4,915 research outputs found
Theory of x-ray scattering from laser-driven electronic systems
We describe, within the framework of quantum electrodynamics, an interaction
between a non-resonant hard x-ray pulse and an electronic system in the
presence of a temporally periodic laser field driving electron dynamics in this
system. We apply Floquet theory to describe the laser-driven electronic system,
and then obtain the scattering probability of an arbitrary nonresonant x-ray
pulse from such a system employing the density-matrix formalism. We show that
the scattering probability can be connected to the time-dependent electron
density of the driven electronic system only under certain conditions, in
particular, if the bandwidth of the probe x-ray pulse is sufficiently narrow to
spectroscopically resolve transitions to different final states. A special
focus is laid on application of the theory to laser-driven crystals in a
strongly nonperturbative regime. We show how the time-dependent electron
density of a crystal can be reconstructed from energy-resolved scattering
patterns. This is illustrated by a calculation of a diffraction signal from a
driven MgO crystal.Comment: accepted to Phys Rev
To Wet or Not to Wet? Dispersion Forces Tip the Balance for Water Ice on Metals
Despite widespread discussion, the role of van der Waals dispersion forces in wetting remains unclear. Here we show that nonlocal correlations contribute substantially to the water-metal bond and that this is an important factor in governing the relative stabilities of wetting layers and 3D bulk ice. Because of the greater polarizability of the substrate metal atoms, nonlocal correlations between water and the metal exceed those between water molecules within ice. This sheds light on a long-standing problem, wherein common density functional theory exchange-correlation functionals incorrectly predict that none of the low temperature experimentally characterized icelike wetting layers are thermodynamically stable
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Proteostasis collapse is a driver of cell aging and death.
What molecular processes drive cell aging and death? Here, we model how proteostasis-i.e., the folding, chaperoning, and maintenance of protein function-collapses with age from slowed translation and cumulative oxidative damage. Irreparably damaged proteins accumulate with age, increasingly distracting the chaperones from folding the healthy proteins the cell needs. The tipping point to death occurs when replenishing good proteins no longer keeps up with depletion from misfolding, aggregation, and damage. The model agrees with experiments in the worm Caenorhabditis elegans that show the following: Life span shortens nonlinearly with increased temperature or added oxidant concentration, and life span increases in mutants having more chaperones or proteasomes. It predicts observed increases in cellular oxidative damage with age and provides a mechanism for the Gompertz-like rise in mortality observed in humans and other organisms. Overall, the model shows how the instability of proteins sets the rate at which damage accumulates with age and upends a cell's normal proteostasis balance
Absolute frequency measurement of the 7s S 7s7p P transition in Ra
Transition frequencies were determined for transitions in Ra in an atomic
beam and for reference lines in Te molecules in a vapor cell. The absolute
frequencies were calibrated against a GPS stabilized Rb-clock by means of an
optical frequency comb. The 7s^2\,^1S(F = 1/2)-7s7p\,^1P(F = 3/2)
transition in Ra was determined to be MHz. The
measurements provide input for designing efficient and robust laser cooling of
Ra atoms in preparation of a search for a permanent electric dipole moment in
Ra isotopes.Comment: Accepted for publication in the rapid communication of Physical
review
An integrated water balance model for assessing water scarcity in a data-sparse interfluve in Eastern India
The objective of this study is to measure the balance of water demand versus water resource availability in an interfluve of West Bengal, India to support water resource planning, particularly of inter-basin transfers. Surface water availability was modelled using the Soil Conservation Service Curve Number (SCS-CN) model, whilst groundwater availability was modelled based on water level fluctuations and the rainfall infiltration method. Water use was modelled separately for the agricultural, industrial, and domestic sectors using a predominantly normative approach and water use to availability ratios calculated for different administrative areas within the interfluve. Overall, the approach suggested that the interfluve receives 327×106m3year?1 of excess water after satisfying these sectoral demands, but that the eastern part of the study area is in deficit. However, a sensitivity analysis carried on the approach to several assumptions in the model suggested changed circumstances would produce surplus/deficit ranging from -215×106m3year?1 to 435 ×106m3year?1 . The approach could have potential for localised water balance modelling in other Indian catchment
On how good DFT exchange-correlation functionals are for H bonds in small water clusters: Benchmarks approaching the complete basis set limit
The ability of several density-functional theory (DFT) exchange-correlation
functionals to describe hydrogen bonds in small water clusters (dimer to
pentamer) in their global minimum energy structures is evaluated with reference
to second order Moeller Plesset perturbation theory (MP2). Errors from basis
set incompleteness have been minimized in both the MP2 reference data and the
DFT calculations, thus enabling a consistent systematic evaluation of the true
performance of the tested functionals. Among all the functionals considered,
the hybrid X3LYP and PBE0 functionals offer the best performance and among the
non-hybrid GGA functionals mPWLYP and PBE1W perform the best. The popular BLYP
and B3LYP functionals consistently underbind and PBE and PW91 display rather
variable performance with cluster size.Comment: 9 pages including 4 figures; related publications can be found at
http://www.fhi-berlin.mpg.de/th/th.htm
Stochastic Multifacility Location Problem under Triangular Area Constraint with Euclidean Norm
The multifacility location issue is an augmentation of the single-location problem in which we might be keen on finding the location of various new facilities concerning different existing locations. In the present study, multifacility location under triangular zone limitation with probabilistic methodology for the weights considered in the objective function and the Euclidean distances between the locations has been presented. Scientific detailing and the explanatory arrangement have been acquired by utilizing Kuhn-Tucker conditions. The arrangement strategy has been represented with the assistance of a numerical illustration. Two sub-instances of the issue in each of which the new locations are to be situated in semi-open rectangular zone have likewise been talked about
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