The State of Sustainable Research Software: Results from the Workshop on Sustainable Software for Science: Practice and Experiences (WSSSPE5.1)

This article summarizes motivations, organization, and activities of the Workshop on Sustainable Software for Science: Practice and Experiences (WSSSPE5.1) held in Manchester, UK in September 2017. The WSSSPE series promotes sustainable research software by positively impacting principles and best practices, careers, learning, and credit. This article discusses the Code of Conduct, idea papers, position papers, experience papers, demos, and lightning talks presented during the workshop. The main part of the article discusses the speed-blogging groups that formed during the meeting, along with the outputs of those sessions

Circulating Biologically Active Adrenomedullin Predicts Organ Failure and Mortality in Sepsis

BACKGROUND: Sepsis is a life-threatening organ dysfunction caused by a dysregulated host response to infection. Biologically active adrenomedullin (bio-ADM) is an emerging biomarker for sepsis. We explored whether bio-ADM concentration could predict severity, organ failure, and 30-day mortality in septic patients. METHODS: In 215 septic patients (109 patients with sepsis; 106 patients with septic shock), bio-ADM concentration was measured at diagnosis of sepsis, using sphingotest bio-ADM (Sphingotec GmbH, Hennigsdorf, Germany) and analyzed in terms of sepsis severity, vasopressor use, and 30-day mortality. The number of organ failures, sequential (sepsis-related) organ failure assessment (SOFA) score, and 30-day mortality were compared according to bio-ADM quartiles. RESULTS: Bio-ADM concentration was significantly higher in patients with septic shock, vasopressor use, and non-survivors than in patients with solitary sepsis, no vasopressor use, and survivors, respectively (all P<0.0001). Bio-ADM quartiles were associated with the number of organ failures (P<0.0001), as well as SOFA cardiovascular, renal, coagulation, and liver subscores (all P<0.05). The 30-day mortality rate showed a stepwise increase in each bio-ADM quartile (all P<0.0001). Bio-ADM concentration and SOFA score equally predicted the 30-day mortality (area under the curve: 0.827 vs 0.830). CONCLUSIONS: Bio-ADM could serve as a useful and objective biomarker to predict severity, organ failure, and 30-day mortality in septic patients

Propulsion system ignition overpressure for the Space Shuttle

Liquid and solid rocket motor propulsion systems create an overpressure wave during ignition, caused by the accelerating gas particles pushing against or displacing the air contained in the launch pad or launch facility and by the afterburning of the fuel-rich gases. This wave behaves as a blast or shock wave characterized by a positive triangular-shaped first pulse and a negative half-sine wave second pulse. The pulse travels up the space vehicle and has the potential of either overloading individual elements or exciting overall vehicle dynamics. The latter effect results from the phasing difference of the wave from one side of the vehicle to the other. This overpressure phasing, or delta P environment, because of its frequency content as well as amplitude, becomes a design driver for certain panels (e.g., thermal shields) and payloads for the Space Shuttle. The history of overpressure effects on the Space Shuttle, the basic overpressure phenomenon, Space Shuttle overpressure environment, scale model overpressure testing, and techniques for suppressing the overpressure environments are considered

