Currents, Torques, and Polarization Factors in Magnetic Tunnel Junctions

Application of Bardeen's tunneling theory to magnetic tunnel junctions having a general degree of atomic disorder reveals the close relationship between magneto-conduction and voltage-driven pseudo-torque, as well as the thickness dependence of tunnel-polarization factors. Among the results: 1) The torque generally varies as sin theta at constant applied voltage. 2) Whenever polarization factors are well defined, the voltage-driven torque on each moment is uniquely proportional to the polarization factor of the other magnet. 3) At finite applied voltage, this relation predicts significant voltage-asymmetry in the torque. For one sign of voltage the torque remains substantial even when the magnetoconductance is greatly diminished. 4) A broadly defined junction model, called ideal middle, allows for atomic disorder within the magnets and F/I interface regions. In this model, the spin dependence of a state-weighting factor proportional to the sum over general state index of evaluated within the (e.g. vacuum) barrier generalizes the local state density in previous theories of the tunnel-polarization factor. 5) For small applied voltage, tunnel-polarization factors remain legitimate up to first order in the inverse thickness of the ideal middle. An algebraic formula describes the first-order corrections to polarization factors in terms of newly defined lateral auto-correllation scales.Comment: This version no. 3 is thoroughly revised for clarity. Just a few notations and equations are changed, and references completed. No change in results. 17 pages including 4 figure

Zinc(II) Complexes with Triplet Charge-Transfer Excited States Enabling Energy-Transfer Catalysis, Photoinduced Electron Transfer, and Upconversion

Many CuI complexes have luminescent triplet charge-transfer excited states with diverse applications in photophysics and photochemistry, but for isoelectronic ZnII compounds, this behavior is much less common, and they typically only show ligand-based fluorescence from singlet π–π* states. We report two closely related tetrahedral ZnII compounds, in which intersystem crossing occurs with appreciable quantum yields and leads to the population of triplet excited states with intraligand charge-transfer (ILCT) character. In addition to showing fluorescence from their initially excited 1ILCT states, these new compounds therefore undergo triplet–triplet energy transfer (TTET) from their 3ILCT states and consequently can act as sensitizers for photo-isomerization reactions and triplet–triplet annihilation upconversion from the blue to the ultraviolet spectral range. The photoactive 3ILCT state furthermore facilitates photoinduced electron transfer. Collectively, our findings demonstrate that mononuclear ZnII compounds with photophysical and photochemical properties reminiscent of well-known CuI complexes are accessible with suitable ligands and that they are potentially amenable to many different applications. Our insights seem relevant in the greater context of obtaining photoactive compounds based on abundant transition metals, complementing well-known precious-metal-based luminophores and photosensitizers

Anisotropic Topological Hall Effect with Real and Momentum Space Berry Curvature in the Antiskrymion Hosting Heusler Compound Mn1.4_{1.4}PtSn

The topological Hall effect (THE) is one of the key signatures of topologically non-trivial magnetic spin textures, wherein electrons feel an additional transverse voltage to the applied current. The magnitude of THE is often small compared to the anomalous Hall effect. Here, we find a large THE of 0.9 $\mu\Omega$cm that is of the same order of the anomalous Hall effect in the single crystalline antiskyrmion hosting Heusler compound Mn$_{1.4}$PtSn, a non-centrosymmetric tetragonal compound. The THE is highly anisotropic and survives in the whole temperature range where the spin structure is noncoplanar (<170 K). The THE is zero above the spin reorientation transition temperature of 170 K, where the magnetization will have a collinear and ferromagnetic alignment. The large value of the THE entails a significant contribution from the momentum space Berry curvature along with real space Berry curvature, which has never been observed earlier

Agent-based model of last-mile parcel deliveries and travel demand incorporating online shopping behavior

In this paper, we present an extension of the agent-based travel demand model mobiTopp with a last-mile parcel delivery module called logiTopp, in which online shopping choice is modeled explicitly. Online shopping behavior is modeled using logistic and Poisson regression models, which consider both the socio-demographic characteristics of the customer and aspects of their travel behavior. As mobiTopp is a framework that simulates travel demand over one week, we are able to capture interactions between travel behavior and online shopping that do not become apparent in single-day simulations. The results show that the integrated choice model reflects the findings presented in the literature in that male, affluent, young professionals are most likely to (frequently) order parcels online compared to other groups of the population. Application of the agent-based model to a city in Germany shows that socio-demographic and behavioral characteristics are considered realistically within the simulation. The model presented here is a suitable simulation tool for alternative urban last-mile delivery solutions, and the open-source and modular framework allows for transfer to other regions as the underlying choice models are consistent with literature from other spatial contexts. The findings are of interest to transportation planners and policymakers as they contribute to the understanding of how increased e-commerce demand influences the transportation system and solutions to mitigate adverse effects

Current-induced magnetization dynamics in disordered itinerant ferromagnets

Current-driven magnetization dynamics in ferromagnetic metals are studied in a self-consistent adiabatic local-density approximation in the presence of spin-conserving and spin-dephasing impurity scattering. Based on a quantum kinetic equation, we derive Gilbert damping and spin-transfer torques entering the Landau-Lifshitz equation to linear order in frequency and wave vector. Gilbert damping and a current-driven dissipative torque scale identically and compete, with the result that a steady current-driven domain-wall motion is insensitive to spin dephasing in the limit of weak ferromagnetism. A uniform magnetization is found to be much more stable against spin torques in the itinerant than in the \textit{s}-\textit{d} model for ferromagnetism. A dynamic spin-transfer torque reminiscent of the spin pumping in multilayers is identified and shown to govern the current-induced domain-wall distortion

Large Noncollinearity and Spin Reorientation in the Novel Mn2RhSn Heusler Magnet

Noncollinear magnets provide essential ingredients for the next generation memory technology. It is a new prospect for the Heusler materials, already well known due to the diverse range of other fundamental characteristics. Here, we present a combined experimental and theoretical study of novel noncollinear tetragonal Mn2RhSn Heusler material exhibiting unusually strong canting of its magnetic sublattices. It undergoes a spin-reorientation transition, induced by a temperature change and suppressed by an external magnetic field. Because of the presence of Dzyaloshinskii-Moriya exchange and magnetic anisotropy, Mn2RhSn is suggested to be a promising candidate for realizing the Skyrmion state in the Heusler family

Finite-temperature magnetism of Fex_xPd1−x_{1-x} and Cox_xPt1−x_{1-x} alloys

The finite-temperature magnetic properties of Fe$_x$Pd$_{1-x}$ and Co$_x$Pt$_{1-x}$ alloys have been investigated. It is shown that the temperature-dependent magnetic behaviour of alloys, composed of originally magnetic and non-magnetic elements, cannot be described properly unless the coupling between magnetic moments at magnetic atoms (Fe,Co) mediated through the interactions with induced magnetic moments of non-magnetic atoms (Pd,Pt) is included. A scheme for the calculation of the Curie temperature ($T_C$) for this type of systems is presented which is based on the extended Heisenberg Hamiltonian with the appropriate exchange parameters $J_{ij}$ obtained from {\em ab-initio} electronic structure calculations. Within the present study the KKR Green's function method has been used to calculate the $J_{ij}$ parameters. A comparison of the obtained Curie temperatures for Fe$_x$Pd$_{1-x}$ and Co$_x$Pt$_{1-x}$ alloys with experimental data shows rather good agreement.Comment: 10 pages, 12 figure