Efficient electrocatalytic water oxidation at neutral and high pH by adventitious nickel at nanomolar concentrations

Electrolytic water oxidation using earth-abundant elements is a key challenge in the quest to develop cheap, large surface area arrays for solar-to-hydrogen conversion. There have been numerous studies in this area in recent years, but there remains an imperative to demonstrate that the current densities reported are indeed due to the species under consideration and not due to the presence of adventitious (yet possibly highly active) contaminants at low levels. Herein, we show that adventitious nickel at concentrations as low as 17 nM can act as a water oxidation catalyst in mildly basic aqueous solutions, achieving stable (tens of hours) current densities of 1 mA cm–2 at overpotentials as low as 540 mV at pH 9.2 and 400 mV at pH 13. This nickel was not added to the electrolysis baths deliberately, but it was found to be present in the electrolytes as an impurity by ICP-MS. The presence of nickel on anodes from extended-time bulk electrolysis experiments was confirmed by XPS. In showing that such low levels of nickel can perform water oxidation at overpotentials comparable to many recently reported water oxidation catalysts, this work serves to raise the burden of proof required of new materials in this field: contamination by adventitious metal ions at trace loadings must be excluded as a possible cause of any observed water oxidation activity

Russell Square: a lifelong resource for teaching and learning

A quarter of a century ago, in 1978, Birkbeck College’s Faculty of Continuing Education (FCE, then the Department for Extra-Mural Studies of the federal University) moved to the offices that it now occupies in numbers 26 and 25 Russell Square. Then, as now, FCE was the one of the largest and most active extra-mural departments of any British university, with an enormous range of courses covering virtually every subject taught in ‘internal’ university departments and many more besides 1. Some of these courses have, from time to time, used Russell Square as a learning resource. Many more staff and students alike have (along with thousands of local workers, tourists and residents) used the square’s gardens for relaxation and recovery, without reflecting on its origins or present significance. This Occasional Paper examines the past and present fabric of Russell Square (‘the Square’) as a resource for teaching and learning. It is a composite narrative assembled by FCE staff whose disciplines range from nature conservation through garden history and architectural history to social policy. It deconstructs the Square as an entity and attempts to decipher some of its ‘meanings’ that provide links between subjects taught within FCE. We hope that it will stimulate discussion about the way this single ‘place’ – our Square - can be ‘seen’ or interpreted in different ways for diverse purposes, and about the way that it can be used as a resource for teaching and learning across disciplines