Electrical and Mechanical Properties of new Recyclable Power Cable Insulation Materials based upon Polyethylene Blends

Chemically crosslinked polyethylene (XLPE) has been used as electrical insulation for power cables since the 1970s due to its favourable combination of electrical and mechanical properties. However, as the electrical engineering community has become increasingly aware of the life cycle environmental impacts, XLPE has come under scrutiny for its lack of recyclability and the high process energies used in its manufacture. Although technologies are being developed to facilitate the re-use of XLPE at the end of its initial service life, the use of this material is inferior to fully recyclable and low process energy alternatives. In this investigation, we concentrated on the use of binary blends of linear and branched polyethylene (LPE / BPE) as potential replacement materials for XLPE, since such systems have the potential to combine comparable mechanical properties and enhanced breakdown strength with good recyclability. We compare the thin film AC ramp breakdown behaviour of blends as a function of temperature up to 97 oC. These consist of the same BPE in virgin and crosslinked states and in a blend with 20wt% LPE. These data are augmented with dynamic mechanical analysis. In concert, these data indicate that with appropriate morphological control the blended thermoplastic material exhibits superior properties to XLPE under conventional operating conditions and may even be suitable for higher temperature operation than XLPE. The paper will discuss the importance of polymer blending and blend physical properties in the context of the process requirements and the implications for cable manufacture and on cable electrical and environmental performance in comparison with XLPE

The stability of immiscible viscous fingering in Hele-Shaw cells with spatially varying permeability

In this paper, we investigate the stability of immiscible viscous fingering in Hele-Shaw cells with spatially varying permeability, across a range of capillary numbers. We utilise a coupled boundary element - radial basis function (BE –RBF) numerical method that adapts and moves with the growing interface, providing an efficient, high accuracy scheme to track the interfacial displacement of immiscible fluids. By comparing the interfacial evolution and growth rate in varying permeability cells to that in uniform cells, we can assess the relative stability of the perturbations as a consequence of the variable permeability. Numerical experiments in Hele-Shaw cells with gradually varying permeability highlight 3 aperture effects that control the interfacial stability: (1) Gradients in the capillary pressure (2) Local changes in fluid mobility (3) Variation in the viscous pressure gradient. In low capillary number regimes, we find that aperture effect 1 and 2 dominate, which (relatively) stabilise interfacial perturbations in converging geometries and destabilise perturbations in diverging geometries. In high capillary number regimes, aperture effect 3 dominates meaning the relative stability transitions; the interface is destabilised in converging cells and stabilised in diverging cells. We find an upper bound critical capillary number Cagt at which the relative stability transitions in our gradually varying cell as 1000<Cagt<1250, which is independent of both α and ϵ0. This result is much lower than the value of Cagt=9139 predicted by linear stability theory, due to significant non-linear perturbation growth. This transition links the results found in previous works performed at low and high capillary numbers, providing new insight into the viscous fingering instability in variable permeability cells. To conclude, we present simulations in Hele-Shaw cells with large geometric heterogeneities and anisotropy, in order to demonstrate the significant fluid re-distribution that can occur due to localised variations in cell permeability. Using periodic permeability distributions, we show the significant re-distribution of fluid that can occur due to large capillary pressure gradients in the capillary limit, and the channelling of flow that can occur in the viscous limit along anisotropic features

Ventricular septal defect due to blunt chest trauma

Blunt chest trauma may cause cardiac trauma, this possibility often being overlooked. Various anatomical structures may be affected. A case of ventr'icular septal defect due to blunt chest trauma is described and the relevant literature is reviewed

Thermoplastic cable insulation comprising a blend of isotactic polypropylene and a propylene-ethylene copolymer

