Role of Surface Interactions in Determining Surface Structure and State Formation in III-V Semiconductors

GaAs(100), (110), and (111) surfaces are chosen as a vehicle to explain the plethora of surface relaxation and reconstruction phenomena seen for III-V compound semiconductors. These relaxation and reconstruction processes directly affect the formation of surface states. The occupation of these states, in turn, can have a profound influence on device performance. The purpose of this work is to attempt to provide a unified description of the phenomena responsible for surface relaxation and reconstruction on these surfaces. Our work makes use of an ab initio effective core potential scheme based on the Hartree Fock approximation. We discuss the critical steps involved in both the surface reconstruction process and surface energy band structure evolution for (100) surfaces. It is shown that the reconstruction mechanism is driven by the need to satisfy the surface dangling bonds and by a steepening relaxation. (111) A and B surface reconstruction is discussed by reference to Ga6As6H18 model cluster calculation results. The importance of site specific chemical character on bonding and reconstruction is underlined. The main factors responsible for relaxation and reconstruction of III-V compound semiconductor surfaces are thus shown to include satisfying dangling bonds, steepening relaxation and site specific chemical character

Theory of transient spectroscopy of multiple quantum well structures

A theory of the transient spectroscopy of quantum well (QW) structures under a large applied bias is presented. An analytical model of the initial part of the transient current is proposed. The time constant of the transient current depends not only on the emission rate from the QWs, as is usually assumed, but also on the subsequent carrier transport across QWs. Numerical simulation was used to confirm the validity of the proposed model, and to study the transient current on a larger time scale. It is shown that the transient current is influenced by the nonuniform distribution of the electric field and related effects, which results in a step-like behavior of the current. A procedure of extraction of the QW emission time from the transient spectroscopy experiments is suggested.Comment: 5 pages, 4 figures, to be published in J. Appl. Phy

Aryl Phosphoramidates of 5-Phospho Erythronohydroxamic Acid, A New Class of Potent Trypanocidal Compounds

RNAi and enzymatic studies have shown the importance of 6-phosphogluconate dehydrogenase (6-PGDH) in Trypanosoma brucei for the parasite survival and make it an attractive drug target for the development of new treatments against human African trypanosomiasis. 2,3-O-Isopropylidene-4-erythrono hydroxamate is a potent inhibitor of parasite Trypanosoma brucei 6-phosphogluconate dehydrogenase (6-PGDH), the third enzyme of the pentose phosphate pathway. However, this compound does not have trypanocidal activity due to its poor membrane permeability. Consequently, we have previously reported a prodrug approach to improve the antiparasitic activity of this inhibitor by converting the phosphate group into a less charged phosphate prodrug. The activity of prodrugs appeared to be dependent on their stability in phosphate buffer. Here we have successfully further extended the development of the aryl phosphoramidate prodrugs of 2,3-O-isopropylidene-4-erythrono hydroxamate by synthesizing a small library of phosphoramidates and evaluating their biological activity and stability in a variety of assays. Some of the compounds showed high trypanocidal activity and good correlation of activity with their stability in fresh mouse blood

Quantum Computing in Decoherence-Free Subspace Constructed by Triangulation

A formalism for quantum computing in decoherence-free subspaces is presented. The constructed subspaces are partial triangulated to an index related to environment. The quantum states in the subspaces are just projected states which are ruled by a subdynamic kinetic equation. These projected states can be used to perform ideal quantum logical operations without decoherence

Electron beam induced current in InSb-InAs nanowire type-III heterostructures

InSb-InAs nanowire heterostructure diodes investigated by electron beam induced current (EBIC) demonstrate an unusual spatial profile where the sign of the EBIC signal changes in the vicinity of the heterointerface. A qualitative explanation confirmed by theoretical calculations is based on the specific band diagram of the structure representing a type-III heterojunction with an accumulation layer in InAs. The sign of the EBIC signal depends on the specific parameters of this layer. In the course of measurements, the diffusion length of holes in InAs and its temperature dependence are also determined

Electrical properties and band diagram of InSb-InAs nanowire type-III heterojunctions

The electrical properties of nanowire-based n-InSb-n-InAs heterojunctions were investigated theoretically and experimentally. Analysis of the current-voltage characteristics showed that the current through the heterojunction is caused mostly by generation-recombination processes in the InSb and at the heterointerface. Due to the partially overlapping valence band of InSb and the conduction band of InAs, the second process is fast and activationless. Theoretical analysis showed that, depending on the heterojunction parameters, the flux of non-equilibrium minority carriers may have a different direction, explaining the experimentally observed non-monotonic coordinate dependence of the electron beam induced current

Two Qubit Quantum Computing in a Projected Subspace

A formulation for performing quantum computing in a projected subspace is presented, based on the subdynamical kinetic equation (SKE) for an open quantum system. The eigenvectors of the kinetic equation are shown to remain invariant before and after interaction with the environment. However, the eigenvalues in the projected subspace exhibit a type of phase shift to the evolutionary states. This phase shift does not destroy the decoherence-free (DF) property of the subspace because the associated fidelity is 1. This permits a universal formalism to be presented - the eigenprojectors of the free part of the Hamiltonian for the system and bath may be used to construct a DF projected subspace based on the SKE. To eliminate possible phase or unitary errors induced by the change in the eigenvalues, a cancellation technique is proposed, using the adjustment of the coupling time, and applied to a two qubit computing system. A general criteria for constructing a DF projected subspace from the SKE is discussed. Finally, a proposal for using triangulation to realize a decoherence-free subsystem based on SKE is presented. The concrete formulation for a two-qubit model is given exactly. Our approach is novel and general, and appears applicable to any type of decoherence. Key Words: Quantum Computing, Decoherence, Subspace, Open System PACS number: 03.67.Lx,33.25.+k,.76.60.-kComment: 24 pages. accepted by Phys. Rev.

Changes in melatonin concentrations in seminal plasma are not correlated with testosterone or antioxidant enzyme activity when rams are located in areas with an equatorial photoperiod

In temperate climates, photoperiod and melatonin regulate ram reproduction, modulating hormonal secretions, sperm quality, and seminal plasma composition. Information on the effect of an equatorial photoperiod (12L:12D) on ram reproduction, however, is scarce, and no data on hormonal concentrations and antioxidant enzyme activity in seminal plasma have been reported. Thus, the variation was investigated of melatonin and its relationship with testosterone and antioxidant enzyme activity in the seminal plasma of three sheep breeds in Colombia, when there was a consistent photoperiod during two dry and two rainy seasons per year. Semen was collected once a week from 12 mature rams (four of each breed: Colombian Creole, Hampshire, and Romney Marsh). Seminal plasma was obtained by centrifugation. The concentration of melatonin and testosterone were quantified along with the enzymatic activity of glutathione peroxidase (GPx), glutathione reductase (GRD), and catalase (CAT). Correlation analyses between melatonin and testosterone concentrations or enzymatic activity were also performed. Melatonin concentration was affected by season (P < 0.05) but not breed, with lesser concentrations in the first rainy season. Testosterone concentration, however, was affected by breed and season, with greater concentrations (P < 0.01) in the Hampshire and Romney Marsh rams during the second dry season. Regarding antioxidant enzyme activity, there was only seasonal variation in GPx activity (P < 0.05). When correlation analyses were used for data assessments, there was a negative correlation between melatonin and testosterone concentrations in Hampshire rams. In conclusion, melatonin concentrations in seminal plasma of rams that were located in an area with an equatorial photoperiod was affected by the climatological season but there was no positive correlation with testosterone concentration or antioxidant enzyme activity