58 research outputs found
Carbon Tetrachloride as Thermoporometry Liquid-probe to Study the Cross linking of Styrene Copolymer Networks
Mesh Size Distributions (MSDs) of swollen cross linked styrene copolymer networks have been measured by thermoporometry using CCl4 as a probe liquid. All numerical relationships required for the calculation of the MSD were established for both the liquid-to-solid and the solid-to-solid thermal transitions of CCl4 and successfully validated on test samples. It was found that the polymer network, for both thermally and photo-cross linked materials, was completely built in about four hours of exposure. A clear correlation was established between the average mesh size of the swollen polymer network on the one hand and the benzoyl peroxide groups content and swelling ratio on the other hand
Polymeric materials temporality: application ime vs lifetime durability
International audienc
Cycle de vie des materiaux polymeres : de la durabilite a la temporalite
International audienc
Photooxidation of polyoctenamer: viscoelastic assessment of gel formation
International audienc
In situ detection of hindered amine stabilizer consumption in polymer through oxidation by indirect electron spin resonance
International audienc
Durabilité de composites bois – polymères biodégradables
Cette étude porte sur la photodurabilité de matériaux
entièrement biodégradables : des composites bois – polymères
biodégradables. Les matrices polymères sont le poly(acide lactique),
l'Ecoflex et l'Ecovio. Les charges sont différentes
farines de peuplier dont certaines ont subi un traitement thermique
appelé rétification, visant à diminuer leur hygroscopie et ainsi
leur biodégradabilité. Ces mélanges (50/50) sont analysés
par rhéométrie à l'état fondu et par analyse enthalpique
différentielle (DSC) afin de caractériser leurs propriétés
initiales. Ils sont ensuite soumis Ă un photovieillissement naturel et
accéléré en enceinte et analysés de la même façon
afin d'évaluer leur durabilité face à la lumière solaire. En
effet, des mesures rhéologiques et thermiques vont nous permettre
d'observer les changements intervenant au niveau moléculaire au cours de
la dégradation et ainsi de proposer des mécanismes de
photodégradation
Eco-Friendly Aliphatic Polyesters Containing 1,4-Cyclohexane Dicarboxylate Units: Effect of Diol Chain Length on Thermo-Mechanical Properties
Aliphatic polyesters containing 1,4-cyclohexylene rings are an interesting class of materials, not yet fully investigated. They potentially have the good characteristics typical of biopolyesters (for example, polyalkylene dicarboxylates and polyhydroxy alkanoates), such as sustainability and biodegradability. Indeed, renewable biomass resources can be used as feedstock to prepare the monomers and some preliminary tests of biodegradation suggest that the aliphatic rings do not hinder the microorganism attack.1 Moreover, the presence of cyclohexyl groups into the main chain provides rigidity to macromolecular chains, raises Tg, and imparts desirable physical-mechanical properties. In this way, the problem of the poor mechanical properties generally found in aliphatic polyesters can be solved. Finally, the 1,4-cyclohexylene unit shows the other remarkable peculiarity that it can have two possible configurations, cis and trans. In a polymer containing the 1,4-cyclohexylene rings, it will suffice to slightly modify the cis/trans isomeric ratio to obtain materials whose phase behavior changes from fully amorphous to semicrystalline.2 Therefore, the final properties of these materials can be easily tailored according to the specific applications.
In this work diols with different chain length were tested as monomers for novel polyesters and the effects of the molecular characteristics on final properties were analyzed
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