Thermo-kinetic approach of single-particles and clusters involving anomalous diffusion under viscoelastic response

We present a thermo-kinetic description of anomalous diffusion of single-particles and clusters in a viscoelastic medium in terms of a non-Markovian diffusion equation involving memory functions. The scaling behaviour of these functions is analyzed by considering hydrodynamics and cluster-size space random walk arguments. We explain experimental results on diffusion of Brownian particles in the cytoskeleton, in cluster-cluster aggregation and in a suspension of micelles.Comment: To be published in the Journal of Physical Chemistry

Periodic Modulation Induced Increase of Reaction Rates in Autocatalytic Systems

We propose a new mechanism to increase the reactions ratesin multistable autocatalytic systems. The mechanism is based upon the possibility for the enhancement of the response of the system due to the cooperative behavior between the noise and an external periodic modulation. In order to illustrate this feature we compute the reaction velocities for the particular case of the Sel'Kov model, showing that they increase significantly when the periodic modulation is introduced. This behavior originates from the existence of a minimum in the mean first passage time, one of the signatures of stochastic resonance.Comment: Submitted to J. Chem. Phy

Self-consistent theory of shot noise in nondegenerate ballistic conductors

A self-consistent theory of shot noise in ballistic two-terminal conductors under the action of long-range Coulomb correlations is presented. Analytical formulas for the electron distribution function and its fluctuation along the conductor, which account for the Coulomb correlations, have been derived. Based upon these formulas, the current-noise reduction factor has been obtained for biases ranging from thermal to shot-noise limits as dependent on two parameters: the ratio between the length of the sample and the Debye screening length \lambda=d/L_D and the applied voltage qU/k_BT. The difference with the formulas for a vacuum diode is discussed.Comment: 21 pages, 11 figs, minor change