Hardcore dimer aspects of the SU(2) Singlet wavefunction

We demonstrate that any SU(2) singlet wavefunction can be characterized by a set of Valence Bond occupation numbers, testing dimer presence/vacancy on pairs of sites. This genuine quantum property of singlet states (i) shows that SU(2) singlets share some of the intuitive features of hardcore quantum dimers, (ii) gives rigorous basis for interesting albeit apparently ill-defined quantities introduced recently in the context of Quantum Magnetism or Quantum Information to measure respectively spin correlations and bipartite entanglement and, (iii) suggests a scheme to define consistently a wide family of quantities analogous to high order spin correlation. This result is demonstrated in the framework of a general functional mapping between the Hilbert space generated by an arbitrary number of spins and a set of algebraic functions found to be an efficient analytical tool for the description of quantum spins or qubits systems.Comment: 5 pages, 2 figure

The structure of spinful quantum Hall states: a squeezing perspective

We provide a set of rules to define several spinful quantum Hall model states. The method extends the one known for spin polarized states. It is achieved by specifying an undressed root partition, a squeezing procedure and rules to dress the configurations with spin. It applies to both the excitation-less state and the quasihole states. In particular, we show that the naive generalization where one preserves the spin information during the squeezing sequence, may fail. We give numerous examples such as the Halperin states, the non-abelian spin-singlet states or the spin-charge separated states. The squeezing procedure for the series (k=2,r) of spinless quantum Hall states, which vanish as r powers when k+1 particles coincide, is generalized to the spinful case. As an application of our method, we show that the counting observed in the particle entanglement spectrum of several spinful states matches the one obtained through the root partitions and our rules. This counting also matches the counting of quasihole states of the corresponding model Hamiltonians, when the latter is available.Comment: 19 pages, 7 figures; v2: minor changes, and added references. Mathematica packages are available for downloa

Master equation approach to computing RVB bond amplitudes

We describe a "master equation" analysis for the bond amplitudes h(r) of an RVB wavefunction. Starting from any initial guess, h(r) evolves (in a manner dictated by the spin hamiltonian under consideration) toward a steady-state distribution representing an approximation to the true ground state. Unknown transition coefficients in the master equation are treated as variational parameters. We illustrate the method by applying it to the J1-J2 antiferromagnetic Heisenberg model. Without frustration (J2=0), the amplitudes are radially symmetric and fall off as 1/r^3 in the bond length. As the frustration increases, there are precursor signs of columnar or plaquette VBS order: the bonds preferentially align along the axes of the square lattice and weight accrues in the nearest-neighbour bond amplitudes. The Marshall sign rule holds over a large range of couplings, J2/J1 < 0.418. It fails when the r=(2,1) bond amplitude first goes negative, a point also marked by a cusp in the ground state energy. A nonrigourous extrapolation of the staggered magnetic moment (through this point of nonanalyticity) shows it vanishing continuously at a critical value J2/J1 = 0.447. This may be preempted by a first-order transition to a state of broken translational symmetry.Comment: 8 pages, 7 figure

Valence Bond Entanglement and Fluctuations in Random Singlet Phases

The ground state of the uniform antiferromagnetic spin-1/2 Heisenberg chain can be viewed as a strongly fluctuating liquid of valence bonds, while in disordered chains these bonds lock into random singlet states on long length scales. We show that this phenomenon can be studied numerically, even in the case of weak disorder, by calculating the mean value of the number of valence bonds leaving a block of $L$ contiguous spins (the valence-bond entanglement entropy) as well as the fluctuations in this number. These fluctuations show a clear crossover from a small $L$ regime, in which they behave similar to those of the uniform model, to a large $L$ regime in which they saturate in a way consistent with the formation of a random singlet state on long length scales. A scaling analysis of these fluctuations is used to study the dependence on disorder strength of the length scale characterizing the crossover between these two regimes. Results are obtained for a class of models which include, in addition to the spin-1/2 Heisenberg chain, the uniform and disordered critical 1D transverse-field Ising model and chains of interacting non-Abelian anyons.Comment: 8 pages, 6 figure