There is much interest in the development of replacement materials for crosslinked polyethylene (XLPE) that are both recyclable (i.e. thermoplastic) and capable of high temperature operation. Thermally, polypropylene is the ideal choice, although its stiffness and low electrical breakdown strength make for a challenging materials design problem. We report here on the compositional optimization of a propylene homopolymer/propylene-ethylene copolymer blend in terms of its dynamic mechanical properties and thin film electrical breakdown strength. The extrusion of a trial mini-cable using the optimized blend is also discussed, which is shown to exhibit a significantly improved electrical performance, as gauged by its DC breakdown strength, than an XLPE-insulated reference

ISPIDER Central: an integrated database web-server for proteomics

Despite the growing volumes of proteomic data, integration of the underlying results remains problematic owing to differences in formats, data captured, protein accessions and services available from the individual repositories. To address this, we present the ISPIDER Central Proteomic Database search (http://www.ispider.manchester.ac.uk/cgi-bin/ProteomicSearch.pl), an integration service offering novel search capabilities over leading, mature, proteomic repositories including PRoteomics IDEntifications database (PRIDE), PepSeeker, PeptideAtlas and the Global Proteome Machine. It enables users to search for proteins and peptides that have been characterised in mass spectrometry-based proteomics experiments from different groups, stored in different databases, and view the collated results with specialist viewers/clients. In order to overcome limitations imposed by the great variability in protein accessions used by individual laboratories, the European Bioinformatics Institute's Protein Identifier Cross-Reference (PICR) service is used to resolve accessions from different sequence repositories. Custom-built clients allow users to view peptide/protein identifications in different contexts from multiple experiments and repositories, as well as integration with the Dasty2 client supporting any annotations available from Distributed Annotation System servers. Further information on the protein hits may also be added via external web services able to take a protein as input. This web server offers the first truly integrated access to proteomics repositories and provides a unique service to biologists interested in mass spectrometry-based proteomics

Unusual morphologies and the occurrence of pseudomorphs after ikaite (CaCO3•6H2O) in fast growing, hyperalkaline speleothem

Unusual speleothem, associated with hyperalkaline (pH>12) groundwaters have formed within a shallow, abandoned railway tunnel at Peak Dale, Derbyshire, UK. The hyperalkaline groundwaters are produced by the leaching of a thin layer (<2 m) of old lime kiln waste above the soil-bedrock surface above the tunnel by rainwater. This results in a different reaction and chemical process to that more commonly associated with the formation of calcium carbonate speleothems from Ca-HCO3-type groundwaters and degassing of CO2. Stalagmites within the Peak Dale tunnel have grown rapidly (averaging 33 mm y-1), following the closure of the tunnel 70 years ago. They have an unusual morphology comprising a central sub-horizontally-laminated column of micro- to nano-crystalline calcium carbonate encompassed by an outer sub-vertical assymetric ripple laminated layer. The stalagmites are largely composed of secondary calcite forming pseudomorphs (<1 mm) which we believe to be predominantly after the ‘cold climate’ calcium carbonate polymorph, ikaite (calcium carbonate hexahydrate: CaCO3•6H2O), with minor volumes of small (<5 μm) pseudomorphs after vaterite. The tunnel has a near constant temperature of 8-9°C which is slightly above the previously published crystallisation temperatures for ikaite (<6°C). Analysis of a stalagmite actively growing at the time of sampling, and preserved immediately within a dry nitrogen cryogenic vessel, indicates that following crystallisation of ikaite, decomposition to calcite occurs rapidly, if not instantaneously. We believe this is the first occurrence of this calcium carbonate polymorph observed within speleothem

Magnetic Fields at First Order Phase Transition: A Threat to Electroweak Baryogenesis

