The Behaviour of Finely Ground Bottom Ash in Portland Cement

The aim of this project was to assess the effects of finely ground MSWI bottom ash in Portland cement. Mortar mixes were prepared with 10% and 40% replacement of cement by ground IBA and then tested with regards to their material composition and engineering behaviour. IBA was found not to be inert, but showed some degree of reactivity. Replacement of cement with IBA was found to have no detrimental effects at low concentrations. This was not the case for 40% replacement, where cement replacement greatly affected strength, creep and drying shrinkage

Mapping Atomic Motions with Electrons: Toward the Quantum Limit to Imaging Chemistry

Recent advances in ultrafast electron and X-ray diffraction have pushed imaging of structural dynamics into the femtosecond time domain, that is, the fundamental time scale of atomic motion. New physics can be reached beyond the scope of traditional diffraction or reciprocal space imaging. By exploiting the high time resolution, it has been possible to directly observe the collapse of nearly innumerable possible nuclear motions to a few key reaction modes that direct chemistry. It is this reduction in dimensionality in the transition state region that makes chemistry a transferable concept, with the same class of reactions being applicable to synthetic strategies to nearly arbitrary levels of complexity. The ability to image the underlying key reaction modes has been achieved with resolution to relative changes in atomic positions to better than 0.01 Å, that is, comparable to thermal motions. We have effectively reached the fundamental space-time limit with respect to the reaction energetics and imaging the acting forces. In the process of ensemble measured structural changes, we have missed the quantum aspects of chemistry. This perspective reviews the current state of the art in imaging chemistry in action and poses the challenge to access quantum information on the dynamics. There is the possibility with the present ultrabright electron and X-ray sources, at least in principle, to do tomographic reconstruction of quantum states in the form of a Wigner function and density matrix for the vibrational, rotational, and electronic degrees of freedom. Accessing this quantum information constitutes the ultimate demand on the spatial and temporal resolution of reciprocal space imaging of chemistry. Given the much shorter wavelength and corresponding intrinsically higher spatial resolution of current electron sources over X-rays, this Perspective will focus on electrons to provide an overview of the challenge on both the theory and the experimental fronts to extract the quantum aspects of molecular dynamics

Revisit of cosmic age problem

We investigate the cosmic age problem associated with 9 extremely old globular clusters in M31 galaxy and 1 very old high-$z$ quasar APM 08279 + 5255 at $z=3.91$. These 9 globular clusters have not been used to study the cosmic age problem in the previous literature. By evaluating the age of the universe in the $\Lambda$CDM model with the observational constraints from the SNIa, the BAO, the CMB, and the independent $H_0$ measurements, we find that the existence of 5 globular clusters and 1 high-$z$ quasar are in tension (over 2$\sigma$ confidence level) with the current cosmological observations. So if the age estimates of these objects are correct, the cosmic age puzzle still remains in the standard cosmology. Moreover, we extend our investigations to the cases of the interacting dark energy models. It is found that although the introduction of the interaction between dark sectors can give a larger cosmic age, the interacting dark energy models still have difficulty to pass the cosmic age test.Comment: 11 pages, 5 figures, 1 table, accepted for publication in PR

Neuroinflammation is a putative target for the prevention and treatment of perioperative neurocognitive disorders.

IntroductionThe demographics of aging of the surgical population has increased the risk for perioperative neurocognitive disorders in which trauma-induced neuroinflammation plays a pivotal role.Sources of dataAfter determining the scope of the review, the authors used PubMed with select phrases encompassing the words in the scope. Both preclinical and clinical reports were considered.Areas of agreementNeuroinflammation is a sine qua non for development of perioperative neurocognitive disorders.Areas of controversyWhat is the best method for ameliorating trauma-induced neuroinflammation while preserving inflammation-based wound healing.Growing pointsThis review considers how to prepare for and manage the vulnerable elderly surgical patient through the entire spectrum, from preoperative assessment to postoperative period.Areas timely for developing researchWhat are the most effective and safest interventions for preventing and/or reversing Perioperative Neurocognitive Disorders

Using Different Approaches to Evaluate Individual Social Equity in Transport

Inequalities not only exist in the field of economics in relation to income and wealth, but also in other areas, such as the transport sector, where access to and use of different transport modes varies markedly across population groups, and which provides the means to access everyday living activities. A key concern within the transport sector is that inequality has extended beyond the traditional measures of travel, and now covers a wide range of effects relating to social exclusion, freedom, well-being and being able to access reasonable opportunities and resources. In order to address the aforementioned issues, an important question to resolve is what type of methods can be used to measure inequalities in transport most effectively. Therefore, this study aims to apply different approaches, including the Capabilities Approach (CA) and a further six inequality indices, namely the Gini coefficient, the Atkinson index, the Palma ratio, the Pietra ratio, the Schutz coefficient and the Theil index, to the case study using the relatively migrant-rich lower-income neighbourhood of Tuqiao, in Beijing, in order to assess individual transport-related social inequity issues. The findings suggest that the CA is useful in assessing transport-related inequalities where there are significant barriers to the take up of accessibility, for example where there are high levels of disadvantaged groups and disaggregated analysis can be undertaken. The Palma ratio appears to have a larger effect than the Gini coefficient and the other inequality indices when measuring transport-related social inequity. In addition, we also found that most income inequality methods adapted from econometrics may be better suited to measuring transport-related social inequity between different regions, cities or countries, or within the same area, but at different points in time, rather than to measuring a single neighbourhood as a whole. Finally, we argue that to what extent politicians or transport planners can use appropriate management tools to measure transport-related social inequalities may be significant in terms of the progress that can be made in the fight against social inequity in the transport field

Around 200 new X-ray binary IDs from 13 years of Chandra observations of the M31 center

We have created 0.3--10 keV, 13 year, unabsorbed luminosity lightcurves for 528 X-ray sources in the central 20' of M31. We have 174 Chandra observations spaced at ~1 month intervals thanks to our transient monitoring program, deeper observations of the M31 nucleus, and some public data from other surveys. We created 0.5--4.5 keV structure functions (SFs) for each source, for comparison with the ensemble structure function of AGN. We find 220 X-ray sources with luminosities > ~1E+35 erg/s that have SFs with significantly more variability than the ensemble AGN SF, and are likely X-ray binaries (XBs). A further 30 X-ray sources were identified as XBs using other methods. We therefore have 250 probable XBs in total, including ~200 new identifications. This result represents great progress over the ~50 XBs and ~40 XB candidates previously identified out of the ~2000 X-ray sources within the D_25 region of M31; it also demonstrates the power of SF analysis for identifying XBs in external galaxies. We also identify a new transient black hole candidate, associated with the M31 globular cluster B128.Comment: Accepted for publication in ApJ; 20 pages, 7 figures; Tables 1 and 2 continue after the references (8 pages

Domain Wall and Periodic Solutions of Coupled phi4 Models in an External Field

Coupled double well (phi4) one-dimensional potentials abound in both condensed matter physics and field theory. Here we provide an exhaustive set of exact periodic solutions of a coupled $\phi^4$ model in an external field in terms of elliptic functions (domain wall arrays) and obtain single domain wall solutions in specific limits. We also calculate the energy and interaction between solitons for various solutions. Both topological and nontopological (e.g. some pulse-like solutions in the presence of a conjugate field) domain walls are obtained. We relate some of these solutions to the recently observed magnetic domain walls in certain multiferroic materials and also in the field theory context wherever possible. Discrete analogs of these coupled models, relevant for structural transitions on a lattice, are also considered.Comment: 35 pages, no figures (J. Math. Phys. 2006