The Use of Dramatic Demonstrations to Enhance the Motivation and Learning of Chemistry Students

As part of the Virginia Collaborative for Excellence in the Preparation of Teachers (VCEPT) project, a series of demonstrations was incorporated into Chemistry 100: Man and Environment, a science course taken by non-science majors including many prospective K-12 teachers. Dramatic chemical demonstrations were first presented to the undergraduate students by the instructor, and then they used demonstration activities to teach each other during the semester. Finally, these undergraduates presented to the K-6 students in the Norfolk Statue University (NSU) Summer Children’s College. The perceptions of science by the undergraduates at the beginning and end of the course were assessed using a questionnaire. The responses of the K-6 students in the Children’s College were assessed through informal interviews and audience response. The use of these demonstrations seemed to change the perception of science held by the undergraduate students. In addition, this limited assessment indicated that these demonstrations may have helped more of the undergraduates consider teaching as a career option

On giant piezoresistance effects in silicon nanowires and microwires

The giant piezoresistance (PZR) previously reported in silicon nanowires is experimentally investigated in a large number of surface depleted silicon nano- and micro-structures. The resistance is shown to vary strongly with time due to electron and hole trapping at the sample surfaces. Importantly, this time varying resistance manifests itself as an apparent giant PZR identical to that reported elsewhere. By modulating the applied stress in time, the true PZR of the structures is found to be comparable with that of bulk silicon

Spin and recombination dynamics of excitons and free electrons in p-type GaAs : effect of carrier density

Carrier and spin recombination are investigated in p-type GaAs of acceptor concentration NA = 1.5 x 10^(17) cm^(-3) using time-resolved photoluminescence spectroscopy at 15 K. At low pho- tocarrier concentration, acceptors are mostly neutral and photoelectrons can either recombine with holes bound to acceptors (e-A0 line) or form excitons which are mostly trapped on neutral acceptors forming the (A0X) complex. It is found that the spin lifetime is shorter for electrons that recombine through the e-A0 transition due to spin relaxation generated by the exchange scattering of free electrons with either trapped or free holes, whereas spin flip processes are less likely to occur once the electron forms with a free hole an exciton bound to a neutral acceptor. An increase of exci- tation power induces a cross-over to a regime where the bimolecular band-to-band (b-b) emission becomes more favorable due to screening of the electron-hole Coulomb interaction and ionization of excitonic complexes and free excitons. Then, the formation of excitons is no longer possible, the carrier recombination lifetime increases and the spin lifetime is found to decrease dramatically with concentration due to fast spin relaxation with free photoholes. In this high density regime, both the electrons that recombine through the e-A0 transition and through the b-b transition have the same spin relaxation time.Comment: 4 pages, 5 figure

Collective states of the odd-mass nuclei within the framework of the Interacting Vector Boson Model

A supersymmetric extension of the dynamical symmetry group $Sp^{B}(12,R)$ of the Interacting Vector Boson Model (IVBM), to the orthosymplectic group $OSp(2\Omega/12,R)$ is developed in order to incorporate fermion degrees of freedom into the nuclear dynamics and to encompass the treatment of odd mass nuclei. The bosonic sector of the supergroup is used to describe the complex collective spectra of the neighboring even-even nuclei and is considered as a core structure of the odd nucleus. The fermionic sector is represented by the fermion spin group $SO^{F}(2\Omega)\supset SU^{F}(2)$. The so obtained, new exactly solvable limiting case is applied for the description of the nuclear collective spectra of odd mass nuclei. The theoretical predictions for different collective bands in three odd mass nuclei, namely $^{157}Gd$, $^{173}Yb$ and $^{163}Dy$ from rare earth region are compared with the experiment. The $B(E2)$ transition probabilities for the $^{157}Gd$ and $^{163}Dy$ between the states of the ground band are also studied. The important role of the symplectic structure of the model for the proper reproduction of the $B(E2)$ behavior is revealed. The obtained results reveal the applicability of the models extension.Comment: 18 pages, 8 figure