Infinite-Randomness Fixed Points for Chains of Non-Abelian Quasiparticles

One-dimensional chains of non-Abelian quasiparticles described by $SU(2)_k$ Chern-Simons-Witten theory can enter random singlet phases analogous to that of a random chain of ordinary spin-1/2 particles (corresponding to $k \to \infty$). For $k=2$ this phase provides a random singlet description of the infinite randomness fixed point of the critical transverse field Ising model. The entanglement entropy of a region of size $L$ in these phases scales as $S_L \simeq \frac{\ln d}{3} \log_2 L$ for large $L$, where $d$ is the quantum dimension of the particles.Comment: 4 pages, 4 figure

Statistical Ensembles with Fluctuating Extensive Quantities

We suggest an extension of the standard concept of statistical ensembles. Namely, we introduce a class of ensembles with extensive quantities fluctuating according to an externally given distribution. As an example the influence of energy fluctuations on multiplicity fluctuations in limited segments of momentum space for a classical ultra-relativistic gas is considered.Comment: 4 pages, 2 figure

Dual function additives: A small molecule crosslinker for enhanced efficiency and stability in organic solar cells

A bis‐azide‐based small molecule cross­linker is synthesized and evaluated as both a stabilizing and efficiency‐boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a non­invasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%

Kaluza-Klein 5D Ideas Made Fully Geometric

After the 1916 success of General relativity that explained gravity by adding time as a fourth dimension, physicists have been trying to explain other physical fields by adding extra dimensions. In 1921, Kaluza and Klein has shown that under certain conditions like cylindricity ($\partial g_{ij}/\partial x^5=0$), the addition of the 5th dimension can explain the electromagnetic field. The problem with this approach is that while the model itself is geometric, conditions like cylindricity are not geometric. This problem was partly solved by Einstein and Bergman who proposed, in their 1938 paper, that the 5th dimension is compactified into a small circle $S^1$ so that in the resulting cylindric 5D space-time $R^4\times S^1$ the dependence on $x^5$ is not macroscopically noticeable. We show that if, in all definitions of vectors, tensors, etc., we replace $R^4$ with $R^4\times S^1$, then conditions like cylindricity automatically follow -- i.e., these conditions become fully geometric.Comment: 14 page

Variational ground states of 2D antiferromagnets in the valence bond basis

We study a variational wave function for the ground state of the two-dimensional S=1/2 Heisenberg antiferromagnet in the valence bond basis. The expansion coefficients are products of amplitudes h(x,y) for valence bonds connecting spins separated by (x,y) lattice spacings. In contrast to previous studies, in which a functional form for h(x,y) was assumed, we here optimize all the amplitudes for lattices with up to 32*32 spins. We use two different schemes for optimizing the amplitudes; a Newton/conjugate-gradient method and a stochastic method which requires only the signs of the first derivatives of the energy. The latter method performs significantly better. The energy for large systems deviates by only approx. 0.06% from its exact value (calculated using unbiased quantum Monte Carlo simulations). The spin correlations are also well reproduced, falling approx. 2% below the exact ones at long distances. The amplitudes h(r) for valence bonds of long length r decay as 1/r^3. We also discuss some results for small frustrated lattices.Comment: v2: 8 pages, 5 figures, significantly expanded, new optimization method, improved result

Monte Carlo Simulations of Interacting Anyon Chains

A generalized version of the valence-bond Monte Carlo method is used to study ground state properties of the 1+1 dimensional quantum $Q$-state Potts models. For appropriate values of $Q$ these models can be used to describe interacting chains of non-Abelian anyons --- quasiparticle excitations of certain exotic fractional quantum Hall states.Comment: 4 pages, 5 figure