Flux-cutting and flux-transport effects in type-II superconductor slabs in a parallel rotating magnetic field

The magnetic response of irreversible type-II superconductor slabs subjected to in-plane rotating magnetic field is investigated by applying the circular, elliptic, extended-elliptic, and rectangular flux-line-cutting critical-state models. Specifically, the models have been applied to explain experiments on a PbBi rotating disk in a fixed magnetic field ${\bm H}_a$, parallel to the flat surfaces. Here, we have exploited the equivalency of the experimental situation with that of a fixed disk under the action of a parallel magnetic field, rotating in the opposite sense. The effect of both the magnitude $H_a$ of the applied magnetic field and its angle of rotation $\alpha_s$ upon the magnetization of the superconductor sample is analyzed. When $H_a$ is smaller than the penetration field $H_P$, the magnetization components, parallel and perpendicular to ${\bm H_a}$, oscillate with increasing the rotation angle. On the other hand, if the magnitude of the applied field, $H_a$, is larger than $H_P$, both magnetization components become constant functions of $\alpha_s$ at large rotation angles. The evolution of the magnetic induction profiles inside the superconductor is also studied.Comment: 12 pages, 29 figure

Bringing Math teachers to ICT for teaching and learning

En este documento se presenta una primera fase de un proceso de introducción de tecnologías digitales de la información y comunicación (TICS) en formación de profesores de matemáticas en ejercicio del Departamento del Tolima en Colombia. Se han indagado los procesos cognitivos de representación en conexión con los tipos de procesos y pensamiento matemáticos definidos en los Lineamientos Curriculares para el área de Matemáticas en Colombia. Se han empleado 10 software libres en la red de Internet y se han encontrado índices de dificultad en la resolución de problemas y en el empleo de representaciones.This paper presents a first phase of a process of introducing digital technologies of information and communication (ICT) into mathematics teacher training in exercise of the Department of Tolima in Colombia. The inquiry explores the cognitive processes of representation in connection with the types of mathematical thinking and processes defined in the Curriculum Guidelines for Mathematics area in Colombia. Have been used 10 software free in the Internet and found rates of difficulty in problem solving and the use of representations

Lignocellulose Nanofibre Obtained from Agricultural Wastes of Tomato, Pepper and Eggplants Improves the Performance of Films of Polyvinyl Alcohol (PVA) for Food Packaging

Films formulated with polyvinyl alcohol (PVA) (synthetic biopolymer) were reinforced with lignocellulose nanofibres (LCNF) from residues of vegetable production (natural biopolymer). The LCNF were obtained by mechanical and chemical pre-treatment by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO) and added to the polyvinyl alcohol (polymer matrix) with the aim of improving the properties of the film for use in food packaging. The mechanical properties, crystallinity, thermal resistance, chemical structure, antioxidant activity, water barrier properties and optical properties (transparency and UV barrier), were evaluated. In general, with the addition of LCNF, an improvement in the studied properties of the films was observed. In terms of mechanical properties, the films reinforced with 7% LCNF TEMPO showed the best results for tensile strength, Young’s modulus and elongation at break. At the same LCNF proportion, the thermal stability (Tmax) increased between 5.5% and 10.8%, and the antioxidant activity increased between 90.9% and 191.8%, depending on the raw material and the pre-treatment used to obtain the different LCNF. Finally, a large increase in UV blocking was also observed with the addition of 7% LCNF. In particular, the films with 7% of eggplant LCNF showed higher performance for Young’s modulus, elongation at break, thermal stability and UV barrier. Overall, results demonstrated that the use of LCNF generated from agricultural residues represents a suitable bioeconomy approach able to enhance film properties for its application in the development of more sustainable and eco-friendly food packaging systems

Horticultural Plant Residues as New Source for Lignocellulose Nanofibers Isolation: Application on the Recycling Paperboard Process

Horticultural plant residues (tomato, pepper, and eggplant) were identified as new sources for lignocellulose nanofibers (LCNF). Cellulosic pulp was obtained from the different plant residues using an environmentally friendly process, energy-sustainable, simple, and with low-chemical reagent consumption. The chemical composition of the obtained pulps was analyzed in order to study its influence in the nanofibrillation process. Cellulosic fibers were subjected to two different pretreatments, mechanical and TEMPO(2,2,6,6-Tetramethyl-piperidin-1-oxyl)-mediated oxidation, followed by high-pressure homogenization to produce different lignocellulose nanofibers. Then, LCNF were deeply characterized in terms of nanofibrillation yield, cationic demand, carboxyl content, morphology, crystallinity, and thermal stability. The suitability of each raw material to produce lignocellulose nanofibers was analyzed from the point of view of each pretreatment. TEMPO-mediated oxidation was identified as a more effective pretreatment to produce LCNF, however, it produces a decrease in the thermal stability of the LCNF. The different LCNF were added as reinforcing agent on recycled paperboard and compared with the improving produced by the industrial mechanical beating. The analysis of the papersheets’ mechanical properties shows that the addition of LCNF as a reinforcing agent in the paperboard recycling process is a viable alternative to mechanical beating, achieving greater reinforcing effect and increasing the products’ life cycles

