A Laplace Transform Method for Molecular Mass Distribution Calculation from Rheometric Data

Polydisperse linear polymer melts can be microscopically described by the tube model and fractal reptation dynamics, while on the macroscopic side the generalized Maxwell model is capable of correctly displaying most of the rheological behavior. In this paper, a Laplace transform method is derived and different macroscopic starting points for molecular mass distribution calculation are compared to a classical light scattering evaluation. The underlying assumptions comprise the modern understanding on polymer dynamics in entangled systems but can be stated in a mathematically generalized way. The resulting method is very easy to use due to its mathematical structure and it is capable of calculating multimodal molecular mass distributions of linear polymer melts

Electron-Transport Properties of Na Nanowires under Applied Bias Voltages

We present first-principles calculations on electron transport through Na nanowires at finite bias voltages. The nanowire exhibits a nonlinear current-voltage characteristic and negative differential conductance. The latter is explained by the drastic suppression of the transmission peaks which is attributed to the electron transportability of the negatively biased plinth attached to the end of the nanowire. In addition, the finding that a voltage drop preferentially occurs on the negatively biased side of the nanowire is discussed in relation to the electronic structure and conduction.Comment: 4 pages, 6 figure

Towards the Green-Griffiths-Lang conjecture

The Green-Griffiths-Lang conjecture stipulates that for every projective variety X of general type over C, there exists a proper algebraic subvariety of X containing all non constant entire curves f : C $\rightarrow$ X. Using the formalism of directed varieties, we prove here that this assertion holds true in case X satisfies a strong general type condition that is related to a certain jet-semistability property of the tangent bundle TX . We then give a sufficient criterion for the Kobayashi hyperbolicity of an arbitrary directed variety (X,V). This work is dedicated to the memory of Professor Salah Baouendi.Comment: version 2 has been expanded and improved (15 pages

The anomaly-free quantization of two-dimensional relativistic string. I

An anomaly-free quantum theory of a relativistic string is constructed in two-dimensional space-time. The states of the string are found to be similar to the states of a massless chiral quantum particle. This result is obtained by generalizing the concept of an ``operator'' in quantum field theory.Comment: LaTeX, 19 pages, no figure

Generating loop graphs via Hopf algebra in quantum field theory

We use the Hopf algebra structure of the time-ordered algebra of field operators to generate all connected weighted Feynman graphs in a recursive and efficient manner. The algebraic representation of the graphs is such that they can be evaluated directly as contributions to the connected n-point functions. The recursion proceeds by loop order and vertex number.Comment: 22 pages, LaTeX + AMS + eepic; new section with alternative recursion formula added, further minor changes and correction

High Frequency Scattering from Arbitrarily Oriented Dielectric Disks

Calculations have been made of electromagnetic wave scattering from dielectric disks of arbitrary shape and orientation in the high frequency (physical optics) regime. The solution is obtained by approximating the fields inside the disk with the fields induced inside an identically oriented slab (i.e. infinite parallel planes) with the same thickness and dielectric properties. The fields inside the disk excite conduction and polarization currents which are used to calculate the scattered fields by integrating the radiation from these sources over the volume of the disk. This computation has been executed for observers in the far field of the disk in the case of disks with arbitrary orientation and for arbitrary polarization of the incident radiation. The results have been expressed in the form of a dyadic scattering amplitude for the disk. The results apply to disks whose diameter is large compared to wavelength and whose thickness is small compared to diameter, but the thickness need not be small compared to wavelength. Examples of the dependence of the scattering amplitude on frequency, dielectric properties of the disk and disk orientation are presented for disks of circular cross section

Low-energy models for correlated materials: bandwidth renormalization from Coulombic screening

We provide a prescription for constructing Hamiltonians representing the low energy physics of correlated electron materials with dynamically screened Coulomb interactions. The key feature is a renormalization of the hopping and hybridization parameters by the processes that lead to the dynamical screening. The renormalization is shown to be non-negligible for various classes of correlated electron materials. The bandwidth reduction effect is necessary for connecting models to materials behavior and for making quantitative predictions for low-energy properties of solids.Comment: 4 pages, 2 figure

Quantum phase transition in the Dicke model with critical and non-critical entanglement

We study the quantum phase transition of the Dicke model in the classical oscillator limit, where it occurs already for finite spin length. In contrast to the classical spin limit, for which spin-oscillator entanglement diverges at the transition, entanglement in the classical oscillator limit remains small. We derive the quantum phase transition with identical critical behavior in the two classical limits and explain the differences with respect to quantum fluctuations around the mean-field ground state through an effective model for the oscillator degrees of freedom. With numerical data for the full quantum model we study convergence to the classical limits. We contrast the classical oscillator limit with the dual limit of a high frequency oscillator, where the spin degrees of freedom are described by the Lipkin-Meshkov-Glick model. An alternative limit can be defined for the Rabi case of spin length one-half, in which spin frequency renormalization replaces the quantum phase transition.Comment: 1o pages, 10 figures, published versio