643 research outputs found
Aluminium Nanowires: Influence of Work Hardening on Conductance Histograms
Conductance histograms of work-hardened Al show a series up to 11 equidistant
peaks with a period of 1.15 +/- 0.02 of the quantum conductance unit G_0 =
2e^2/h. Assuming the peaks originate from atomic discreteness, this agrees with
the value of 1.16 G_0 per atom obtained in numerical calculations by Hasmy et
al.Comment: 4 pages, 4 figure
Conductance of Pd-H nanojunctions
Results of an experimental study of palladium nanojunctions in hydrogen
environment are presented. Two new hydrogen-related atomic configurations are
found, which have a conductances of ~0.5 and ~1 quantum unit (2e^2/h). Phonon
spectrum measurements demonstrate that these configurations are situated
between electrodes containing dissolved hydrogen. The crucial differences
compared to the previously studied Pt-H_2 junctions, and the possible
microscopic realizations of the new configurations in palladium-hydrogen
atomic-sized contacts are discussed.Comment: 4 pages, 4 figure
Network theory approach for data evaluation in the dynamic force spectroscopy of biomolecular interactions
Investigations of molecular bonds between single molecules and molecular
complexes by the dynamic force spectroscopy are subject to large fluctuations
at nanoscale and possible other aspecific binding, which mask the experimental
output. Big efforts are devoted to develop methods for effective selection of
the relevant experimental data, before taking the quantitative analysis of bond
parameters. Here we present a methodology which is based on the application of
graph theory. The force-distance curves corresponding to repeated pulling
events are mapped onto their correlation network (mathematical graph). On these
graphs the groups of similar curves appear as topological modules, which are
identified using the spectral analysis of graphs. We demonstrate the approach
by analyzing a large ensemble of the force-distance curves measured on:
ssDNA-ssDNA, peptide-RNA (system from HIV1), and peptide-Au surface. Within our
data sets the methodology systematically separates subgroups of curves which
are related to different intermolecular interactions and to spatial
arrangements in which the molecules are brought together and/or pulling speeds.
This demonstrates the sensitivity of the method to the spatial degrees of
freedom, suggesting potential applications in the case of large molecular
complexes and situations with multiple binding sites
Correlative Microscopy of Morphology and Luminescence of Cu porphyrin aggregates
Transfer of energy and information through molecule aggregates requires as
one important building block anisotropic, cable-like structures. Knowledge on
the spatial correlation of luminescence and morphology represents a
prerequisite in the understanding of internal processes and will be important
for architecting suitable landscapes. In this context we study the morphology,
fluorescence and phosphorescence of molecule aggregate structures on surfaces
in a spatially correlative way. We consider as two morphologies, lengthy
strands and isotropic islands. It turns out that phosphorescence is quite
strong compared to fluorescence and the spatial variation of the observed
intensities is largely in line with the amount of dye. However in proportion,
the strands exhibit more fluorescence than the isotropic islands suggesting
weaker non-radiative channels. The ratio fluorescence to phosphorescence
appears to be correlated with the degree of aggregation or internal order. The
heights at which luminescence saturates is explained in the context of
attenuation and emission multireflection, inside the dye. This is supported by
correlative photoemission electron microscopy which is more sensitive to the
surface region. The lengthy structures exhibit a pronounced polarization
dependence of the luminescence with a relative dichroism up to about 60%,
revealing substantial perpendicular orientation preference of the molecules
with respect to the substrate and parallel with respect to the strands
Atomic size oscillations in conductance histograms for gold nanowires and the influence of work hardening
Nanowires of different nature have been shown to self-assemble as a function
of stress at the contact between two macroscopic metallic leads. Here we
demonstrate for gold wires that the balance between various metastable nanowire
configurations is influenced by the microstructure of the starting materials
and we discover a new set of periodic structures, which we interpret as due to
