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Not AvailableLine formed from intricate network of gullies because of localized physical degradation due to surface runoff affecting the friable unconsolidated material in the formation of perceptible channels resulting in undulating terrain with fragile ecosystem. Over-exploitation of this vast tract of existing ravine lands coupled with improper management practices has led to deterioration of soil health and poses threat to adjoining productive agricultural lands. Under ravine landscapes, soil undergoes various changes due to accelerated erosional processes. With rapidly shrinking per capita availability of land, there is a growing need for restoration of these areas for productive land uses. Maintenance of soil organic carbon is one of the most important factors for aggregate stability, soil structural durability and nutrient availability in ravine areas. Deficiency of nutrients and poor water retention are two major causative factors of stagnation in crop productivity in ravine lands. In this chapter, an attempt has been made to consolidate various best nutrient management practices for soils under ravine region for increasing crop productivity and improving soil health. Also, there is a need to harness and manage the indigenous technical knowledge and fine-tune them to suit the modern needs. Overall, the twin aspect of devising strategies for leveraging resources to tackle the challenge of enhancing soil health and carbon sequestration will help in combating climate change without compromising economic development in ravine areas. The future R&D strategies for maintaining soil health, crop productivity and environmental sustainability in degraded ravine land have also been included.Not Availabl

New insights into pertinent Fe complexes for the synthesis of iron via the instant polyol process

Chemically synthesized iron is in demand for biomedical applications due to its large saturation magnetization compared to iron oxides. The polyol process, suitable for obtaining Co and Ni particles and their alloys, is laborious in synthesizing Fe. The reaction yields iron oxides, and the reaction pathway remains unexplored. This study shows that a vicinal polyol, such as 1,2 propanediol, is suitable for obtaining Fe rather than 1,3 propanediol owing to the formation of a reducible Fe intermediate complex. X ray absorption spectroscopy analysis reveals the ferric octahedral geometry and tetrahedral geometry in the ferrous state of the reaction intermediates in 1,2 propanediol and 1,3 propanediol, respectively. The final product obtained using a vicinal polyol is Fe with a amp; 947; Fe2O3 shell, while the terminal polyol is favourable for Fe3O4. The distinct Fe Fe and Fe O bond lengths suggest the presence of a carboxylate group and a terminal alkoxide ligand in the intermediate of 1,2 propanediol. A large Fe Fe bond distance suggests diiron complexes with bidentate carboxylate bridges. Prominent high spin and low spin states indicate the possibility of transition, which favors the reduction of iron ions in the reaction using 1,2 propanedio

Sentinel Node Imaging in Breast Cancer using Superficial Injections: Technical Details and Observations

International audienceSentinel lymph node (SLN) biopsy is the evolving standard of care for the management of early breast cancer. Accurate identification of the SLN is paramount for success of this procedure. Various techniques are described for SLN identification, but the superficial injection techniques, advocated by the UK national training programme (NEW START) are validated, reproducible and rapid. Pre-operative lymphoscintigraphy provides a road map for the surgeon and requires a reporting template

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Not AvailableEnhancing crop productivity with higher input use efficiency without any damage to the soil and water resources is a big challenge to Indian agriculture. Soil is a complex system having physical, chemical and biological properties which differ from soil type to soil type. These properties/characteristics play an important role in deciding the response of any management imposed and thus ultimately govern the soil productivity and inputs use efficiency. It is, therefore, important that before developing any technology for the judicious use of inputs, these characteristics including soil-water-plant relations are well understood. In the recent past various advancements have been made to understand the various soil physical processes and the flow mechanism of water, gases and heat into and from the soil profile which affects the soil environment and the atmosphere above it. Different models have been developed with an attempt to solve many problems related to complex and dynamic soil-water-tillage-nutrient-plant system. Also, techniques have been developed for rapid and precise estimation of various kinds of abiotic stresses which have a bearing on plant growth, grain yield and judicious use of various inputs in agriculture in order to arrive at sustainable and conservation agriculture. Our knowledge on the subject, however, is still limited owing to the complex nature of the soil system. There is need to study this dynamic system in-depth in multidisciplinary mode, including the root system architecture with respect to water and nutrient uptake and mitigation of various kinds of plant abiotic and biotic stresses. This paper discusses, in brief, the various advancements made in the area of soil physics and their impact on sustainable agriculture.Not Availabl

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Not AvailableOf late, intensive farming for higher food production is often associated with many negative implications for soil systems, such as decline of soil organic matter (SOM), increase in risks of soil erosion by wind and/or water, decline in soil biological diversity, increase in degradation of soil physical quality, lower nutrient-use efficiency, high risks of groundwater pollution, falling water tables, increasing salinization and waterlogging, in-field burning of crop residues, pollution of air and emission of greenhouse gases (GHG), leading to global warming, and decline in factor productivity. These negative implications necessitate an objective review of strategies to develop sustainable management practices, which could not only sustain soil health and ensure food security, but also enhance carbon sequestration, decrease GHG emissions, and offer clean and better ecosystem services. Conservation agriculture (CA), that includes reduced or no-till practices along with crop residue retention and mixed crop rotations, offers multiple benefits. Adoption of a system-based CA conserves water, improves and creates more efficient use of natural resources through the integrated management of available soil nutrients, water, and biological resources, and enhances use efficiency of external inputs. Due to apparent benefits of CA, it is increasingly being adopted and now covers about 180 million hectares (Mha) worldwide. However, in South Asia its spread is low (<5 Mha), mostly concentrated in the Indo-Gangetic Plains (IGP). In this region, one of the serious issues is “residue burning” with severe environmental impacts. A huge amount of crop residue left over after the combine harvest of rice has forced farmers to practice widespread residue burning (∼140 M tonnes) to cope with excessive stubble and also for timely planting/sowing of succeeding crops. In rice-wheat cropping systems, which cover more than 10 Mha in the IGP, CA practices are relatively more accepted by farmers. In these systems, any delay in sowing leads to yield penalty of 1–1.5% per day after the optimum sowing date of wheat. The strong adoption of CA practices in IGP is mainly to overcome delayed sowing due to the field preparation and control of weeds, timely planting, and also escape from terminal heat during the grain-filling stage. Major challenges to CA adoption in South Asia are small land holdings (<1 ha), low technological reach to farmers, nonavailability of suitable farm implements for small farm holders, and the staunch conventional farming mind-set. South Asia region consists of many countries of diverse agro-ecologies with contrasting farming systems and management. This region, recently known for rapid economic growth and increasing population, necessitates higher food production and also hot-spots for adoption of CA technologies. Therefore, in this review critically explores the possibility, extent of area, prospects, challenges, and benefits of CA in South Asia.Not Availabl

