Ferroelectricity and isotope effects in hydrogen-bonded KDP crystals

Based on an accurate first principles description of the energetics in H-bonded KDP, we conduct a first study of nuclear quantum effects and of the changes brought about by deuteration. Cluster tunneling involving also heavy ions is allowed, the main effect of deuteration being a depletion of the proton probability density at the O-H-O bridge center, which in turn weakens its proton-mediated covalent bonding. The ensuing lattice expansion couples selfconsistently with the proton off-centering, thus explaining both the giant isotope effect, and its close connection with geometrical effects.Comment: 4 two-column pages, 4 figure

Angular distribution studies on the two-photon ionization of hydrogen-like ions: Relativistic description

The angular distribution of the emitted electrons, following the two-photon ionization of the hydrogen-like ions, is studied within the framework of second order perturbation theory and the Dirac equation. Using a density matrix approach, we have investigated the effects which arise from the polarization of the incoming light as well as from the higher multipoles in the expansion of the electron--photon interaction. For medium- and high-Z ions, in particular, the non-dipole contributions give rise to a significant change in the angular distribution of the emitted electrons, if compared with the electric-dipole approximation. This includes a strong forward emission while, in dipole approxmation, the electron emission always occurs symmetric with respect to the plane which is perpendicular to the photon beam. Detailed computations for the dependence of the photoelectron angular distributions on the polarization of the incident light are carried out for the ionization of H, Xe$^{53+}$, and U$^{91+}$ (hydrogen-like) ions.Comment: 16 pages, 4 figures, published in J Phys

Deuteron Momentum Distribution in KD2HPO4

The momentum distribution in KD2PO4(DKDP) has been measured using neutron Compton scattering above and below the weakly first order paraelectric-ferroelectric phase transition(T=229K). There is very litte difference between the two distributions, and no sign of the coherence over two locations for the proton observed in the paraelectric phase, as in KH2PO4(KDP). We conclude that the tunnel splitting must be much less than 20mev. The width of the distribution indicates that the effective potential for DKDP is significantly softer than that for KDP. As electronic structure calculations indicate that the stiffness of the potential increases with the size of the coherent region locally undergoing soft mode fluctuations, we conclude that there is a mass dependent quantum coherence length in both systems.Comment: 6 pages 5 figure

Типізація взаємодії, як основа громадянського суспільства.

Коваль С.В. Типізація взаємодії, як основа громадянського суспільства. / С.В.Коваль // Актуальні проблеми політики : зб. наук. пр. / редкол.: С. В. Ківалов (голов. ред.), Л. І. Кормич (заст. голов. ред.), М. А. Польовий (відп. секр.) [та ін.] ; НУ «ОЮА», Південноукр. центр гендер. проблем. – Одеса, 2012. – Вип. 47. – С. 130 - 135.The article is devoted to the study of NGOs as new structural elements in the Ukrainian society. Also in The process of institutionalization of civil society in terms of interpretative paradigm – namely, the symbolic interaktsionizmu