Midrapidity phi production in Au+Au collisions at sqrt[sNN]=130 GeV

We present the first measurement of midrapidity vector meson phi production in Au+Au collisions at RHIC (sqrt[sNN]=130 GeV) from the STAR detector. For the 11% highest multiplicity collisions, the slope parameter from an exponential fit to the transverse mass distribution is T=379±50(stat)±45(syst) MeV, the yield dN/dy=5.73±0.37(stat)±0.69(syst) per event, and the ratio N phi /Nh- is found to be 0.021±0.001(stat)±0.004(syst). The measured ratio N phi /Nh- and T for the phi meson at midrapidity do not change for the selected multiplicity bins.alle Autoren: C. Adler11, Z. Ahammed23, C. Allgower12, J. Amonett14, B. D. Anderson14, M. Anderson5, G. S. Averichev9, J. Balewski12, O. Barannikova9,23, L. S. Barnby14, J. Baudot13, S. Bekele20, V. V. Belaga9, R. Bellwied30, J. Berger11, H. Bichsel29, L. C. Bland12, C. O. Blyth3, B. E. Bonner24, A. Boucham26, A. Brandin18, R. V. Cadman1, H. Caines20, M. Calderón de la Barca Sánchez31, A. Cardenas23, J. Carroll15, J. Castillo26, M. Castro30, D. Cebra5, S. Chattopadhyay30, M. L. Chen2, Y. Chen6, S. P. Chernenko9, M. Cherney8, A. Chikanian31, B. Choi27, W. Christie2, J. P. Coffin13, T. M. Cormier30, J. G. Cramer29, H. J. Crawford4, M. DeMello24, W. S. Deng14, A. A. Derevschikov22, L. Didenko2, J. E. Draper5, V. B. Dunin9, J. C. Dunlop31, V. Eckardt16, L. G. Efimov9, V. Emelianov18, J. Engelage4, G. Eppley24, B. Erazmus26, P. Fachini25, V. Faine2, E. Finch31, Y. Fisyak2, D. Flierl11, K. J. Foley2, J. Fu15, N. Gagunashvili9, J. Gans31, L. Gaudichet26, M. Germain13, F. Geurts24, V. Ghazikhanian6, J. Grabski28, O. Grachov30, D. Greiner15, V. Grigoriev18, M. Guedon13, E. Gushin18, T. J. Hallman2, D. Hardtke15, J. W. Harris31, M. Heffner5, S. Heppelmann21, T. Herston23, B. Hippolyte13, A. Hirsch23, E. Hjort15, G. W. Hoffmann27, M. Horsley31, H. Z. Huang6, T. J. Humanic20, H. Hümmler16, G. Igo6, A. Ishihara27, Yu. I. Ivanshin10, P. Jacobs15, W. W. Jacobs12, M. Janik28, I. Johnson15, P. G. Jones3, E. Judd4, M. Kaneta15, M. Kaplan7, D. Keane14, A. Kisiel28, J. Klay5, S. R. Klein15, A. Klyachko12, A. S. Konstantinov22, L. Kotchenda18, A. D. Kovalenko9, M. Kramer19, P. Kravtsov18, K. Krueger1, C. Kuhn13, A. I. Kulikov9, G. J. Kunde31, C. L. Kunz7, R. Kh. Kutuev10, A. A. Kuznetsov9, L. Lakehal-Ayat26, J. Lamas-Valverde24, M. A. C. Lamont3, J. M. Landgraf2, S. Lange11, C. P. Lansdell27, B. Lasiuk31, F. Laue2, A. Lebedev2, T. LeCompte1, R. Lednický9, V. M. Leontiev22, M. J. LeVine2, Q. Li30, Q. Li15, S. J. Lindenbaum19, M. A. Lisa20, T. Ljubicic2, W. J. Llope24, G. LoCurto16, H. Long6, R. S. Longacre2, M. Lopez-Noriega20, W. A. Love2, D. Lynn2, R. Majka31, S. Margetis14, L. Martin26, J. Marx15, H. S. Matis15, Yu. A. Matulenko22, T. S. McShane8, F. Meissner15, Yu. Melnick22, A. Meschanin22, M. Messer2, M. L. Miller31, Z. Milosevich7, N. G. Minaev22, J. Mitchell24, V. A. Moiseenko10, D. Moltz15, C. F. Moore27, V. Morozov15, M. M. de Moura30, M. G. Munhoz25, G. S. Mutchler24, J. M. Nelson3, P. Nevski2, V. A. Nikitin10, L. V. Nogach22, B. Norman14, S. B. Nurushev22, G. Odyniec15, A. Ogawa21, V. Okorokov18, M. Oldenburg16, D. Olson15, G. Paic20, S. U. Pandey30, Y. Panebratsev9, S. Y. Panitkin2, A. I. Pavlinov30, T. Pawlak28, V. Perevoztchikov2, W. Peryt28, V. A. Petrov10, E. Platner24, J. Pluta28, N. Porile23, J. Porter2, A. M. Poskanzer15, E. Potrebenikova9, D. Prindle29, C. Pruneau30, S. Radomski28, G. Rai15, O. Ravel26, R. L. Ray27, S. V. Razin9,12, D. Reichhold8, J. G. Reid29, F. Retiere15, A. Ridiger18, H. G. Ritter15, J. B. Roberts24, O. V. Rogachevski9, J. L. Romero5, C. Roy26, D. Russ7, V. Rykov30, I. Sakrejda15, J. Sandweiss31, A. C. Saulys2, I. Savin10, J. Schambach27, R. P. Scharenberg23, N. Schmitz16, L. S. Schroeder15, A. Schüttauf16, K. Schweda15, J. Seger8, D. Seliverstov18, P. Seyboth16, E. Shahaliev9, K. E. Shestermanov22, S. S. Shimanskii9, V. S. Shvetcov10, G. Skoro9, N. Smirnov31, R. Snellings15, J. Sowinski12, H. M. Spinka1, B. Srivastava23, E. J. Stephenson12, R. Stock11, A. Stolpovsky30, M. Strikhanov18, B. Stringfellow23, C. Struck11, A. A. P. Suaide30, E. Sugarbaker20, C. Suire13, M. Sumbera9, T. J. M. Symons15, A. Szanto de Toledo25, P. Szarwas28, J. Takahashi25, A. H. Tang14, J. H. Thomas15, V. Tikhomirov18, T. A. Trainor29, S. Trentalange6, M. Tokarev9, M. B. Tonjes17, V. Trofimov18, O. Tsai6, K. Turner2, T. Ullrich2, D. G. Underwood1, G. Van Buren2, A. M. VanderMolen17, A. Vanyashin15, I. M. Vasilevski10, A. N. Vasiliev22, S. E. Vigdor12, S. A. Voloshin30, F. Wang23, H. Ward27, J. W. Watson14, R. Wells20, T. Wenaus2, G. D. Westfall17, C. Whitten, Jr.6, H. Wieman15, R. Willson20, S. W. Wissink12, R. Witt14, N. Xu15, Z. Xu31, A. E. Yakutin22, E. Yamamoto6, J. Yang6, P. Yepes24, A. Yokosawa1, V. I. Yurevich9, Y. V. Zanevski9, I. Zborovský9, H. Zhang31, W. M. Zhang14, R. Zoulkarneev10, and A. N. Zubarev

