Modeling and Testing of the Viscoelastic Properties of a Graphite Nanoplatelet/Epoxy Composite

In order to facilitate the interpretation of experimental data, a micromechanical modeling procedure is developed to predict the viscoelastic properties of a graphite nanoplatelet/epoxy composite as a function of volume fraction and nanoplatelet diameter. The predicted storage and loss moduli for the composite are compared to measured values from the same material using three test methods; Dynamical Mechanical Analysis, nanoindentation, and quasi-static tensile tests. In most cases, the model and experiments indicate that for increasing volume fractions of nanoplatelets, both the storage and loss moduli increase. Also, the results indicate that for nanoplatelet sizes above 15 microns, nanoindentation is capable of measuring properties of individual constituents of a composite system. Comparison of the predicted values to the measured data helps illustrate the relative similarities and differences between the bulk and local measurement techniques

Wetting simulations of high-performance polymer resins on carbon surfaces as a function of temperature using molecular dynamics

Resin/reinforcement wetting is a key parameter in the manufacturing of carbon nanotube (CNT)-based composite materials. Determining the contact angle between combinations of liquid resin and reinforcement surfaces is a common method for quantifying wettability. As experimental measurement of contact angle can be difficult when screening multiple high-performance resins with CNT materials such as CNT bundles or yarns, computational approaches are necessary to fa-cilitate CNT composite material design. A molecular dynamics simulation method is developed to predict the contact angle of high-performance polymer resins on CNT surfaces dominated by aromatic carbon, aliphatic carbon, or a mixture thereof (amorphous carbon). Several resin systems are simulated and compared. The results indicate that the monomer chain length, chemical groups on the monomer, and simulation temperature have a significant impact on the predicted contact angle values on the CNT surface. Difunctional epoxy and cyanate ester resins show the overall highest levels of wettability, regardless of the aromatic/aliphatic nature of the CNT material surface. Tetra-functional epoxy demonstrates excellent wettability on aliphatic-dominated surfaces at elevated temperatures. Bismaleimide and benzoxazine resins show intermediate levels of wetting, while typ-ical molecular weights of polyether ether ketone demonstrate poor wetting on the CNT surfaces

Boron Nitride Nanotubes: Force Field Parameterization, Epoxy Interactions, and Comparison with Carbon Nanotubes for High-Performance Composite Materials

Boron nitride nanotubes (BNNTs) are a very promising reinforcement for future high-performance composites because of their excellent thermo-mechanical properties. To take full advantage of BNNTs in composite materials, it is necessary to have a comprehensive understanding of the wetting characteristics of various high-performance resins. Molecular dynamics (MD) simulations provide an accurate and efficient approach to establish the contact angle values of engineering polymers on reinforcement surfaces, which offers a measure for the interaction between the polymer and reinforcement. In this research, MD simulations and experiments are used to determine the wettability of various epoxy systems on BNNT surfaces. The reactive interface force field (IFF-R) is parameterized and utilized in the simulations to accurately describe the interaction of the epoxy monomers with the BNNT surface. The effect of the epoxy monomer type, hardener type, local atomic charges, and temperature on the contact angle is established. The results show that contact angles decrease with increases in temperature for all the epoxy/hardener systems. The bisphenol-A-based epoxy system demonstrates better wettability with the BNNT surface than the bisphenol-F based epoxy system. Furthermore, the MD predictions demonstrate that these observations are validated with experimental results, wherein the same contact angle trends are observed for macroscopic epoxy drops on nonwoven nanotube papers. As wetting properties drive the resin infusion in the reinforcement materials, these results are important for the future manufacturing of high-quality BNNT/epoxy nanocomposites for high-performance applications such as aerospace and aeronautical vehicles

The Wilkinson Microwave Anisotropy Probe (WMAP) Source Catalog

We present the list of point sources found in the WMAP 5-year maps. The technique used in the first-year and three-year analysis now finds 390 point sources, and the five-year source catalog is complete for regions of the sky away from the galactic plane to a 2 Jy limit, with SNR > 4.7 in all bands in the least covered parts of the sky. The noise at high frequencies is still mainly radiometer noise, but at low frequencies the CMB anisotropy is the largest uncertainty. A separate search of CMB-free V-W maps finds 99 sources of which all but one can be identified with known radio sources. The sources seen by WMAP are not strongly polarized. Many of the WMAP sources show significant variability from year to year, with more than a 2:1 range between the minimum and maximum fluxes.Comment: 31 pages Latex with 4 embedded figures. Version accepted by the ApJ Supplement

Nine-Year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Cosmological Parameter Results

