystal x-ray diffraction. The origin of such a relaxation is explained by
a strong environmental strains induced by the presence of anthracene entities.
Also, the estn. of the frontier orbital levels showed that this structural
relaxation affects mainly the LUMO that is lowered of 190 meV in the gas phase.
To check if these theor. findings would be confirmed for thin films of BAS, the
authors turned to UV photoemission spectroscopy and/or inverse photoemission
spectroscopy and electrooptical measurements. The study of the c.d. or voltage
and luminance or voltage characteristics of an ITO/PEDOT/BAS/Au device clearly
demonstrated a very unusual temp.-dependent behavior. Using a thermally
assisted tunnel transfer model, this behavior likely originated from the
variation of the electronic affinity of the silole deriv. with the temp. The
thermal agitation relaxes the mol. strains in thin films as it is shown when
passing from the cryst. to the gas phase. The relaxation of the intramol. thus
induces an increase of the electronic affinity and, as a consequence, the more
efficient electron injection in org. light-emitting diodes
Field-induced metal-insulator transition and switching phenomenon in correlated insulators
We study the nonequilibrium switching phenomenon associated with the
metal-insulator transition under electric field E in correlated insulator by a
gauge-covariant Keldysh formalism. Due to the feedback effect of the resistive
current I, this occurs as a first-order transition with a hysteresis of I-V
characteristics having a lower threshold electric field (\sim 10^4 Vcm^{-1})
much weaker than that for the Zener breakdown. It is also found that the
localized mid-gap states introduced by impurities and defects act as hot spots
across which the resonant tunneling occurs selectively, which leads to the
conductive filamentary paths and reduces the energy cost of the switching
function.Comment: 5 pages, 3 figures. A study on the metal-insulator transition in
correlated insulators was adde
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