Composición química, estabilidad oxidativa y actividad antiproliferativa del extracto de hexano de semilla de Anethum graveolens (eneldo)

This study aimed to evaluate the physicochemical properties, chemical composition, and anti­proliferative activity of the hexane extract of Anethum graveolens L. (dill) seeds using gas chromatography mass spectrometry (GC-MS). Two fractions, namely the lipid fraction (74%) and volatile fraction (26%), were detected. The extract content of the seeds was about 9.4% and the extract had a pleasant spicy aroma. Oleic acid (52%), cis-vaccenic acid (6.2%), linoleic acid (5.5%), and palmitic acid (3.3%) were the key fatty acids in the lipid fraction, while apiol (23%) and d-carvone (2.4%) were the major volatile components. Tocols (tocopherols and tocotrienols) were also detected in the A. Graveolens extract (155 mg/100 g) and b-tocopherol was identified as the major tocol (71%). Dill extract showed a high oxidative stability (induction time = 45.22 h). Furthermore, dill extract showed antiproliferative activity against breast cancer cell lines.Este estudio tuvo como objetivo evaluar las propiedades fisicoquí­micas, la composición química y la actividad antiproliferativa del extracto de hexano de semillas de Anethum graveolens L. (eneldo) mediante cromatografía de gases con espectrometría de masas (GC-MS). Se detectaron dos fracciones, la fracción lipídica (74%) y la fracción volátil (26%). El contenido del extracto de las semi­llas fue de aproximadamente 9,4% y el extracto tenía un agradable aroma picante. Los ácidos oleico (52%), cis-vaccénico (6,2%), linoleico (5,5%) y palmítico (3,3%) fueron los ácidos grasos clave en la fracción lipídica, mientras que el apiol (23%) y la d-carvona (2,4%) fueron los principales componentes volátiles. También se detectaron tocoles (tocoferoles y tocotrienoles) en el extracto de A. Graveolens (155 mg/100 g) y se identificó el β-tocoferol como el principal tocol (71%). El extracto de eneldo mostró una alta estabilidad oxidativa (tiempo de inducción = 45,22 h). Además, el extracto de eneldo mostró actividad antiproliferativa contra las líneas celulares de cáncer de mama

Conversión de Oleum papaveris seminis en ésteres metílicos mediante un proceso de esterificación: Optimización y estudio cinético

This paper presents an acid pre-treatment process and a kinetic study for the esterification reaction of Oleum papaveris seminis oil with methanol in the presence of amberlite 120 as a solid catalyst to convert the oil into methyl esters. Response surface methodology (RSM) was applied to optimize the reaction parameters, i.e. reaction time, percentage of the catalyst and volume ratio of methanol to oil. The results revealed that 0.87% w/w of catalyst concentration and 44.70% v/v of methanol to oil ratio provided final free fatty acid (FFA) contents of 0.60% w/w at 102.40 min of reaction time. It proved that the contribution of Amberlite 120 in the esterification of FFA was highly significant. The kinetics of the esterification in Oleum papaveris seminis oil with methanol in the presence of the amberlite 120 catalyst were also investigated to establish the reaction rate constant (k), reaction order, and activation energy. The study was performed under the optimized parameters at three reaction temperatures (50, 55, and 60 ºC). The value of k was in the range of 0.013 to 0.027 min-1. The first-order kinetics’ model was suitable for this irreversible FFA esterification with the activation energy of about 60.9 KJ·mol-1.En este artículo se presenta un proceso de pre-tratamiento con ácido, y un estudio cinético de la reacción de esterificación. Se utiliza Oleum papaveris seminis con metanol en presencia de Amberlite 120 como catalizador sólido para la formación de los ésteres metílicos. Se aplicó una metodología de superficie de respuesta (RSM) para optimizar los parámetros de la reacción; es decir, tiempo de reacción, porcentaje de la relación de catalizador y volumen de metanol - aceite. Los resultados mostraron que el 0,87% w/w de la concentración de catalizador y 44,70% v/v de metanol en relación al aceite dan lugar a un contenido final de ácidos grasos libres (FFA) de 0,60% w/w en 102,40 min de tiempo de reacción. Se demostró que la contribución de Amberlite 120 en la esterificación de los FFA fue altamente significativa. La cinética de la esterificación del Oleum papaveris Seminis con metanol en presencia del catalizador Amberlite 120 también se investigó para establecer la constante de velocidad de reacción (k), orden de la reacción, y la energía de activación. El estudio se realizó bajo los parámetros optimizados a tres temperaturas de reacción (50, 55, y 60 °C). El valor de la constante k fué del rango de 0.013 a 0,027 min-1. El modelo de cinética de primer orden fue el adecuado para esta esterificación FFA irreversible con una energía de activación de aproximadamente 60,9 KJ mol -1

