Suppression of magnetism in Ba5AlIr2O11: interplay of Hund's coupling, molecular orbitals and spin-orbit interaction

The electronic and magnetic properties of Ba$_5$AlIr$_2$O$_{11}$ containing Ir-Ir dimers are investigated using the GGA and GGA+SOC calculations. We found that strong suppression of the magnetic moment in this compound recently found in [J. Terzic {\it et al.}, Phys. Rev. B {\bf 91}, 235147 (2015)] is not due to charge-ordering, but is related to the joint effect of the spin-orbit interaction and strong covalency, resulting in the formation of metal-metal bonds. They conspire and act against the intra-atomic Hund's rule exchange interaction to reduce total magnetic moment of the dimer. We argue that the same mechanism could be relevant for other $4d$ and $5d$ dimerized transition metal compounds

Evolution of Magnetism in Single-Crystal Honeycomb Iridates

We report the successful synthesis of single-crystals of the layered iridate, (Na$_{1-x}$Li$_{x}$)$_2$IrO$_3$, $0\leq x \leq 0.9$, and a thorough study of its structural, magnetic, thermal and transport properties. The new compound allows a controlled interpolation between Na$_2$IrO$_3$ and Li$_2$IrO$_3$, while maintaing the novel quantum magnetism of the honeycomb Ir$^{4+}$ planes. The measured phase diagram demonstrates a dramatic suppression of the N\'eel temperature, $T_N$, at intermediate $x$ suggesting that the magnetic order in Na$_2$IrO$_3$ and Li$_2$IrO$_3$ are distinct, and that at $x\approx 0.7$, the compound is close to a magnetically disordered phase that has been sought after in Na$_2$IrO$_3$ and Li$_2$IrO$_3$. By analyzing our magnetic data with a simple theoretical model we also show that the trigonal splitting, on the Ir$^{4+}$ ions changes sign from Na$_2$IrO$_3$ and Li$_2$IrO$_3$, and the honeycomb iridates are in the strong spin-orbit coupling regime, controlled by \jeff=1/2 moments.Comment: updated version with more dat

Random Resonators and Prelocalized Modes in Disordered Dielectric Films

Areal density of disorder-induced resonators with a high quality factor, $Q\gg 1$, in a film with fluctuating refraction index is calculated theoretically. We demonstrate that for a given $kl>1$, where $k$ is the light wave vector, and $l$ is the transport mean free path, when {\em on average} the light propagation is diffusive, the likelihood for finding a random resonator increases dramatically with increasing the correlation radius of the disorder. Parameters of {\em most probable} resonators as functions of $Q$ and $kl$ are found.Comment: 6 pages including 2 figure

Destruction of the Mott Insulating Ground State of Ca_2RuO_4 by a Structural Transition

We report a first-order phase transition at T_M=357 K in single crystal Ca_2RuO_4, an isomorph to the superconductor Sr_2RuO_4. The discontinuous decrease in electrical resistivity signals the near destruction of the Mott insulating phase and is triggered by a structural transition from the low temperature orthorhombic to a high temperature tetragonal phase. The magnetic susceptibility, which is temperature dependent but not Curie-like decreases abruptly at TM and becomes less temperature dependent. Unlike most insulator to metal transitions, the system is not magnetically ordered in either phase, though the Mott insulator phase is antiferromagnetic below T_N=110 K.Comment: Accepted for publication in Phys. Rev. B (Rapid Communications

Anderson Localization of Polar Eigenmodes in Random Planar Composites

Anderson localization of classical waves in disordered media is a fundamental physical phenomenon that has attracted attention in the past three decades. More recently, localization of polar excitations in nanostructured metal-dielectric films (also known as random planar composite) has been subject of intense studies. Potential applications of planar composites include local near-field microscopy and spectroscopy. A number of previous studies have relied on the quasistatic approximation and a direct analogy with localization of electrons in disordered solids. Here I consider the localization problem without the quasistatic approximation. I show that localization of polar excitations is characterized by algebraic rather than by exponential spatial confinement. This result is also valid in two and three dimensions. I also show that the previously used localization criterion based on the gyration radius of eigenmodes is inconsistent with both exponential and algebraic localization. An alternative criterion based on the dipole participation number is proposed. Numerical demonstration of a localization-delocalization transition is given. Finally, it is shown that, contrary to the previous belief, localized modes can be effectively coupled to running waves.Comment: 22 pages, 7 figures. Paper was revised and a more precise definition of the participation number given, data for figures recalculated accordingly. Accepted to J. Phys.: Cond. Mat

Competing Ground States in Triple-layered Sr4Ru3O10: Verging on Itinerant Ferromagnetism with Critical Fluctuations

Sr4Ru3O10 is characterized by a sharp metamagnetic transition and ferromagnetic behavior occurring within the basal plane and along the c-axis, respectively. Resistivity at magnetic field, B, exhibits low-frequency quantum oscillations when B||c-axis and large magnetoresistivity accompanied by critical fluctuations driven by the metamagnetism when B^c-axis. The complex behavior evidenced in resistivity, magnetization and specific heat presented is not characteristic of any obvious ground states, and points to an exotic state that shows a delicate balance between fluctuations and order.Comment: 18 pages, 4 figure

Non-Fermi-liquid behavior in nearly ferromagnetic metallic SrIrO3 single crystals

We report transport and thermodynamic properties of single-crystal SrIrO3 as a function of temperature T and applied magnetic field H. We find that SrIrO3 is a non-Fermi-liquid metal near a ferromagnetic instability, as characterized by the following properties: (1) small ordered moment but no evidence for long-range order down to 1.7 K; (2) strongly enhanced magnetic susceptibility that diverges as T or T1/2 at low temperatures, depending on the applied field; (3) heat capacity C(T,H) ~ -Tlog T that is readily amplified by low applied fields; (4) a strikingly large Wilson ratio at T< 4K; and (5) a T3/2-dependence of electrical resistivity over the range 1.7 < T < 120 K. A phase diagram based on the data implies SrIrO3 is a rare example of a stoichiometric oxide compound that exhibits non-Fermi-liquid behavior near a quantum critical point (T = 0 and H = 0.23 T)

Spin-orbit tuned metal-insulator transitions in single-crystal Sr2Ir1-xRhxO4 (0\leqx\leq1)

Sr2IrO4 is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr2RhO4 is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic and thermal properties reveals that substituting 4d Rh4+ (4d5) ions for 5d Ir4+(5d5) ions in Sr2IrO4 directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr2Ir1-xRhxO4 featuring two major effects: (1) Light Rh doping (0\leqx\leq0.16) prompts a simultaneous and precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x=0. (2) However, with heavier Rh doping (0.24< x<0.85 (\pm0.05)) disorder scattering leads to localized states and a return to an insulating state with spin frustration and exotic magnetic behavior that only disappears near x=1. The intricacy of Sr2Ir1-xRhxO4 is further highlighted by comparison with Sr2Ir1-xRuxO4 where Ru4+(4d4) drives a direct crossover from the insulating to metallic states.Comment: 5 figure

Transverse momentum dependence in the perturbative calculation of pion form factor

By reanalysing transverse momentum dependence in the perturbative calculation of pion form factor an improved expression of pion form factor which takes into account the transverse momentum dependenc in hard scattering amplitude and intrinsic transverse momentum dependence associated with pion wave functions is given to leading order, which is available for momentum transfers of the order of a few GeV as well as for $Q \to \infty$. Our scheme can be extended to evaluate the contributions to the pion form factor beyond leading order.Comment: 13 pages in LaTeX, plus 3 Postscript figure