The generation of the observed baryon asymmetry may have taken place during the electroweak phase transition, thus involving physics testable at LHC, a scenario dubbed electroweak baryogenesis. In this paper we point out that the magnetic field which is produced in the bubbles of a first order phase transition endangers the baryon asymmetry produced in the bubble walls. The reason being that the produced magnetic field couples to the sphaleron magnetic moment and lowers the sphaleron energy; this strengthens the sphaleron transitions inside the bubbles and triggers a more effective wash out of the baryon asymmetry. We apply this scenario to the Minimal Supersymmetric extension of the Standard Model (MSSM) where, in the absence of a magnetic field, successful electroweak baryogenesis requires the lightest CP-even Higgs and the right-handed stop masses to be lighter than about 127 GeV and 120 GeV, respectively. We show that even for moderate values of the magnetic field, the Higgs mass required to preserve the baryon asymmetry is below the present experimental bound. As a consequence electroweak baryogenesis within the MSSM should be confronted on the one hand to future measurements at the LHC on the Higgs and the right-handed stop masses, and on the other hand to more precise calculations of the magnetic field produced at the electroweak phase transition.Comment: 16 pages, 4 figures. Minor corrections and references added to match published versio

Meeting Report: Application of Genotyping Methods to Assess Risks from Cryptosporidium in Watersheds

A workshop titled "Application of Genotyping Methods to Assess Pathogen Risks from Cryptosporidium in Drinking Water Catchments" was held at the International Water Association biennial conference, Marrakech, Morocco, 23 September 2004. The workshop presented and discussed the findings of an interlaboratory trial that compared methods for genotyping Cryptosporidium oocysts isolated from feces. The primary goal of the trial and workshop was to assess the utility of current Cryptosporidium genotyping methods for determining the public health significance of oocysts isolated from feces in potable-water-supply watersheds. An expert panel of 16 watershed managers, public health practitioners, and molecular parasitologists was assembled for the workshop. A subordinate goal of the workshop was to educate watershed management and public health practitioners. An open invitation was extended to all conference delegates to attend the workshop, which drew approximately 50 interested delegates. In this report we summarize the peer consensus emerging from the workshop. Recommendations on the use of current methods by watershed managers and public health practitioners were proposed. Importantly, all the methods that were reported in the trial were mutually supporting and found to be valuable and worthy of further utility and development. Where there were choices as to which method to apply, the small-subunit ribosomal RNA gene was considered to be the optimum genetic locus to target. The single-strand conformational polymorphism method was considered potentially the most valuable for discriminating to the subtype level and where a large number of samples were to be analyzed. A research agenda for protozoan geneticists was proposed to improve the utility of methods into the future. Standardization of methods and nomenclature was promoted

Immiscible thermo-viscous fingering in Hele-Shaw cells

We investigate immiscible radial displacement in a Hele-Shaw cell with a temperature dependent viscosity using two coupled high resolution numerical methods. Thermal gradients created in the domain through the injection of a low viscosity fluid at a different temperature to the resident high viscosity fluid can lead to the formation of unstable thermo-viscous fingers, which we explore in the context of immiscible flows. The transient, multi-zone heat transfer is evaluated using a newly developed auxiliary radial basis function-finite collocation (RBF-FC) method, which locally captures variation in flux and field variable over the moving interface, without the need for ghost node extrapolation. The viscosity couples the transient heat transfer to the Darcy pressure/velocity field, which is solved using a boundary element - RBF-FC method, providing an accurate and robust interface tracking scheme for the full thermo-viscous problem. We explore the thermo-viscous problem space using systematic numerical experiments, revealing that the early stage finger growth is controlled by the pressure gradient induced by the varying temperature and mobility field. In hot injection regimes, negative temperature gradients normal to the interface act to accelerate the interface, promoting finger bifurcation and enhancing the viscous fingering instability. Correspondingly, cold injection regimes stabilise the flow compared to isothermal cases, hindering finger formation. The interfacial mobility distribution controls the late stage bifurcation mode, with non-uniformities induced by the thermal diffusivity creating alternate bifurcation modes. Further numerical experiments reveal the neutral stability of the thermal effects on the fingering evolution, with classical viscous fingering dynamics eventually dominating the evolution. We conclude the paper with a mechanistic summary of the immiscible thermo-viscous fingering regime, providing the first detailed analysis of the thermal problem in immiscible flows