We present cosmological parameter constraints based on the final nine-year WMAP data, in conjunction with additional cosmological data sets. The WMAP data alone, and in combination, continue to be remarkably well fit by a six-parameter LCDM model. When WMAP data are combined with measurements of the high-l CMB anisotropy, the BAO scale, and the Hubble constant, the densities, Omegabh2, Omegach2, and Omega_L, are each determined to a precision of ~1.5%. The amplitude of the primordial spectrum is measured to within 3%, and there is now evidence for a tilt in the primordial spectrum at the 5sigma level, confirming the first detection of tilt based on the five-year WMAP data. At the end of the WMAP mission, the nine-year data decrease the allowable volume of the six-dimensional LCDM parameter space by a factor of 68,000 relative to pre-WMAP measurements. We investigate a number of data combinations and show that their LCDM parameter fits are consistent. New limits on deviations from the six-parameter model are presented, for example: the fractional contribution of tensor modes is limited to r<0.13 (95% CL); the spatial curvature parameter is limited to -0.0027 (+0.0039/-0.0038); the summed mass of neutrinos is <0.44 eV (95% CL); and the number of relativistic species is found to be 3.84+/-0.40 when the full data are analyzed. The joint constraint on Neff and the primordial helium abundance agrees with the prediction of standard Big Bang nucleosynthesis. We compare recent PLANCK measurements of the Sunyaev-Zel'dovich effect with our seven-year measurements, and show their mutual agreement. Our analysis of the polarization pattern around temperature extrema is updated. This confirms a fundamental prediction of the standard cosmological model and provides a striking illustration of acoustic oscillations and adiabatic initial conditions in the early universe.Comment: 32 pages, 12 figures, v3: Version accepted to Astrophysical Journal Supplement Series. Includes improvements in response to referee and community; corrected 3 entries in Table 10, (w0 & wa model). See the Legacy Archive for Microwave Background Data Analysis (LAMBDA): http://lambda.gsfc.nasa.gov/product/map/current/ for further detai

Five-Year Wilkinson Microwave Anisotropy Probe Observations: Source Catalog

We present the list of point sources found in the Wilkinson Microwave Anisotropy Probe (WMAP) five-year maps. The technique used in the first-year and three-year analyses now finds 390 point sources, and the five-year source catalog is complete for regions of the sky away from the Galactic plane to a 2 Jy limit, with SNR > 4.7 in all bands in the least covered parts of the sky. The noise at high frequencies is still mainly radiometer noise, but at low frequencies the cosmic microwave background (CMB) anisotropy is the largest uncertainty. A separate search of CMB-free V-W maps finds 99 sources of which all but one can be identified with known radio sources. The sources seen by WMAP are not strongly polarized. Many of the WMAP sources show significant variability from year to year, with more than a 2: 1 range between the minimum and maximum fluxes.NASA NNG05GE76G, NNX07AL75G S01, LTSA03-000-0090, ATPNNG04GK55G, ADP03-0000-092Astronom

Seven-year Wilkinson Microwave Anisotropy Probe (WMAP) Observations: Galactic Foreground Emission

We present updated estimates of Galactic foreground emission using seven years of WMAP data. Using the power spectrum of differences between multi-frequency template-cleaned maps, we find no evidence for foreground contamination outside of the updated (KQ85y7) foreground mask.We place a 15μK upper bound on rms foreground contamination in the cleaned maps used for cosmological analysis. Further, the cleaning process requires only three power-law foregrounds outside of the mask. We find no evidence for polarized foregrounds beyond those from soft (steep-spectrum) synchrotron and thermal dust emission; in particular we find no indication in the polarization data of an extra “haze” of hard synchrotron emission from energetic electrons near the Galactic center. We provide an updated map of the cosmic microwave background (CMB) using the internal linear combination method, updated foreground masks, and updates to point source catalogs using two different techniques. With additional years of data, we now detect 471 point sources using a five-band technique and 417 sources using a three-band CMB-free technique. In total there are 62 newly detected point sources, a 12% increase over the five-year release. Also new are tests of theMarkov chain Monte Carlo foreground fitting procedure against systematics in the time-stream data, and tests against the observed beam asymmetry. Within a few degrees of the Galactic plane, the behavior in total intensity of low-frequency foregrounds is complicated and not completely understood. WMAP data show a rapidly steepening spectrum from 20 to 40 GHz, which may be due to emission from spinning dust grains, steepening synchrotron, or other effects. Comparisons are made to a 1 deg 408 MHz map (Haslam et al.) and the 11 deg ARCADE 2 data (Singal et al.).We find that spinning dust or steepening synchrotron models fit the combination of WMAP and 408 MHz data equally well. ARCADE data appear inconsistent with the steepening synchrotron model and consistent with the spinning dust model, though some discrepancies remain regarding the relative strength of spinning dust emission. More high-resolution data in the 10–40 GHz range would shed much light on these issues

Comparing the Mechanical Response of Di-, Tri-, and Tetra-functional Resin Epoxies with Reactive Molecular Dynamics

The influence of monomer functionality on the mechanical properties of epoxies is studied using Molecular Dynamics (MD) with the Reax Force Field (ReaxFF). From deformation simulations, the Youngs modulus, yield point, and Poissons ratio are calculated and analyzed. The results demonstrate an increase in stiffness and yield strength with increasing resin functionality. Comparison between the network structures of distinct epoxies is further advanced by the Monomeric Degree Index (MDI). Experimental validation demonstrates the MD results correctly predict the relationship in Youngs moduli. Therefore, ReaxFF is confirmed to be a useful tool for studying the mechanical behavior of epoxies