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Not AvailableConservation agriculture (CA) including reduced or no-tillage and crop residue retention, is known to be a self–sustainable system as well as an alternative to residue burning. The present study evaluated the effect of reduced tillage coupled with residue retention under different cropping systems on soil properties and crop yields in a Vertisol of a semiarid region of central India. Two tillage systems – conventional tillage (CT) with residue removed, and reduced tillage (RT) with residue retained – and six major cropping systems of this region were examined after 3 years of experimentation. Results demonstrated that soil moisture content, mean weight diameter, percent water stable aggregates (>0.25 mm) for the 0–15 cm soil layer were significantly (P moderately labile > less labile. At the 0–15 cm depth, the contributions of moderately labile, less labile and non-labile C fractions to total organic C were 39.3%, 10.3% and 50.4% respectively in RT and corresponding values for CT were 38.9%, 11.7% and 49.4%. Significant differences in different C fractions were observed between RT and CT. Soil microbial biomass C concentration was significantly higher in RT than CT at 0–15 cm depth. The maize–chickpea cropping system had significantly (P < 0.05) higher soybean grain equivalent yield of 4.65 t ha–1 followed by soybean + pigeon pea (2 : 1) intercropping (3.50 t ha–1) and soybean–wheat cropping systems (2.97 t ha–1). Thus, CA practices could be sustainable management practices for improving soil health and crop yields of rainfed Vertisols in these semiarid regions.Not Availabl

Results of shared learning of a new magnetic seed localisation device – A UK iBRA-NET breast cancer localisation study

Introduction Shared learning is imperative in the assessment and safe implementation of new healthcare interventions. Magnetic seeds (Magseed®) potentially offer logistical benefit over wire localisation for non-palpable breast lesions but few data exist on outcomes comparing these techniques. A national registration study (iBRA-NET) was conducted to collate device outcomes. In order to share learning, thematic analysis was conducted to ascertain early clinical experiences of Magseed® and wire guided localisation and explore how learning events may be applied to improve clinical outcomes. Methods A qualitative study of 27 oncoplastic surgeons, radiologists and physicians was conducted in January 2020 to ascertain the feasibility and challenges associated with Magseed® versus wire breast localisation surgery. Four focus groups were asked to discuss experiences, concerns and shared learning outcomes which were tabulated and analysed thematically. Results Three key themes were identified comparing Magseed® and wire localisation of breast lesions relating to preoperative, intraoperative and postoperative learning outcomes. Percutaneous Magseed® detection, instrument interference and potential seed or wire dislodgement were the most common issues identified. Clinician experience suggested Magseed® index lesion identification was non-inferior to wire placement and improved the patient pathway in terms of scheduling and multi-site insertion. Conclusions Prospective shared learning suggested Magseed® offered additional non-clinical benefits over wire localisation, improving the efficiency of the patient pathway. Recommendations for improving breast localisation technique, appropriate patient selection and clinical practice through shared learning are discussed that may aid other surgeons in the adoption of this relatively new technique

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Not AvailableSoil organic matter dynamics in terrestrial ecosystems are controlled by complex interactions between various factors such as climate, soil, and agricultural management practices. We utilized a process-based crop model, APSIM, to simulate long-term soil organic carbon (SOC) dynamics for a soybean-wheat cropping system under nitrogen (N) and farmyard manure management (FYM) practices for a 43-year old experimental dataset in India. The APSIM was parameterized and validated to predict grain yield and SOC stock. The validated model was then used to evaluate the impacts of different management practices on SOC dynamics in the top 30 cm of soil through scenario modeling. The results of the APSIM simulations demonstrated that improved N and FYM management practices had great potential to increase SOC sequestration in these Vertisols. The equilibrium SOC concentration under different N management practices increased with a higher N application rate, with the integrated application of N with FYM showing the maximum rate. The optimum N (Nopt) rate for maximum SOC sequestration was estimated to be 155 kg ha−1 for wheat in the studied Vertisol and the time to reach steady-state of the site was 104 years. The Nopt increased SOC by about 28.6% over the initial concentration. We found that the APSIM was robust in predicting long-term changes in SOC stock (Index of agreement = 0.79 and root mean square error = 3.33 Mg ha−1, R2 = 0.92, mean bias error = −1.08) for a Vertisol soil of central India, in this case under a soybean-wheat cropping system. The study results highlighted that balanced fertilization is the key to sustaining SOC stock in the long-term for Vertisols.Not Availabl