Screened electrostatic interactions between clay platelets

An effective pair potential for systems of uniformly charged lamellar colloids in the presence of an electrolytic solution of microscopic co- and counterions is derived. The charge distribution on the discs is expressed as a collection of multipole moments, and the tensors which determine the interactions between these multipoles are derived from a screened Coulomb potential. Unlike previous studies of such systems, the interaction energy may now be expressed for discs at arbitrary mutual orientation. The potential is shown to be exactly equivalent to the use of linearized Poisson-Boltzmann theory.Comment: 23 pages, 10 figures, created with Revtex. To appear in Molecular Physic

A comprehensive model to determine the effects of temperature and species fluctuations on reaction rates in turbulent reacting flows

The use of probability theory to determine the effects of turbulent fluctuations on reaction rates in turbulent combustion systems is briefly reviewed. Results are presented for the effect of species fluctuations in particular. It is found that turbulent fluctuations of species act to reduce the reaction rates, in contrast with the temperature fluctuations previously determined to increase Arrhenius reaction rate constants. For the temperature fluctuations, a criterion is set forth for determining if, in a given region of a turbulent flow field, the temperature can be expected to exhibit ramp like fluctuations. Using the above results, along with results previously obtained, a model is described for testing the effects of turbulent fluctuations of temperature and species on reaction rates in computer programs dealing with turbulent reacting flows. An alternative model which employs three variable probability density functions (temperature and two species) and is currently being formulated is discussed as well

The Global Star Formation Rate from the 1.4 GHz Luminosity Function

The decimetric luminosity of many galaxies appears to be dominated by synchrotron emission excited by supernova explosions. Simple models suggest that the luminosity is directly proportional to the rate of supernova explosions of massive stars averaged over the past 30 Myr. The proportionality may be used together with models of the evolving 1.4 GHz luminosity function to estimate the global star formation rate density in the era z < 1. The local value is estimated to be 0.026 solar masses per year per cubic megaparsec, some 50% larger than the value inferred from the Halpha luminosity density. The value at z ~ 1 is found to be 0.30 solar masses per year per cubic megaparsec. The 10-fold increase in star formation rate density is consistent with the increase inferred from mm-wave, far-infrared, ultra-violet and Halpha observations.Comment: 10 pages, 2 figures, Astrophysical Journal Letters (in press); new PS version has improved figure placemen

The peculiarities of British militarism: The air and navy leagues in interwar Britain

This thesis examines the role of the Air League of the British Empire and the Navy League – founded in 1909 and 1895 respectively – in the (re)militarisation of state and civil society in interwar Britain. More broadly, it considers the place of militarism, militarisation, and military culture at a time when internationalist counter-currents enjoyed significant resonance in British society. Both Leagues occupied a position between ‘high’ and ‘low’ politics, and their case offers new insights into the susceptibility of British popular and political culture to militarism. The two organisations played a prominent part in national debates on militarism, internationalism, youth, modernity, and rearmament. Their activities thus allow us to re-consider familiar themes in the history of interwar Britain in a fresh and conceptually challenging way – national defence, contested notions of Britain’s national status, the impact of war on British society and politics, political activism, and the relationship between state and civil society. This thesis draws on a wide range of sources, including minute books, private papers, memoirs, parliamentary proceedings, posters, pamphlets, government records, local and national newspapers, journals, oral testimony collections, newsreels, photographs, and satirical cartoons. The discussion is divided into two main parts. The chapters in Part A analyse the ways in which the Air League and Navy Leagues engaged with different political questions and contexts. The analysis developed shows how both Leagues promoted aerial and naval rearmament while having to negotiate the rise of issues such as disarmament, arms limitations, pacifism, collective security, and international diplomacy. The chapters in Part B detail how each League addressed civil society. Their focus on young people is traced through their educational ventures and youth organisations (the Air Defence Cadet Corps and the Sea Cadet Corps), while their targeting of mass audiences is explored through their staging of large-scale celebrations on Trafalgar Day and Empire Air Day. With the principal exception of David Edgerton’s work, most studies of British militarism terminate in 1914. However, the outbreak of the First World War did not constitute a terminus for organised militarism, nor did it mark the end of martial values or militaristic sentiment in mainstream British political culture. Overall, this thesis contends that militaristic leagues, the type of which featured prominently in the liberal political culture of Edwardian Britain, occupied a similar, if more contested and complex, place in the associational culture of interwar Britain. It argues that institutional, cultural, and popular forms of militarism were able to continue despite the growth of internationalism, fears that society had been brutalised by the experience of the First World War, the popularity of interwar peace movements, and the widespread support for issues such as disarmament and collective security. Finally, this thesis demonstrates the ways in which the Air and Navy Leagues contributed to the military preparedness of the nation upon the outbreak of the Second World War

