The White Stone Band of the Kimmeridge Clay Formation, an integrated high resolution approach to understanding environmental change

The Kimmeridge Clay is a Jurassic mudrock succession that shows Milankovitch Band climatic cyclicity. A key issue is to determine how the subtle changes that define this cyclicity result from climatic change. Using material from the Natural Environment Research Council Rapid Global Geological Events (RGGE) Kimmeridge Drilling Project boreholes, the White Stone Band was investigated at the lamination scale using backscattered electron imagery and quantitative palynofacies. Fabric analysis shows the lamination to represent successive deposition of coccolith-rich and organic-matter-rich layers. Individual laminae contain unsorted palynological debris with a consistent ratio of marine and terrestrial components. Such mixed organic matter input is interpreted as the result of storm transport. Linking water column processes to laminae deposition suggests seasonal input with a coccolith bloom followed by a more diverse assemblage including dinoflagellates and photosynthetic chlorobiacean bacteria. As the photic zone extended into the euxinic water column organic matter export to the sea bed underwent minimal cycling through oxidation and subsequently became preserved through sulphurization with greatly increased sequestration of carbon. This was significantlyincreased by late season storm-driven mixing of euxinic water into the photic zone. Increased frequency ofstorm systems would therefore dilute the coccolith input to give an oil shale. Hence climatically induced changes in storm frequency would progressively vary the organic content of the sediment and generate the climate cycle signal. Keywords: Milankovitch theory, Kimmeridge Clay, organic matter, high-resolution methods, climate change

The calcified seaweed (maerl) deposits of the Falkland Islands

Scattered across many foreshore areas around the Falkland Islands (Fig. 1) are fragments of white, limy material derived from carbonate-fixing, marine red algae. Locally, the limy detritus is sufficiently abundant to have built-up substantial beach deposits. In their report accompanying publication of the 1:250 000 scale geological maps of the islands, Aldiss and Edwards (1998) drew attention to the potential importance of these deposits as a source of agricultural lime, particularly in the absence of any other indigenous source of limestone. Very similar material has been exploited elsewhere in the world for both agricultural and horticultural use; for example, sub-tidal banks were extensively dredged in the English Channel off Cornwall and Brittanny. There, the limy, algal debris is referred to generically as Lithothamion, and commercially as maerl. The equivalent material in the Falkland Islands is known locally as calcified seaweed

Is silt the most influential soil grain size fraction?

The contribution of individual grain size fractions (2000–500, 500–250, 250–63, 63–2 and < 2 μm) to bulk soil surface area and reactivity is discussed with reference to mineralogical and oxalate and dithionite extractions data. The 63–2 μm fraction contributed up to 56% and 67% of bulk soil volume and BET surface area, respectively. Consideration of these observations and the mineralogy of this fraction suggest that the 63–2 μm fraction may be the most influential for the release of elements via mineral dissolution in the bulk soil

Autonomous Flight in Unknown Indoor Environments

http://multi-science.metapress.com/content/80586kml376k2711/This paper presents our solution for enabling a quadrotor helicopter, equipped with a laser rangefinder sensor, to autonomously explore and map unstructured and unknown indoor environments. While these capabilities are already commodities on ground vehicles, air vehicles seeking the same performance face unique challenges. In this paper, we describe the difficulties in achieving fully autonomous helicopter flight, highlighting the differences between ground and helicopter robots that make it difficult to use algorithms that have been developed for ground robots. We then provide an overview of our solution to the key problems, including a multilevel sensing and control hierarchy, a high-speed laser scan-matching algorithm, an EKF for data fusion, a high-level SLAM implementation, and an exploration planner. Finally, we show experimental results demonstrating the helicopter's ability to navigate accurately and autonomously in unknown environments.National Science Foundation (U.S.) (NSF Division of Information and Intelligent Systems under grant # 0546467)United States. Army Research Office (ARO MAST CTA)Singapore. Armed Force

Anomalous enrichment of molybdenum and associated metals in Lower Jurassic (Lias Group) black shales of central England, as revealed by systematic geochemical surveys

Systematic multi-media geochemical surveying by the British Geological Survey's Geochemical Baseline Survey of the Environment (G-BASE) project has revealed significant anomalous patterns of enrichment for a suite of elements – copper (Cu) and uranium (U) – with exceptionally high levels of molybdenum (Mo), in soils and stream sediments in central England. Enrichment of these elements is most often associated with organic-rich, sulphidic ‘black shale’ lithofacies, typical of oxygen-deficient, euxinic depositional environments. The main anomaly lies between Evesham and Rugby where the bedrock comprises the Blue Lias and Charmouth Mudstone formations. Concentrations of Mo are particularly high, reaching soil values of 50 mg/kg, where the regional background is <2 mg/kg. Analysis of black shale partings sampled from rhythmic limestone–shale couplets reveal Mo levels up to 320 mg/kg. Complementary X-ray diffraction analyses suggest that the anomalous Mo levels are hosted by sulphidic (pyrite) rather than organic phases. High Mo levels may have significant impacts on local agriculture, as well as revealing hitherto unsuspected periods of hypoxic and anoxic bottom water sedimentation within localised basins in central England during the Early Jurassic. Rhythmic alternations of thin beds of Mo-rich, sulphidic black shale (euxinic) with bioclastic and micritic limestone (oxic) represent primary depositional cycles rather than a diagenetic origin. The bed-scale cyclicity is attributed to previously described orbitally-induced precession cycles that influenced climate. These resulted in periods of basin anoxia and black shale sedimentation during periods of enhanced terrestrial fresh-water run-off (possibly below a low-salinity pycnocline), alternating with periods of oxygenation of the sea-water and bottom sediments during overturn of the water column