Quantum communication between trapped ions through a dissipative environment

We study two trapped ions coupled to the axial phonon modes of a one-dimensional Coulomb crystal. This system is formally equivalent to the "two spin-boson" model. We propose a scheme to dynamically generate a maximally entangled state of two ions within a decoherence-free subspace. Here the phononic environment of the trapped ions, whatever its temperature and number of modes, serves as the entangling bus. The efficient production of the pure singlet state can be exploited to perform short-ranged quantum communication which is essential in building up a large-scale quantum computer.Comment: 4 pages, 2 figure

Effect of the Pauli principle on photoelectron spin transport in p+p^+ GaAs

In p+ GaAs thin films, the effect of photoelectron degeneracy on spin transport is investigated theoretically and experimentally by imaging the spin polarization profile as a function of distance from a tightly-focussed light excitation spot. Under degeneracy of the electron gas (high concentration, low temperature), a dip at the center of the polarization profile appears with a polarization maximum at a distance of about $2 \; \mu m$ from the center. This counterintuitive result reveals that photoelectron diffusion depends on spin, as a direct consequence of the Pauli principle. This causes a concentration dependence of the spin stiffness while the spin dependence of the mobility is found to be weak in doped material. The various effects which can modify spin transport in a degenerate electron gas under local laser excitation are considered. A comparison of the data with a numerical solution of the coupled diffusion equations reveals that ambipolar coupling with holes increases the steady-state photo-electron density at the excitation spot and therefore the amplitude of the degeneracy-induced polarization dip. Thermoelectric currrents are predicted to depend on spin under degeneracy (spin Soret currents), but these currents are negligible except at very high excitation power where they play a relatively small role. Coulomb spin drag and bandgap renormalization are negligible due to electrostatic screening by the hole gas

Geometrical dependence of decoherence by electronic interactions in a GaAs/GaAlAs square network

We investigate weak localization in metallic networks etched in a two dimensional electron gas between $25\:$mK and $750\:$mK when electron-electron (e-e) interaction is the dominant phase breaking mechanism. We show that, at the highest temperatures, the contributions arising from trajectories that wind around the rings and trajectories that do not are governed by two different length scales. This is achieved by analyzing separately the envelope and the oscillating part of the magnetoconductance. For $T\gtrsim0.3\:$K we find \Lphi^\mathrm{env}\propto{T}^{-1/3} for the envelope, and \Lphi^\mathrm{osc}\propto{T}^{-1/2} for the oscillations, in agreement with the prediction for a single ring \cite{LudMir04,TexMon05}. This is the first experimental confirmation of the geometry dependence of decoherence due to e-e interaction.Comment: LaTeX, 5 pages, 4 eps figure

Dissipation enhanced vibrational sensing in an olfactory molecular switch

Motivated by a proposed olfactory mechanism based on a vibrationally-activated molecular switch, we study electron transport within a donor-acceptor pair that is coupled to a vibrational mode and embedded in a surrounding environment. We derive a polaron master equation with which we study the dynamics of both the electronic and vibrational degrees of freedom beyond previously employed semiclassical (Marcus-Jortner) rate analyses. We show: (i) that in the absence of explicit dissipation of the vibrational mode, the semiclassical approach is generally unable to capture the dynamics predicted by our master equation due to both its assumption of one-way (exponential) electron transfer from donor to acceptor and its neglect of the spectral details of the environment; (ii) that by additionally allowing strong dissipation to act on the odorant vibrational mode we can recover exponential electron transfer, though typically at a rate that differs from that given by the Marcus-Jortner expression; (iii) that the ability of the molecular switch to discriminate between the presence and absence of the odorant, and its sensitivity to the odorant vibrational frequency, are enhanced significantly in this strong dissipation regime, when compared to the case without mode dissipation; and (iv) that details of the environment absent from previous Marcus-Jortner analyses can also dramatically alter the sensitivity of the molecular switch, in particular allowing its frequency resolution to be improved. Our results thus demonstrate the constructive role dissipation can play in facilitating sensitive and selective operation in molecular switch devices, as well as the inadequacy of semiclassical rate equations in analysing such behaviour over a wide range of parameters.Comment: 12 pages, 6 figures, close to published version, comments welcom