(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)diiodidocadmium

In the title compound, [CdI2(C14H12N2)], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the CdII atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra­hedral geometry. Inversion-related mol­ecules inter­act along the c-axis direction by π–π stacking inter­actions between the phenanthroline ring systems, with centroid–centroid distances of 3.707 (9) and 3.597 (10) Å

Characteristics and fatty acid composition of milk fat from Saudi Aradi goat

Goat milk is the second most prevalent edible milk in Saudi Arabia and is one of the most prominently produced milks in the world. Few studies have focused on the physicochemical properties of goat milk fat (GMF). Samples of Saudi Aradi goat milk were obtained during the spring dairy season to determine the physicochemical characteristics and fatty acid composition of the GMF. The physicochemical properties of Saudi Aradi GMF were as follows: iodine value, 23.2 g of I2·100 g−1 of fat; saponification value, 213.2 mg KOH·g−1 of fat; refractive index (25 °C), 1.4583; unsaponifiable matter, 0.54%; acidity, 0.52%; and peroxide value, 2.07 meq O2·kg−1 of fat. α-Tocopherol was the major tocol (70.9%), followed by β-tocopherol (22.02%). GMF had significant contents of polyunsaturated fatty acid (FA) (6.16%), conjugated linolenic acid (0.36%), saturated FA (67.04%) and branched FA (1.98%). The thermal profiles of the Saudi Aradi GMF samples were examined using a thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). Saudi Aradi GMF showed some absorbance in the UV-C range. This study demonstrated that the milk fat from the Saudi goat has physically and chemically favorable properties, as well as good nutritional properties, as a source of essential fatty acids and fat-soluble vitamin E

Cationic dye degradation and real textile wastewater treatment by heterogeneous photo-fenton, using a novel natural catalyst

A photo-Fenton process using a local iron oxide as a natural catalyst was compared to Fenton and UV/H2O2 advanced oxidation processes for degrading crystal violet (CV) dye in aqueous solutions. The catalyst was characterized by transmission electron microscopy (TEM), energy dispersive X-ray microanalysis (EDX), Fourier transform infrared spectroscopy (FT-IR), Raman spectrum, X-ray diffraction (XRD), UV-vis spectroscopy, and Brunauer–Emmett–Teller (BET) analysis. The optical properties proved that the catalyst represents a good candidate for photocatalytic activity. The impact of different parameters (catalyst dose, initial CV concentration, initial H2O2 concentration, pH) on the photo-Fenton efficiency was evaluated. A photo-Fenton process operated under UVC light irradiation, at spontaneous pH, with 1.0 g/L of catalyst and 30 mg/L of H2O2 was the most effective process, resulting in 98% CV dye removal within 3 h. LC-MS and ion-chromatography techniques were used to identify demethylated organic intermediates during the process. Furthermore, a regeneration study of the catalyst showed its stability and reusability (after three treatment cycles, CV dye degradation decreased from 94% to 83%). Finally, the photo-Fenton process was tested in the treatment of real textile wastewater, and the effluent was found to be in compliance with standards for industrial wastewater disposal into sewerage