the atomic discreteness of the contact size for the three principal crystal
orientations.Comment: This version corrects an error in attributing the three observed
periods, and includes a comparison with recent model calculation
Out-of-plane magnetic domain structure in a thin film of La0.67Sr0.33MnO3 on SrTiO3 (001) observed by magnetic force microscopy
The room temperature out-of-plane magnetization of epitaxial thin films of La0.67Sr0.33MnO3 on SrTiO3 (001) has been investigated with magnetic force microscopy, using magnetic tips with very small coercivity, relative to the film. A clear magnetic pattern in the form of a checkerboard, with domain dimensions of a few hundred nanometers, was found for the thin, coherently strained films, which is approximately aligned along the maximum strain [110] and [1[overline 1]0] directions in the film. With increasing in-plane applied magnetic field, the magnetic contrast reduces, reflecting the rotation of the magnetization vector into the plane of the film. This process is reversible with the field. The out-of-plane magnetic pattern is not sensitive to rotation of the in-plane field. We attribute the observed out-of-plane magnetization component to an out-of-plane magnetic anisotropy, which is a remainder of the [111] magnetic easy axis in bulk La0.67Sr0.33MnO3 single crystal
Strain in epitaxial MnSi films on Si(111) in the thick film limit studied by polarization-dependent extended x-ray absorption fine structure
We report a study of the strain state of epitaxial MnSi films on Si(111)
substrates in the thick film limit (100-500~\AA) as a function of film
thickness using polarization-dependent extended x-ray absorption fine structure
(EXAFS). All films investigated are phase-pure and of high quality with a sharp
interface between MnSi and Si. The investigated MnSi films are in a thickness
regime where the magnetic transition temperature assumes a
thickness-independent enhanced value of 43~K as compared with that of
bulk MnSi, where . A detailed refinement of
the EXAFS data reveals that the Mn positions are unchanged, whereas the Si
positions vary along the out-of-plane [111]-direction, alternating in
orientation from unit cell to unit cell. Thus, for thick MnSi films, the unit
cell volume is essentially that of bulk MnSi --- except in the vicinity of the
interface with the Si substrate (thin film limit). In view of the enhanced
magnetic transition temperature we conclude that the mere presence of the
interface, and its specific characteristics, strongly affects the magnetic
properties of the entire MnSi film, even far from the interface. Our analysis
provides invaluable information about the local strain at the MnSi/Si(111)
interface. The presented methodology of polarization dependent EXAFS can also
be employed to investigate the local structure of other interesting interfaces.Comment: 11 pages, 10 figure
High resolution characterisation of microstructural evolution in RbFeSe crystals on annealing
The superconducting and magnetic properties of phase-separated
AFeSe compounds are known to depend on post-growth heat
treatments and cooling profiles. This paper focusses on the evolution of
microstructure on annealing, and how this influences the superconducting
properties of RbFeSe crystals. We find that the minority phase in
the as-grown crystal has increased unit cell anisotropy (c/a ratio), reduced Rb
content and increased Fe content compared to the matrix. The microstructure is
rather complex, with two-phase mesoscopic plate-shaped features aligned along
{113} habit planes. The minority phase are strongly facetted on the {113}
planes, which we have shown to be driven by minimising the volume strain energy
introduced as a result of the phase transformation. Annealing at 488K results
in coarsening of the mesoscopic plate-shaped features and the formation of a
third distinct phase. The subtle differences in structure and chemistry of the
minority phase(s) in the crystals are thought to be responsible for changes in
the superconducting transition temperature. In addition, scanning photoemission
microscopy has clearly shown that the electronic structure of the minority
phase has a higher occupied density of states of the low binding energy Fe3d
orbitals, characteristic of crystals that exhibit superconductivity. This
demonstrates a clear correlation between the Fe-vacancy-free phase with high
c/a ratio and the electronic structure characteristics of the superconducting
phase.Comment: 6 figures v2 is exactly the same as v1. The typesetting errors in the
abstract have been correcte
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