Quantifying the contribution of sediment compaction to late Holocene salt-marsh sea-level reconstructions, North Carolina, USA

Salt-marsh sediments provide accurate and precise reconstructions of late Holocene relative sea-level changes. However, compaction of salt-marsh stratigraphies can cause post-depositional lowering (PDL) of the samples used to reconstruct sea level, creating an estimation of former sea level that is too low and a rate of rise that is too great. We estimated the contribution of compaction to late Holocene sea-level trends reconstructed at Tump Point, North Carolina, USA. We used a geotechnical model that was empirically calibrated by performing tests on surface sediments from modern depositional environments analogous to those encountered in the sediment core. The model generated depth-specific estimates of PDL, allowing samples to be returned to their depositional altitudes. After removing an estimate of land-level change, error-in-variables changepoint analysis of the decompacted and original sea-level reconstructions identified three trends. Compaction did not generate artificial sea-level trends and cannot be invoked as a causal mechanism for the features in the Tump Point record. The maximum relative contribution of compaction to reconstructed sea-level change was 12%. The decompacted sea-level record shows 1.71 mm yr−1 of rise since AD 1845

An improved approach to characterize potash-bearing evaporite deposits, evidenced in North Yorkshire, United Kingdom

Traditionally, potash mineral deposits have been characterized using downhole geophysical logging in tandem with geochemical analysis of core samples to establish the critical potassium (% K2O) content. These techniques have been employed in a recent exploration study of the Permian evaporite succession of North Yorkshire, United Kingdom, but the characterization of these complex deposits has been led by mineralogical analysis, using quantitative X-ray diffraction (QXRD). The novel QXRD approach provides data on K content with the level of confidence needed for reliable reporting of resources and also identifies and quantifies more precisely the nature of the K-bearing minerals. Errors have also been identified when employing traditional geochemical approaches for this deposit, which would have resulted in underestimated potash grades. QXRD analysis has consistently identified polyhalite (K2Ca2Mg(SO4)4·2(H2O) in the Fordon (Evaporite) Formation and sylvite (KCl) in the Boulby Potash and Sneaton Potash members as the principal K-bearing host minerals in North Yorkshire. However, other K hosts, including kalistrontite (K2Sr(SO4)2) a first recorded occurrence in the UK, and a range of boron-bearing minerals have also been detected. Application of the QXRD-led characterization program across the evaporitic basin has helped to produce a descriptive, empirical model for the deposits, including the polyhalite-bearing Shelf and Basin seams and two, newly discovered sylvite-bearing bittern salt horizons, the Pasture Beck and Gough seams. The characterization program has enabled a polyhalite mineral inventory in excess of 2.5 billion metric tons (Bt) to be identified, suggesting that this region possesses the world’s largest known resource of polyhalite. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution and reproduction in any medium provided that the original work is properly attributed

The role of fault gouge properties on fault reactivation during hydraulic stimulation; an experimental study using analogue faults

During the hydraulic stimulation of shale gas reservoirs the pore pressure on pre-existing faults/fractures can be raised sufficiently to cause reactivation/slip. There is some discrepancy in the literature over whether this interaction is beneficial or not to hydrocarbon extraction. Some state that the interaction will enhance the connectivity of fractures and also increase the Stimulated Reservoir Volume. However, other research states that natural fractures may cause leak-off of fracturing fluid away from the target zone, therefore reducing the amount of hydrocarbons extracted. Furthermore, at a larger scale there is potential for the reactivation of larger faults, this has the potential to harm the well integrity or cause leakage of fracturing fluid to overlying aquifers. In order to understand fault reactivation potential during hydraulic stimulation a series of analogue tests have been performed. These tests were conducted using a Bowland Shale gouge in the Angled Shear Rig (ASR). Firstly, the gouge was sheared until critically stressed. Water was then injected into the gouge to simulate pore fluid increase as a response to hydraulic stimulation. A number of experimental parameters were monitored to identify fracture reactivation. This study examined the effect of stress state, moisture content, and mineralogy on the fault properties. The mechanical strength of a gouge increases with stress and therefore depth. As expected, a reduction of moisture content also resulted in a small increase in mechanical strength. Results were compared with tests previously performed using the ASR apparatus, these showed that mineralogy will also affect the mechanical strength of the gouge. However, further work is required to investigate the roles of specific minerals, e.g. quartz content. During the reactivation phase of testing all tests reactivated, releasing small amounts of energy. This indicates that in these basic conditions natural fractures and faults will reactivate during the hydraulic stimulation if critically stressed. Furthermore, more variables should be investigated in the future, such as the effect of fluid injection rate and type of fluid