Graphene zigzag ribbons, square lattice models and quantum spin chains

We present an extended study of finite-width zigzag graphene ribbons (ZGRs) based on a tight-binding model with hard-wall boundary conditions. We provide an exact analytic solution that clarifies the origin of the predicted width dependence on the conductance through junctions of ribbons with different widths. An analysis of the obtained solutions suggests a new description of ZGRs in terms of coupled chains. We pursue these ideas further by introducing a mapping between the ZGR model and the Hamiltonian for N-coupled quantum chains as described in terms of 2N Majorana fermions. The proposed mapping preserves the dependence of ribbon properties on its width thus rendering metallic ribbons for N odd and zero-gap semiconductor ribbons for N even. Furthermore, it reveals a close connection between the low-energy properties of the ZGR model and a continuous family of square lattice model Hamiltonians with similar width-dependent properties that includes the $\pi-$flux and the trivial square lattice models. As a further extension, we show that this new description makes it possible to identify various aspects of the physics of graphene ribbons with those predicted by models of quantum spin chains (QSCs)

d-bar and 3He-bar production in sqrt[sNN] = 130 GeV Au+Au collisions

The first measurements of light antinucleus production in Au+Au collisions at the Relativistic Heavy-Ion Collider are reported. The observed production rates for d-bar and 3He-bar are much larger than in lower energy nucleus-nucleus collisions. A coalescence model analysis of the yields indicates that there is little or no increase in the antinucleon freeze-out volume compared to collisions at CERN SPS energy. These analyses also indicate that the 3He-bar freeze-out volume is smaller than the d-bar freeze-out volume.alle Autoren: C. Adler11, Z. Ahammed23, C. Allgower12, J. Amonett14, B. D. Anderson14, M. Anderson5, G. S. Averichev9, J. Balewski12, O. Barannikova9,23, L. S. Barnby14, J. Baudot13, S. Bekele20, V. V. Belaga9, R. Bellwied30, J. Berger11, H. Bichsel29, L. C. Bland12, C. O. Blyth3, B. E. Bonner24, A. Boucham26, A. Brandin18, R. V. Cadman1, H. Caines20, M. Calderón de la Barca Sánchez31, A. Cardenas23, J. Carroll15, J. Castillo26, M. Castro30, D. Cebra5, S. Chattopadhyay30, M. L. Chen2, Y. Chen6, S. P. Chernenko9, M. Cherney8, A. Chikanian31, B. Choi27, W. Christie2, J. P. Coffin13, T. M. Cormier30, J. G. Cramer29, H. J. Crawford4, M. DeMello24, W. S. Deng14, A. A. Derevschikov22, L. Didenko2, J. E. Draper5, V. B. Dunin9, J. C. Dunlop31, V. Eckardt16, L. G. Efimov9, V. Emelianov18, J. Engelage4, G. Eppley24, B. Erazmus26, P. Fachini25, V. Faine2, E. Finch31, Y. Fisyak2, D. Flierl11, K. J. Foley2, J. Fu15, N. Gagunashvili9, J. Gans31, L. Gaudichet26, M. Germain13, F. Geurts24, V. Ghazikhanian6, J. Grabski28, O. Grachov30, D. Greiner15, V. Grigoriev18, M. Guedon13, E. Gushin18, T. J. Hallman2, D. Hardtke15, J. W. Harris31, M. Heffner5, S. Heppelmann21, T. Herston23, B. Hippolyte13, A. Hirsch23, E. Hjort15, G. W. Hoffmann27, M. Horsley31, H. Z. Huang6, T. J. Humanic20, H. Hümmler16, G. Igo6, A. Ishihara27, Yu. I. Ivanshin10, P. Jacobs15, W. W. Jacobs12, M. Janik28, I. Johnson15, P. G. Jones3, E. Judd4, M. Kaneta15, M. Kaplan7, D. Keane14, A. Kisiel28, J. Klay5, S. R. Klein15, A. Klyachko12, A. S. Konstantinov22, L. Kotchenda18, A. D. Kovalenko9, M. Kramer19, P. Kravtsov18, K. Krueger1, C. Kuhn13, A. I. Kulikov9, G. J. Kunde31, C. L. Kunz7, R. Kh. Kutuev10, A. A. Kuznetsov9, L. Lakehal-Ayat26, J. Lamas-Valverde24, M. A. C. Lamont3, J. M. Landgraf2, S. Lange11, C. P. Lansdell27, B. Lasiuk31, F. Laue2, A. Lebedev2, T. LeCompte1, R. Lednický9, V. M. Leontiev22, M. J. LeVine2, Q. Li30, Q. Li15, S. J. Lindenbaum19, M. A. Lisa20, T. Ljubicic2, W. J. Llope24, G. LoCurto16, H. Long6, R. S. Longacre2, M. Lopez-Noriega20, W. A. Love2, D. Lynn2, R. Majka31, S. Margetis14, L. Martin26, J. Marx15, H. S. Matis15, Yu. A. Matulenko22, T. S. McShane8, F. Meissner15, Yu. Melnick22, A. Meschanin22, M. Messer2, M. L. Miller31, Z. Milosevich7, N. G. Minaev22, J. Mitchell24, V. A. Moiseenko10, D. Moltz15, C. F. Moore27, V. Morozov15, M. M. de Moura30, M. G. Munhoz25, G. S. Mutchler24, J. M. Nelson3, P. Nevski2, V. A. Nikitin10, L. V. Nogach22, B. Norman14, S. B. Nurushev22, G. Odyniec15, A. Ogawa21, V. Okorokov18, M. Oldenburg16, D. Olson15, G. Paic20, S. U. Pandey30, Y. Panebratsev9, S. Y. Panitkin2, A. I. Pavlinov30, T. Pawlak28, V. Perevoztchikov2, W. Peryt28, V. A. Petrov10, E. Platner24, J. Pluta28, N. Porile23, J. Porter2, A. M. Poskanzer15, E. Potrebenikova9, D. Prindle29, C. Pruneau30, S. Radomski28, G. Rai15, O. Ravel26, R. L. Ray27, S. V. Razin9,12, D. Reichhold8, J. G. Reid29, F. Retiere15, A. Ridiger18, H. G. Ritter15, J. B. Roberts24, O. V. Rogachevski9, J. L. Romero5, C. Roy26, D. Russ7, V. Rykov30, I. Sakrejda15, J. Sandweiss31, A. C. Saulys2, I. Savin10, J. Schambach27, R. P. Scharenberg23, N. Schmitz16, L. S. Schroeder15, A. Schüttauf16, K. Schweda15, J. Seger8, D. Seliverstov18, P. Seyboth16, E. Shahaliev9, K. E. Shestermanov22, S. S. Shimanskii9, V. S. Shvetcov10, G. Skoro9, N. Smirnov31, R. Snellings15, J. Sowinski12, H. M. Spinka1, B. Srivastava23, E. J. Stephenson12, R. Stock11, A. Stolpovsky30, M. Strikhanov18, B. Stringfellow23, C. Struck11, A. A. P. Suaide30, E. Sugarbaker20, C. Suire13, M. Sumbera9, T. J. M. Symons15, A. Szanto de Toledo25, P. Szarwas28, J. Takahashi25, A. H. Tang14, J. H. Thomas15, V. Tikhomirov18, T. A. Trainor29, S. Trentalange6, M. Tokarev9, M. B. Tonjes17, V. Trofimov18, O. Tsai6, K. Turner2, T. Ullrich2, D. G. Underwood1, G. Van Buren2, A. M. VanderMolen17, A. Vanyashin15, I. M. Vasilevski10, A. N. Vasiliev22, S. E. Vigdor12, S. A. Voloshin30, F. Wang23, H. Ward27, J. W. Watson14, R. Wells20, T. Wenaus2, G. D. Westfall17, C. Whitten, Jr.6, H. Wieman15, R. Willson20, S. W. Wissink12, R. Witt14, N. Xu15, Z. Xu31, A. E. Yakutin22, E. Yamamoto6, J. Yang6, P. Yepes24, A. Yokosawa1, V. I. Yurevich9, Y. V. Zanevski9, I. Zborovský9, H. Zhang31, W. M. Zhang14, R. Zoulkarneev10, and A. N. Zubarev