The star-formation history of the universe - an infrared perspective

A simple and versatile parameterized approach to the star formation history allows a quantitative investigation of the constraints from far infrared and submillimetre counts and background intensity measurements. The models include four spectral components: infrared cirrus (emission from interstellar dust), an M82-like starburst, an Arp220-like starburst and an AGN dust torus. The 60 $\mu$m luminosity function is determined for each chosen rate of evolution using the PSCz redshift data for 15000 galaxies. The proportions of each spectral type as a function of 60 $\mu$m luminosity are chosen for consistency with IRAS and SCUBA colour-luminosity relations, and with the fraction of AGN as a function of luminosity found in 12 $\mu$m samples. The luminosity function for each component at any wavelength can then be calculated from the assumed spectral energy distributions. With assumptions about the optical seds corresponding to each component and, for the AGN component, the optical and near infrared counts can be accurately modelled. A good fit to the observed counts at 0.44, 2.2, 15, 60, 90, 175 and 850 $\mu$m can be found with pure luminosity evolution in all 3 cosmological models investigated: $\Omega_o$ = 1, $\Omega_o$ = 0.3 ($\Lambda$ = 0), and $\Omega_o$ = 0.3, $\Lambda$ = 0.7. All 3 models also give an acceptable fit to the integrated background spectrum. Selected predictions of the models, for example redshift distributions for each component at selected wavelengths and fluxes, are shown. The total mass-density of stars generated is consistent with that observed, in all 3 cosmological models.Comment: 20 pages, 25 figures. Accepted for publication in ApJ. Full details of models can be found at http://astro.ic.ac.uk/~mrr/countmodel

Thermal Emission from HII Galaxies: Discovering the Youngest Systems

We studied the radio properties of very young massive regions of star formation in HII galaxies, with the aim of detecting episodes of recent star formation in an early phase of evolution where the first supernovae start to appear. Our sample consists of 31 HII galaxies, characterized by strong Hydrogen emission lines, for which low resolution VLA 3.5cm and 6cm observations were obtained. The radio spectral energy distribution has a range of behaviours; 1) there are galaxies where the SED is characterized by a synchrotron-type slope, 2) galaxies with a thermal slope, and, 3) galaxies with possible free-free absorption at long wavelengths. The latter SEDs were found in a few galaxies and represent a signature of heavily embedded massive star clusters closely related to the early stages of massive star formation. Based on the comparison of the star formation rates determined from the recombination lines and those determined from the radio emission we find that SFR(Ha) is on average five times higher than SFR(1.4GHz). We confirm this tendency by comparing the ratio between the observed flux at 20 cm and the expected one, calculated based on the Ha star formation rates, both for the galaxies in our sample and for normal ones. This analysis shows that this ratio is a factor of 2 smaller in our galaxies than in normal ones, indicating that they fall below the FIR/radio correlation. These results suggest that the emission of these galaxies is dominated by a recent and massive star formation event in which the first supernovae (SN) just started to explode. We conclude that the systematic lack of synchrotron emission in those systems with the largest equivalent width of Hb can only be explained if those are young starbursts of less than 3.5Myr of age.Comment: Accepted for publication in Ap

Metabolomics-coupled functional pharmacology of chlorophyll compounds isolated from the leaves of Ficus Exasperata Vahl (Moraceae) provides novel pathways on myometrial activity

