Facile Low-Temperature synthesis of novel carbon nitrides for efficient conversion of carbon dioxide into Value-Added chemicals

The interest in using carbon nitrides (CN) for CO2 conversion has stimulated extensive research on CN synthesis. Herein, we report the synthesis of two novel CN materials using low-cost commercially available precursors at low temperatures in a short duration of time. Two CN materials, one derived from 5-amino tetrazole (named 4NZ-CN) and the other derived from 3, 5-diamino-1, 2, 4-triazole (named 3NZ-CN) precursors, are prepared by refluxing these precursors for 2 h at 100 °C. 4NZ-CN and 3NZ-CN catalysts show higher surface areas (55.80 and 52.00 m2 g−1) and more basic sites (10.05 and 5.65 mmol g−1) than the conventional graphitic carbon nitride (g-C3N4) derived from melamine, for which the corresponding values are 9.20 m2 g−1 and 0.62 mmol g−1, respectively. In addition, both CN exhibit a 3-fold higher catalytic activity for CO2 cycloaddition to epoxides than g-C3N4. The structure−activity relationship was ascertained using a combination of experimental and computational studies, and a catalytic mechanism was proposed. This work provides a facile strategy for the synthesis of novel CN materials at relatively low temperatures, and the developed catalysts show remarkable performance in the conversion of CO2 to value-added chemicals

Nuclear Shadowing in the Structure Function F3(x)F_3(x)

Nuclear modification of the structure function $F_3$ is investigated. Although it could be estimated in the medium and large $x$ regions from the nuclear structure function $F_2^A$, it is essentially unknown at small $x$. The nuclear structure function $F_3^A$ at small $x$ is investigated in two different theoretical models: a parton-recombination model with $Q^2$ rescaling and an aligned-jet model. We find that these models predict completely different behavior at small $x$: {\it antishadowing} in the first parton model and {\it shadowing} in the aligned-jet model. Therefore, studies of the ratio $F_3^A/F_3^D$ at small $x$ could be useful in discriminating among different models, which produce similar shadowing behavior in the structure function $F_2$. We also estimate currently acceptable nuclear modification of $F_3$ at small $x$ by using $F_2^A/F_2^D$ experimental data and baryon-number conservation.Comment: 10 pages, Latex, Figs.1 and 2 are not included, Complete postscript file including the figures is available at ftp://ftp.cc.saga-u.ac.jp/pub/paper/riko/quantum1/saga-he-78.ps.gz or at http://www.cc.saga-u.ac.jp/saga-u/riko/physics/quantum1/structure.htm

Fabricating a Structured Single-Atom Catalyst via High-Resolution Photopolymerization 3D Printing

This study introduces a novel solution to the design of structured catalysts, integrating single-piece 3D printing with single-atom catalysis. Structured catalysts are widely employed in industrial processes, as they provide optimal mass and heat transfer, leading to a more efficient use of catalytic materials. They are conventionally prepared using ceramic or metallic bodies, which are then washcoated and impregnated with catalytically active layers. However, this approach may lead to adhesion issues of the latter. By employing photopolymerization printing, a stable and active single-atom catalyst is directly shaped into a stand-alone, single-piece structured material. The battery of characterization methods employed in the present study confirms the uniform distribution of catalytically active species and the structural integrity of the material. Computational fluid dynamics simulations are applied to demonstrate enhanced momentum transfer and light distribution within the structured body. The materials are finally evaluated in the continuous-flow photocatalytic oxidation of benzyl alcohol to benzaldehyde, a relevant reaction to prepare biomass-derived building blocks. The innovative approach reported herein to manufacture a structured single-atom catalyst circumvents the complexities of traditional synthetic methods, offering scalability and efficiency improvements, and highlights the transformative role of 3D printing in catalysis engineering to revolutionize catalysts’ design

Resonance production by neutrinos: I. J=3/2 Resonances

The article contains general formulas for the production of J=3/2 resonances by neutrinos and antineutrinos. It specializes to the P_{33}(1232) resonance whose form factors are determined by theory and experiment and then are compared with experimental results at low and high energies. It is shown that the minimum in the low Q^2 region is a consequence of a combined effect from the vanishing of the vector form factors, the muon mass and Pauli blocking. Several improvements for the future investigations are suggested.Comment: 10 pages, LaTeX, misprints corrected, 1 reference adde

Highly effective adsorption of synthetic phenol effluent by a novel activated carbon prepared from fruit wastes of the Ceiba speciosa forest species

Fruit wastes of the Ceiba speciosa forest species were employed as raw material for preparing activated carbon towards removing phenol from water. Concave cavities spread over the entire material surface were observed from characterization results, resulting in a high surface area, 842 m2 g−1. Adsorption isotherm and kinetic studies were performed under the best conditions of pH (7) and adsorbent dosage (0.83 g L−1). An increase in temperature from 298 K to 328 K disfavored the phenol adsorption, decreasing from 156.7 to 145 mg g−1 for the best-fit model, Langmuir. The thermodynamic results indicated that the phenol adsorption was spontaneous, favorable, and exothermic. The phenol concentration decay shows that the equilibrium is reached at 120 min. The pore volume and surface diffusion model (PVSDM) was employed satisfactorily to describe the phenol decay behavior. The surface diffusion coefficient values were in the range of 10−9 cm2 s−1. The external and the internal mass transfer were the rate-controlling mechanisms. Therefore, the application of fruit wastes from Ceiba speciosa as raw material for preparing activated carbon proved very efficient towards removing phenol from an aqueous medium. The activated carbon is an alternative material to suppress water contamination due to phenol-derived species

Light-driven C–O coupling of carboxylic acids and alkyl halides over a Ni single-atom catalyst

Although visible-light-driven dual photoredox catalysis, a method that combines photoabsorbers and transition metals, has become a powerful tool to conduct coupling reactions, resource economical and scalability issues persist, owing to the use of catalysts and light absorbers that exploit critical raw materials (such as iridium complexes), and are homogeneous in nature. Here we report the merger of metallic single-atom and photoredox catalysis, in the form of a Ni atom-supported carbon nitride material, for the C–O coupling of carboxylic acids and alkyl halides. This operationally straightforward system, composed of only earth-abundant components, exhibits a wide functional group tolerance. Additionally, short reaction times, facile recovery and high catalyst stability make this method highly attractive for industrial applications

Leptoproduction of J/psi

We study leptoproduction of $J/\psi$ at large $Q^2$ within the nonrelativistic QCD (NRQCD) factorization formalism. The cross section is dominated by color-octet terms that are of order $\alpha_s$. The color-singlet term, which is of order $\alpha^2_s$, is shown to be a small contribution to the total cross section. We also calculate the tree diagrams for color-octet production at order $\alpha^2_s$ in a region of phase space where there is no leading color-octet contribution. We find that in this regime the color-singlet contribution dominates. We argue that non-perturbative corrections arising from diffractive leptoproduction, higher twist effects, and higher order terms in the NRQCD velocity expansion should be suppressed as $Q^2$ is increased. Therefore, the color-octet matrix elements $$and$$ can be reliably extracted from this process. Finally, we point out that an experimental measurement of the polarization of leptoproduced $J/\psi$ will provide an excellent test of the NRQCD factorization formalism.Comment: 33 pages latex. 10 figures. Uses revtex, epsf, and rotate macros. This paper is also available via the UW phenomenology archives at http://phenom.physics.wisc.edu/pub/preprints