Measurement of inclusive antiprotons from Au+Au collisions at sqrt[sNN] = 130 GeVd-bar and 3He-bar production in sqrt[sNN] = 130 GeV Au+Au collisions

We report the first measurement of inclusive antiproton production at midrapidity in Au+Au collisions at sqrt[sNN] = 130 GeV by the STAR experiment at RHIC. The antiproton transverse mass distributions in the measured transverse momentum range of 0.25<pperp<0.95 GeV/c are found to fall less steeply for more central collisions. The extrapolated antiproton rapidity density is found to scale approximately with the negative hadron multiplicity density.alle Autoren: C. Adler11, Z. Ahammed23, C. Allgower12, J. Amonett14, B. D. Anderson14, M. Anderson5, G. S. Averichev9, J. Balewski12, O. Barannikova9,23, L. S. Barnby14, J. Baudot13, S. Bekele20, V. V. Belaga9, R. Bellwied31, J. Berger11, H. Bichsel30, L. C. Bland12, C. O. Blyth3, B. E. Bonner24, A. Boucham26, A. Brandin18, R. V. Cadman1, H. Caines20, M. Calderón de la Barca Sánchez33, A. Cardenas23, J. Carroll15, J. Castillo26, M. Castro31, D. Cebra5, S. Chattopadhyay31, M. L. Chen2, Y. Chen6, S. P. Chernenko9, M. Cherney8, A. Chikanian33, B. Choi28, W. Christie2, J. P. Coffin13, T. M. Cormier31, J. G. Cramer30, H. J. Crawford4, M. DeMello24, W. S. Deng14, A. A. Derevschikov22, L. Didenko2, J. E. Draper5, V. B. Dunin9, J. C. Dunlop33, V. Eckardt16, L. G. Efimov9, V. Emelianov18, J. Engelage4, G. Eppley24, B. Erazmus26, P. Fachini25, V. Faine2, K. Filimonov15, E. Finch33, Y. Fisyak2, D. Flierl11, K. J. Foley2, J. Fu15, C. A. Gagliardi27, N. Gagunashvili9, J. Gans33, L. Gaudichet26, M. Germain13, F. Geurts24, V. Ghazikhanian6, J. Grabski29, O. Grachov31, V. Grigoriev18, M. Guedon13, E. Gushin18, T. J. Hallman2, D. Hardtke15, J. W. Harris33, M. Heffner5, S. Heppelmann21, T. Herston23, B. Hippolyte13, A. Hirsch23, E. Hjort15, G. W. Hoffmann28, M. Horsley33, H. Z. Huang6, T. J. Humanic20, H. Hümmler16, G. Igo6, A. Ishihara28, Yu. I. Ivanshin10, P. Jacobs15, W. W. Jacobs12, M. Janik29, I. Johnson15, P. G. Jones3, E. Judd4, M. Kaneta15, M. Kaplan7, D. Keane14, A. Kisiel29, J. Klay15, S. R. Klein15, A. Klyachko12, A. S. Konstantinov22, L. Kotchenda18, A. D. Kovalenko9, M. Kramer19, P. Kravtsov18, K. Krueger1, C. Kuhn13, A. I. Kulikov9, G. J. Kunde33, C. L. Kunz7, R. Kh. Kutuev10, A. A. Kuznetsov9, L. Lakehal-Ayat26, J. Lamas-Valverde24, M. A. C. Lamont3, J. M. Landgraf2, S. Lange11, C. P. Lansdell28, B. Lasiuk33, F. Laue2, A. Lebedev2, R. Lednický9, V. M. Leontiev22, M. J. LeVine2, Q. Li31, S. J. Lindenbaum19, M. A. Lisa20, F. Liu32, L. Liu32, Z. Liu32, Q. J. Liu30, T. Ljubicic2, W. J. Llope24, G. LoCurto16, H. Long6, R. S. Longacre2, M. Lopez-Noriega20, W. A. Love2, D. Lynn2, R. Majka33, S. Margetis14, L. Martin26, J. Marx15, H. S. Matis15, Yu. A. Matulenko22, T. S. McShane8, F. Meissner15, Yu. Melnick22, A. Meschanin22, M. Messer2, M. L. Miller33, Z. Milosevich7, N. G. Minaev22, J. Mitchell24, V. A. Moiseenko10, C. F. Moore28, V. Morozov15, M. M. de