The Reactivity of MgB2 with Common Substrate and Electronic Materials

The reactivity of MgB2 with powdered forms of common substrate and electronic materials is reported. Reaction temperatures between 600 C and 800 C, encompassing the range commonly employed in thin-film fabrication, were studied. The materials tested for reactivity were ZrO2, yttria stabilized zirconia (YSZ), MgO, Al2O3, SiO2, SrTiO3, TiN, TaN, AlN, Si, and SiC. At 600 C, MgB2 reacted only with SiO2 and Si. At 800 C, however, reactions were observed for MgB2 with Al2O3, SiO2, Si, SiC, and SrTiO3. The Tc of MgB2 decreased in the reactions with SiC and Al2O3.Comment: 5 figure

Strength Tests on Acetylated Aspen Flakeboards Exposed to a Brown-Rot Fungus

Aspen flakeboards made from control flakes and acetylated flakes at 18% acetyl weight gain using phenol-formaldehyde or isocyanate adhesives were subjected to a bending creep test under progressive brown-rot fungal attack with Tyromyces palustris. Deflection of the boards was measured as a function of time until failure. Isocyanate-bonded control flakeboards failed in an average of 26 days, while isocyanate-bonded acetylated boards showed little deflection after 100 days in test. Average weight loss of isocyanate-bonded control boards at failure averaged 6.2%, while the acetylated boards showed about 1.0% weight loss at the end of 100 days. Phenol-formaldehyde-bonded control flakeboards failed in an average of 76 days, while acetylated boards showed little deflection after 100 days in test. Average weight loss of phenol-formaldehyde-bonded control boards at failure averaged 8.6%, while the acetylated boards showed no weight loss after 100 days

Dimensional Stability of Acetylated Aspen Flakeboard

This study was conducted to determine if thickness swelling of flakeboards, which is much greater than that of plywood or solid wood, can be improved by chemical modification of the constituent wood flakes prior to board manufacture. The chemical treatment involved acetylation of oven-dry aspen ring flakes with a 50/50 mixture of acetic anhydride and xylene. Thickness swell of treated and control samples was measured by either immersion in water for periods of up to 10 days or exposure to 90% relative humidity for periods of up to 20 days. Treated samples exhibited one-sixth to one-seventh the thickness swelling of controls for the water-soak test. Similar trends were observed for humidity exposure

Gene by Sex Interaction for Measures of Obesity in the Framingham Heart Study

Obesity is an increasingly prevalent and severe health concern with a substantial heritable component and marked sex differences. We sought to determine if the effect of genetic variants also differed by sex by performing a genome-wide association study modeling the effect of genotype-by-sex interaction on obesity phenotypes. Genotype data from individuals in the Framingham Heart Study Offspring cohort were analyzed across five exams. Although no variants showed genome-wide significant gene-by-sex interaction in any individual exam, four polymorphisms displayed a consistent BMI association (P-values .00186 to .00010) across all five exams. These variants were clustered downstream of LYPLAL1, which encodes a lipase/esterase expressed in adipose tissue, a locus previously identified as having sex-specific effects on central obesity. Primary effects in males were in the opposite direction from females and were replicated in Framingham Generation 3. Our data support a sex-influenced association between genetic variation at the LYPLAL1 locus and obesity-related traits

‘Eastern African paradox’ rainfall decline due to shorter not less intense long rains

An observed decline in the Eastern African Long Rains from the 1980s to late 2000s appears contrary to the projected increase under future climate change. This “Eastern African climate paradox” confounds use of climate projections for adaptation planning across Eastern Africa. Here we show the decline corresponds to a later onset and earlier cessation of the long rains, with a similar seasonal maximum in area-averaged daily rainfall. Previous studies have explored the role of remote teleconnections, but those mechanisms do not sufficiently explain the decline or the newly identified change in seasonality. Using a large ensemble of observations, reanalyses and atmospheric simulations, we propose a regional mechanism that explains both the observed decline and the recent partial recovery. A decrease in surface pressure over Arabia and warmer north Arabian Sea is associated with enhanced southerlies and an earlier cessation of the long rains. This is supported by a similar signal in surface pressure in many atmosphere-only models giving lower May rainfall and an earlier cessation. Anomalously warm seas south of Eastern Africa delay the northward movement of the tropical rain-band, giving a later onset. These results are key in understanding the paradox. It is now a priority to establish the balance of mechanisms that have led to these trends, which are partially captured in atmosphere-only simulations