Production of Cellulose Nanofibers from Olive Tree Harvest—a Residue with Wide Applications

With the aim of identifying new sources to produce cellulose nanofibers, olive tree pruning biomass (OTPB) was proposed for valorization as a sustainable source of cellulose. OTPB was subjected to a soda pulping process for cellulose purification and to facilitate the delamination of the fiber in the nanofibrillation process. Unbleached and bleached pulp were used to study the effect of lignin in the production of cellulose nanofibers through different pretreatments (mechanical and TEMPO-mediated oxidation). High-pressure homogenization was used as the nanofibrillation treatment. It was observed that for mechanical pretreatment, the presence of lignin in the fiber produces a greater fibrillation, resulting in a smaller width than that achieved with bleached fiber. In the case of TEMPO-mediated oxidation, the cellulose nanofiber characteristics show that the presence of lignin has an adverse effect on fiber oxidation, resulting in lower nanofibrillation. It was observed that the crystallinity of the nanofibers is lower than that of the original fiber, especially for unbleached nanofibers. The residual lignin content resulted in a greater thermal stability of the cellulose nanofibers, especially for those obtained by TEMPO-mediated oxidation. The characteristics of the cellulose nanofibers obtained in this work identify a gateway to many possibilities for reinforcement agents in paper suspension and polymeric matrices

Cellulose Nanofibers from Olive Tree Pruning as Food Packaging Additive of a Biodegradable Film

A biodegradable packaging film containing cellulose nanofibers from olive tree pruning, a by-product of olives production, was obtained using a solvent casting method. Nanocellulose was added to polyvinyl alcohol (PVA) to enhance the technological properties of the composite film as food packaging material. Nanocellulose was obtained from unbleached and bleached pulp through a mechanical and TEMPO pretreatment. Crystalline and chemical structure, surface microstructure, UV and gas barrier, optical, mechanical and antioxidant properties, as well as thermal stability were evaluated. Regarding optical properties, the UV barrier was increased from 6% for the pure PVA film to 50% and 24% for unbleached and bleached nanocellulose, respectively. The antioxidant capacity increased significantly in unbleached mechanical nanocellulose-films (5.3%) compared to pure PVA film (1.7%). In terms of mechanical properties, the tensile strength of the 5% unbleached mechanical nanocellulose films was significantly improved compared to the pure PVA film. Similarly, the 5% nanocellulose films had increased the thermal stability and improved barrier properties, reducing water vapor permeability by 38–59% and presenting an oxygen barrier comparable to aluminum layer and plastic films. Our results support the use of the developed films as a green alternative material for food packaging

Cellulose Nanofiber-Based Aerogels from Wheat Straw: Influence of Surface Load and Lignin Content on Their Properties and Dye Removal Capacity

Water pollution is one of the most serious problems worldwide. Nanocellulose-based aerogels usually show excellent adsorption capacities due to their high aspect ratio, specific surface area and surface charge, making them ideal for water purification. In this work, (ligno)cellulose nanofibers (LCNFs/CNFs) from wheat straw residues were obtained using two types of pre-treatments: mechanical (Mec) and TEMPO-mediated oxidization (TO), to obtain different consistency (0.2, 0.4, 0.6 and 0.8) bioaerogels, and their adsorption capacities as dye removers were further studied. The materials were characterized in terms of density, porosity and mechanical properties. An inversely proportional relationship was observed between the consistencies of the aerogels and their achieved densities. Despite the increase in density, all samples showed porosities above 99%. In terms of mechanical properties, the best results were obtained for the 0.8% consistency LCNF and CNF-Mec aerogels, reaching 67.87 kPa and 64.6 kPa for tensile strength and Young’s modulus, respectively. In contrast, the adsorption capacity of the aerogels was better for TEMPO-oxidized aerogels, reaching removal rates of almost 100% for the CNF-TO5 samples. Furthermore, the residual lignin content in LCNF-Mec aerogels showed a great improvement in the removal capacity, reaching rates higher than 80%, further improving the cost efficiency of the samples due to the reduction in chemical treatments

Production of Cellulosic Pulp from Reed (Phragmites australis) to Produce Paper and Paperboard

Due to the global increase in the demand for paper and cardboard, and depletion in some areas of wood resources (main raw material in the paper industry), it has been necessary to investigate new raw materials to substitute the conventional ones. In this work, Phragmites australis, commonly known as reed, has been studied. It has been characterized the chemical composition of the raw material by determining the ash content, α-cellulose, holocellulose, lignin and their extractables in ethanol, 1% soda and hot water. Subsequently three pulping processes have been conducted, using the “soda method" under three different operating conditions. The cellulosic pulps and the papersheets made from the pulps were analysed in order to determine the chemical and physical properties following the relevant TAPPI, UNE and ISO standards. Comparing the results obtained, it can be possible to conclude that the pulp obtained under the following operating conditions: 175°, 90 minutes and 14% of NaOH, presents the best results

Identification of non-small cell lung cancer biomarkers using mass spectrometry

Comunicaciones a congreso