Charge exchange neutral particle analysis with natural diamond detectors on LHD heliotron

Semiconductor detectors based on natural diamonds have been installed on the Large Helical Device (LHD) heliotron to measure the energy distribution of charge exchange fast neutral particles from different viewing angles. Advantages of a natural diamond detector (NDD) are (1) very compact size, (2) relatively easy handling, and (3) high energy resolution. Although NDDs are sensitive to visible light, vacuum ultraviolet, and soft x rays, unfavorable pulses produced by such radiation were greatly reduced by choosing an appropriate stainless steel shield in this experiment. In LHD, the time-resolved energy distribution of counter-going beam ions and ion cyclotron range of frequency-produced energetic ions have been successfully obtained by means of an NDD. The performance of NDDs as a neutral particle analyzer and its good suitability to LHD plasmas were demonstrated throughout this work

Triplet Exciton Generation in Bulk-Heterojunction Solar Cells based on Endohedral Fullerenes

Organic bulk-heterojunctions (BHJ) and solar cells containing the trimetallic nitride endohedral fullerene 1-[3-(2-ethyl)hexoxy carbonyl]propyl-1-phenyl-Lu3N@C80 (Lu3N@C80-PCBEH) show an open circuit voltage (VOC) 0.3 V higher than similar devices with [6,6]-phenyl-C[61]-butyric acid methyl ester (PC61BM). To fully exploit the potential of this acceptor molecule with respect to the power conversion efficiency (PCE) of solar cells, the short circuit current (JSC) should be improved to become competitive with the state of the art solar cells. Here, we address factors influencing the JSC in blends containing the high voltage absorber Lu3N@C80-PCBEH in view of both photogeneration but also transport and extraction of charge carriers. We apply optical, charge carrier extraction, morphology, and spin-sensitive techniques. In blends containing Lu3N@C80-PCBEH, we found 2 times weaker photoluminescence quenching, remainders of interchain excitons, and, most remarkably, triplet excitons formed on the polymer chain, which were absent in the reference P3HT:PC61BM blends. We show that electron back transfer to the triplet state along with the lower exciton dissociation yield due to intramolecular charge transfer in Lu3N@C80-PCBEH are responsible for the reduced photocurrent