Separation of n-hexane - ethyl acetate mixture by azeotropic batch distillation with heterogeneous entrainers

In this article, a systematic study of the separation of the n-hexane - ethyl acetate mixture with an entrainer by heterogeneous azeotropic batch distillation is performed. Based upon the thermodynamic behaviour of the ternary mixtures, potential entrainers partially miscible with one or two original azeotropic components are chosen. In all cases, the entrainer adds a heterogeneous binary or ternary azeotrope that is the lowest boiling point in the ternary diagram. Therefore, it leaves the column by the overhead stream which is subcooled to get two liquid phases in the decanter. The phase with the highest amount of the original component is removed as distillate product whereas the entrainer – rich phase is continuously refluxed to the column. Considering methanol, acetonitrile, water and nitromethane as heterogeneous entrainers, screening was performed based on the composition of the unstable heteroazeotropic mixture, the ratio of both liquid phases in the condensed top vapour and the purity of the distillate product determined by the liquid – liquid envelope at the decanter temperature. The process feasibility analysis is validated by using rigorous simulation with the batch process simulator ProSimBatch. Simulation results are then corroborated in a bench experimental column for the selected entrainer, showing several advantages of heterogeneous batch distillation compared to homogeneous systems

Boson-conserving one-nucleon transfer operator in the interacting boson model

The boson-conserving one-nucleon transfer operator in the interacting boson model (IBA) is reanalyzed. Extra terms are added to the usual form used for that operator. These new terms change generalized seniority by one unit, as the ones considered up to now. The results obtained using the new form for the transfer operator are compared with those obtained with the traditional form in a simple case involving the pseudo-spin Bose-Fermi symmetry $U^{B}(6) \otimes U^F(12)$ in its $U^{BF}(5) \otimes U^F(2)$ limit. Sizeable differences are found. These results are of relevance in the study of transfer reactions to check nuclear supersymmetry and in the description of (\beta)-decay within IBA.Comment: 13 pages, 1 table, 0 figures. To be published in Phys. Rev.

Cute Balloons with Thickness

Based on the fnite element method, we present a simple volume-preserved thin shell deformation algorithm to simulate the process of inflating a balloon. Diff erent from other thin shells, the material of balloons has special features: large stretch, small bend and shear, and incompressibility. Previous deformation methods often focus on typical three-dimensional models or thin plate models such as cloth model. The rest thin shell methods are complex or ignore the special features of thin shells especially balloons. We modify the triangle element to simple three-prism element, ignore bending and shearing deformation, and use volume preservation algorithm to match the incompressibility of balloons. Simple gas model is used, which interacts with shells to make the balloons inflated. Di different balloon examples have been tested in our experiments and the results are compared with those of other methods. The experiments show that our algorithm is simple and effective

Gamow-Teller Strength in the Region of 100^{100}Sn

New calculations are presented for Gamow-Teller beta decay of nuclei near $^{100}$Sn. Essentially all of the $^{100}$Sn Gamow-Teller decay strength is predicted to go to a single state at an excitation energy of 1.8 MeV in $^{100}$In. The first calculations are presented for the decays of neighboring odd-even and odd-odd nuclei which show, in contrast to $^{100}$Sn, surprisingly complex and broad Gamow-Teller strength distributions. The results are compared to existing experimental data and the resulting hindrance factors are discussed.Comment: 12 pages (latex) and 2 figures available on reques

Overconstrained estimates of neutrinoless double beta decay within the QRPA

Estimates of nuclear matrix elements for neutrinoless double beta decay (0nu2beta) based on the quasiparticle random phase approximations (QRPA) are affected by theoretical uncertainties, which can be substantially reduced by fixing the unknown strength parameter g_pp of the residual particle-particle interaction through one experimental constraint - most notably through the two-neutrino double beta decay (2nu2beta) lifetime. However, it has been noted that the g_pp adjustment via 2\nu2\beta data may bring QRPA models in disagreement with independent data on electron capture (EC) and single beta decay (beta^-) lifetimes. Actually, in two nuclei of interest for 0nu2beta decay (Mo-100 and Cd-116), for which all such data are available, we show that the disagreement vanishes, provided that the axial vector coupling g_A is treated as a free parameter, with allowance for g_A<1 (``strong quenching''). Three independent lifetime data (2nu2beta, EC, \beta^-) are then accurately reproduced by means of two free parameters (g_pp, g_A), resulting in an overconstrained parameter space. In addition, the sign of the 2nu2beta matrix element M^2nu is unambiguously selected (M^2nu>0) by the combination of all data. We discuss quantitatively, in each of the two nuclei, these phenomenological constraints and their consequences for QRPA estimates of the 0nu2beta matrix elements and of their uncertainties.Comment: Revised version (27 pages, including 10 figures), focussed on Mo-100 and Cd-116. To appear in J. Phys. G: Nucl. Phys. (2008

Neutrinoless Double Beta Decay in Gauge Theories

Neutrinoless double beta decay is a very important process both from the particle and nuclear physics point of view. Its observation will severely constrain the existing models and signal that the neutrinos are massive Majorana particles. From the elementary particle point of view it pops up in almost every model. In addition to the traditional mechanisms, like the neutrino mass, the admixture of right handed currents etc, it may occur due to the R-parity violating supersymmetric (SUSY) interactions. From the nuclear physics point of view it is challenging, because: 1) The relevant nuclei have complicated nuclear structure. 2) The energetically allowed transitions are exhaust a small part of all the strength. 3) One must cope with the short distance behavior of the transition operators, especially when the intermediate particles are heavy (eg in SUSY models). Thus novel effects, like the double beta decay of pions in flight between nucleons, have to be considered. 4) The intermediate momenta involved are about 100 MeV. Thus one has to take into account possible momentum dependent terms in the nucleon current. We find that, for the mass mechanism, such modifications of the nucleon current for light neutrinos reduce the nuclear matrix elements by about 25 per cent, almost regardless of the nuclear model. In the case of heavy neutrinos the effect is much larger and model dependent. Taking the above effects into account, the available nuclear matrix elements for the experimentally interesting nuclei A = 76, 82, 96, 100, 116, 128, 130, 136 and 150 and the experimental limits on the life times we have extracted new stringent limits on the average neutrino mass and on the R-parity violating coupling for various SUSY models.Comment: Latex, 24 pages, 1 postscript figure, uses iopconf.st