Future changes in seasonality in Eastern Africa from regional simulations with explicit and parametrised convection

The Eastern Africa precipitation seasonal cycle is of significant societal importance, and yet the current generation of coupled global climate models fails to correctly capture this seasonality. The use of convective parametrisation schemes is a known source of precipitation bias in such models. Recently, a high-resolution regional model was used to produce the first pan-African climate change simulation that explicitly models convection. Here, this is compared with a corresponding parametrised-convection simulation, to explore the effect of the parametrisation on representation of Eastern Africa precipitation seasonality. Both models capture current seasonality, although an overestimate in September-October in the parametrised simulation leads to an early bias in the onset of the boreal autumn short rains, associated with higher convective instability and near-surface moist static energy. This bias is removed in the explicit model. Under future climate change both models show the short rains getting later and wetter. For the boreal spring long rains, the explicit convection simulation shows the onset advancing but the parametrised simulation shows little change. Over Uganda and western Kenya both simulations show rainfall increases in the January-February dry season, and large increases in boreal summer and autumn rainfall, particularly in the explicit convection model, changing the shape of the seasonal cycle, with potential for pronounced socio-economic impacts. Interannual variability is similar in both models. Results imply that parameterisation of convection may be a source of uncertainty for projections of changes in seasonal timing from global models, and that potentially impactful changes in seasonality should be highlighted to users

Low Temperature Fabrication of MgB2

We report the fabrication of MgB2 with bulk superconducting properties by conventional solid state methods at temperatures as low as 550 C. Mg deficiencies of the type Mg1-xB2 were tested. Tc was found to decrease by about 1K at large x, though the amount of non-stoichiometry, if any, is likely to be very small. For specific processing conditions, indications of the 25-30 K transition often seen in thin films were seen in the bulk materials. The lower temperature transition may be associated with the grain boundaries. These results indicate that it should be possible to fabricate MgB2 with bulk properties in in-situ thin films at temperatures of 600 C or less.Comment: 3 pages, 5 figures (submitted to Journal of Applied Physics

Evidence for stratospheric sudden warming effects on the upper thermosphere derived from satellite orbital decay data during 1967–2013

We investigate possible impact of stratospheric sudden warmings (SSWs) on the thermosphere by using long-term data of the global average thermospheric total mass density derived from satellite orbital drag during 1967–2013. Residuals are analyzed between the data and empirical Global Average Mass Density Model (GAMDM) that takes into account density variability due to solar activity, season, geomagnetic activity, and long-term trend. A superposed epoch analysis of 37 SSW events reveals a density reduction of 3–7% at 250–575 km around the time of maximum polar vortex weakening. The relative density perturbation is found to be greater at higher altitudes. The temperature perturbation is estimated to be −7.0 K at 400 km. We show that the density reduction can arise from enhanced wave forcing from the lower atmosphere

Representation of precipitation and top-of-atmosphere radiation in a multi-model convection-permitting ensemble for the Lake Victoria Basin (East-Africa)

The CORDEX Flagship Pilot Study ELVIC (climate Extremes in the Lake VICtoria basin) was recently established to investigate how extreme weather events will evolve in this region of the world and to provide improved information for the climate impact community. Here we assess the added value of the convection-permitting scale simulations on the representation of moist convective systems over and around Lake Victoria. With this aim, 10 year present-day model simulations were carried out with five regional climate models at both PARameterized (PAR) scales (12–25 km) and Convection-Permitting (CP) scales (2.5–4.5 km), with COSMO-CLM, RegCM, AROME, WRF and UKMO. Most substantial systematic improvements were found in metrics related to deep convection. For example, the timing of the daily maximum in precipitation is systematically delayed in CP compared to PAR models, thereby improving the agreement with observations. The large overestimation in the total number of rainy events is alleviated in the CP models. Systematic improvements were found in the diurnal cycle in Top-Of-Atmosphere (TOA) radiation and in some metrics for precipitation intensity. No unanimous improvement nor deterioration was found in the representation of the spatial distribution of total rainfall and the seasonal cycle when going to the CP scale. Furthermore, some substantial biases in TOA upward radiative fluxes remain. Generally our analysis indicates that the representation of the convective systems is strongly improved in CP compared to PAR models, giving confidence that the models are valuable tools for studying how extreme precipitation events may evolve in the future in the Lake Victoria basin and its surroundings