New chlorophyll derivatives (pheophytins along with pheophorbide derivatives) were isolated from the leaves of Ficus exasperata and were found to have varying effects on uterine contractility. The current study was therefore aimed at the utilization of mass spectrometry and nuclear magnetic resonance spectroscopy coupled with isolated uterine tissue assay as a platform to assist in the determination of the mechanism of activity of the isolated chlorophyll compounds from the plant F exasperata. The pheophytin and pheophorbide compounds (200 µg/mL) were added to the isolated uterine tissues. Mice uteri, treated with the pheophytin compounds, and the physiological buffer in which the uterine tissues were immersed, were rapidly collected and analyzed using high-resolution Fourier transform mass spectrometry and proton (1H) nuclear magnetic resonance for bioinformatics study. Resulting data were analyzed via pairwise chemometric comparison models, with P < .05 considered statistically significant. Primary signaling pathways found to be correlated with the pheophytins in this study included cyclic adenosine monophosphate, dopamine, extracellular signal-regulated kinases 1/2, and glutamate pathways

Toward understanding myometrial regulation : metabolomic investigation reveals new pathways of oxytocin and ritodrine activity on the myometrium

In recent times, additional pathways involved in the regulation of the myometrium have been suggested. This also holds true for the effect of drugs such as oxytocin (OT) and β-adrenergic agonists on the myometrium. Knowledge of these additional pathways will certainly prove useful in designing better therapies for pathologies of the myometrium. This study was therefore aimed at investigating the possibility of other pathways involved in the activities of both OT and ritodrine (RIT; a β-adrenergic agonist) in the myometrium by utilizing metabolomics and bioinformatics. High-resolution Fourier transform mass spectrometry (HRFTMS) and nuclear magnetic resonance (NMR) spectroscopy coupled with functional uterine assays were used for an innovative assessment. In vitro pharmacological assay of OT (1 nmol/L) and RIT (0.1 nmol/L) on isolated mice uteri mounted in 3 mL organ baths was performed. Mice uteri, treated with OT or RIT, as well as the physiological buffer in which the uterine tissues were immersed, were rapidly collected and analyzed using HRFTMS, proton ((1)H)-NMR, and bioinformatics. Resulting data were analyzed via pairwise chemometric comparison models, with P ≤ .05 considered statistically significant. In addition to previously known metabolites, nicotinamide adenine dinucleotide, γ-aminobutyric acid, and sphingosine were significantly associated with the activity of OT, whereas the activity of RIT was associated with a downstream involvement of prostaglandin F1 and phosphatidylinositol signaling. These findings add evidence to the reports on additional regulation of myometrial activity by these drugs and suggest newer pathways for therapeutic manipulation

Post-ISCO Ringdown Amplitudes in Extreme Mass Ratio Inspiral

An extreme mass ratio inspiral consists of two parts: adiabatic inspiral and plunge. The plunge trajectory from the innermost stable circular orbit (ISCO) is special (somewhat independent of initial conditions). We write an expression for its solution in closed-form and for the emitted waveform. In particular we extract an expression for the associated black-hole ringdown amplitudes, and evaluate them numerically.Comment: 21 pages, 5 figures. v4: added section with numerical evaluation of the ringdown amplitude

On the nature of the ISO-selected sources in the ELAIS S2 region

We have studied the optical, near-IR and radio properties of a complete sample of 43 sources detected at 15-micron in one of the deeper ELAIS repeatedly observed region. The extragalactic objects in this sample have 15-micron flux densities in the range 0.4-10 mJy, where the source counts start diverging from no evolution models. About 90% of the sources (39 out of 43) have optical counterparts brighter than I=21 mag. Eight of these 39 sources have been identified with stars on the basis of imaging data, while for another 22 sources we have obtained optical spectroscopy, reaching a high identification percentage (30/43, ~70%). All but one of the 28 sources with flux density > 0.7 mJy are identified. Most of the extragalactic objects are normal spiral or starburst galaxies at moderate redshift (z_med~0.2); four objects are Active Galactic Nuclei. We have used the 15-micron, H_alpha and 1.4-GHz luminosities as indicators of star-formation rate and we have compared the results obtained in these three bands. While 1.4-GHz and 15-micron estimates are in good agreement, showing that our galaxies are forming stars at a median rate of ~40 Mo/yr, the raw H_alpha-based estimates are a factor ~5-10 lower and need a mean correction of ~2 mag to be brought on the same scale as the other two indicators. A correction of ~2 mag is consistent with what suggested by the Balmer decrements H_alpha/H_beta and by the optical colours. Moreover, it is intermediate between the correction found locally for normal spirals and the correction needed for high-luminosity 15-micron objects, suggesting that the average extinction suffered by galaxies increases with infrared luminosity.Comment: 19 pages, 11 figures (3 in JPEG format), MNRAS, accepte