Moura31, M. G. Munhoz25, G. S. Mutchler24, J. M. Nelson3, P. Nevski2, V. A. Nikitin10, L. V. Nogach22, B. Norman14, S. B. Nurushev22, G. Odyniec15, A. Ogawa21, V. Okorokov18, M. Oldenburg16, D. Olson15, G. Paic20, S. U. Pandey31, Y. Panebratsev9, S. Y. Panitkin2, A. I. Pavlinov31, T. Pawlak29, V. Perevoztchikov2, W. Peryt29, V. A. Petrov10, E. Platner24, J. Pluta29, N. Porile23, J. Porter2, A. M. Poskanzer15, E. Potrebenikova9, D. Prindle30, C. Pruneau31, S. Radomski29, G. Rai15, O. Ravel26, R. L. Ray28, S. V. Razin9,12, D. Reichhold8, J. G. Reid30, F. Retiere15, A. Ridiger18, H. G. Ritter15, J. B. Roberts24, O. V. Rogachevski9, J. L. Romero5, C. Roy26, V. Rykov31, I. Sakrejda15, J. Sandweiss33, A. C. Saulys2, I. Savin10, J. Schambach28, R. P. Scharenberg23, N. Schmitz16, L. S. Schroeder15, A. Schüttauf16, K. Schweda15, J. Seger8, D. Seliverstov18, P. Seyboth16, E. Shahaliev9, K. E. Shestermanov22, S. S. Shimanskii9, V. S. Shvetcov10, G. Skoro9, N. Smirnov33, R. Snellings15, J. Sowinski12, H. M. Spinka1, B. Srivastava23, E. J. Stephenson12, R. Stock11, A. Stolpovsky31, M. Strikhanov18, B. Stringfellow23, C. Struck11, A. A. P. Suaide31, E. Sugarbaker20, C. Suire13, M. Sumbera9, T. J. M. Symons15, A. Szanto de Toledo25, P. Szarwas29, J. Takahashi25, A. H. Tang14, J. H. Thomas15, M. Thompson3, V. Tikhomirov18, T. A. Trainor30, S. Trentalange6, R. E. Tribble27, M. Tokarev9, M. B. Tonjes17, V. Trofimov18, O. Tsai6, K. Turner2, T. Ullrich2, D. G. Underwood1, G. Van Buren2, A. M. VanderMolen17, A. Vanyashin15, I. M. Vasilevski10, A. N. Vasiliev22, S. E. Vigdor12, S. A. Voloshin31, F. Wang23, H. Ward28, J. W. Watson14, R. Wells20, T. Wenaus2, G. D. Westfall17, C. Whitten, Jr.6, H. Wieman15, R. Willson20, S. W. Wissink12, R. Witt14, N. Xu15, Z. Xu2, A. E. Yakutin22, E. Yamamoto15, J. Yang6, P. Yepes24, V. I. Yurevich9, Y. V. Zanevski9, I. Zborovský9, H. Zhang33, W. M. Zhang14, R. Zoulkarneev10, and A. N. Zubarev

Excitated state properties of 20-chloro-chlorophyll a

The excited-state and lasing properties of 20-chloro-chlorophyll a in ether solution were compared to those of chlorophyll a. Desactivation parameters and cross-sections were obtained from non-linear absorption spectroscopy in combination with a physico-mathematical methods package. The Cl substituent at C-20 (1) increases both intersystem crossing and internal conversion, (2) produces a blue-shift of the S1 absorption spectrum, and (3) leads to pronounced photochemistry