Facile synthesis of iron-titanate nanocomposite as a sustainable material for selective amination of substitued nitro-arenes

The fabrication of durable and low-cost nanostructured materials remains important in chemical, biologic and medicinal applications. Particularly, iron-based nanomaterials are of central importance due to the ‘noble’ features of iron such as its high abundance, low cost and non-toxicity. Herein we report a simple sol–gel method for the synthesis of novel iron–titanium nanocomposite-based material (Fe9TiO15@TiO2). In order to prepare this material, we made a polymeric gel using ferrocene, titanium isopropoxide and THF precursors. The calcination of this gel in air at 500◦C produced Fe-Ti bimetallic nanoparticles-based composite and nano-TiO2 as support. Noteworthy, our methodology provides an excellent control over composition, size and shape of the resulting nanoparticles. The resulted Fe-based material provides a sustainable catalyst for selective synthesis of anilines, which are key intermediates for the synthesis of several chemicals, dyes and materials, via reduction of structurally diverse and functionalized nitroarenes. © 2020 by the authors. Licensee MDPI, Basel, Switzerland

Facile Synthesis of Iron-Titanate Nanocomposite as a Sustainable Material for Selective Amination of Substitued Nitro-Arenes

The fabrication of durable and low-cost nanostructured materials remains important in chemical, biologic and medicinal applications. Particularly, iron-based nanomaterials are of central importance due to the ‘noble’ features of iron such as its high abundance, low cost and non-toxicity. Herein we report a simple sol–gel method for the synthesis of novel iron–titanium nanocomposite-based material (Fe9TiO15@TiO2). In order to prepare this material, we made a polymeric gel using ferrocene, titanium isopropoxide and THF precursors. The calcination of this gel in air at 500 °C produced Fe-Ti bimetallic nanoparticles-based composite and nano-TiO2 as support. Noteworthy, our methodology provides an excellent control over composition, size and shape of the resulting nanoparticles. The resulted Fe-based material provides a sustainable catalyst for selective synthesis of anilines, which are key intermediates for the synthesis of several chemicals, dyes and materials, via reduction of structurally diverse and functionalized nitroarenes

Synthesis and Characterization of a Carbon‐Supported Cobalt Nitride Nano‐Catalyst

Transition metal nitrides have attracted great interest among the non‐noble catalysts employed in heterogeneous catalytic processes because of their exceptional stability and catalytic potential. However, the approach for their synthesis has remained a tremendous challenge. This study presents the synthesis of Co₄N/C catalyst fabricated at 400, 600, and 800 °, symbolized as Co₄N/C‐400, Co₄N/C‐600, Co₄N/C‐800, respectively. The characterization of fabricated catalysts is carried out through various advanced analytical techniques. As prepared nano‐catalyst Co₄N/C shows remarkable catalytic efficiency in terms of low activation energy (Ea=3.038×10⁻¹ KJ mol⁻¹), fast conversion rate (Kapp=0.2884 s⁻¹), and 97.57% conversion efficiency. Moreover, it also exhibits excellent stability and reusability because of its metallic characteristics. The outstanding catalytic activity of the catalyst is the combined effect in which the Co₄N nanoparticles acted as active sites, and the carbon support doped with nitrogen provided an expressway for the transport of electrons required for catalytic reduction. Moreover, the designed catalyst is immobilized on the cellulose membrane filter support, to demonstrate the catalytic reduction of 4‐nitrophenol to 4‐aminophenol. We envision that our work would facilitate the fabrication of cobalt nitrides‐based nano‐catalysts for a wide range of industrial applications

Synthesis and Characterization of a Carbon‐Supported Cobalt Nitride Nano‐Catalyst

Transition metal nitrides have attracted great interest among the non‐noble catalysts employed in heterogeneous catalytic processes because of their exceptional stability and catalytic potential. However, the approach for their synthesis has remained a tremendous challenge. This study presents the synthesis of Co₄N/C catalyst fabricated at 400, 600, and 800 °, symbolized as Co₄N/C‐400, Co₄N/C‐600, Co₄N/C‐800, respectively. The characterization of fabricated catalysts is carried out through various advanced analytical techniques. As prepared nano‐catalyst Co₄N/C shows remarkable catalytic efficiency in terms of low activation energy (Ea=3.038×10⁻¹ KJ mol⁻¹), fast conversion rate (Kapp=0.2884 s⁻¹), and 97.57% conversion efficiency. Moreover, it also exhibits excellent stability and reusability because of its metallic characteristics. The outstanding catalytic activity of the catalyst is the combined effect in which the Co₄N nanoparticles acted as active sites, and the carbon support doped with nitrogen provided an expressway for the transport of electrons required for catalytic reduction. Moreover, the designed catalyst is immobilized on the cellulose membrane filter support, to demonstrate the catalytic reduction of 4‐nitrophenol to 4‐aminophenol. We envision that our work would facilitate the fabrication of cobalt nitrides‐based nano‐catalysts for a wide range of industrial applications