Novel alignment technique for LCD-biosensors

Contains fulltext : 13921.pdf (publisher's version ) (Open Access

Synthesis and self-assembly of giant porphyrin discs

Contains fulltext : 13852.pdf (publisher's version ) (Open Access

Molecular design strategies for electrochemical behavior of aromatic carbonyl compounds in organic and aqueous electrolytes

To sustainably satisfy the growing demand for energy, organic carbonyl compounds (OCCs) are being widely studied as electrode active materials for batteries owing to their high capacity, flexible structure, low cost, environmental friendliness, renewability, and universal applicability. However, their high solubility in electrolytes, limited active sites, and low conductivity are obstacles in increasing their usage. Here, the nucleophilic addition reaction of aromatic carbonyl compounds (ACCs) is first used to explain the electrochemical behavior of carbonyl compounds during charge-discharge, and the relationship of the molecular structure and electrochemical properties of ACCs are discussed. Strategies for molecular structure modifications to improve the performance of ACCs, i.e., the capacity density, cycle life, rate performance, and voltage of the discharge platform, are also elaborated. ACCs, as electrode active materials in aqueous solutions, will become a future research hotspot. ACCs will inevitably become sustainable green materials for batteries with high capacity density and high power density.Huiling Peng, Qianchuan Yu, Shengping Wang, Jeonghun Kim, Alan E. Rowan, Ashok Kumar Nanjundan, Yusuke Yamauchi, and Jingxian Y

Electronic Transport Properties or Ensembles of Perylene-Substituted Poly-isocyanopeptide Arrays

Contains fulltext : 72261.pdf (publisher's version ) (Closed access)9 p

A beryllium-10 chronology of late-glacial moraines in the upper Rakaia valley, Southern Alps, New Zealand supports Southern- Hemisphere warming during the Younger Dryas

Interhemispheric differences in the timing of pauses or reversals in the temperature rise at the end of the last ice age can help to clarify the mechanisms that influence glacial terminations. Our beryllium-10 (10Be) surface-exposure chronology for the moraines of the upper Rakaia valley of New Zealand's Southern Alps, combined with glaciological modeling, show that late-glacial temperature change in the atmosphere over the Southern Alps exhibited an Antarctic-like pattern. During the Antarctic Cold Reversal, the upper Rakaia glacier built two well-defined, closely-spaced moraines on Reischek knob at 13,900 ± 120 [1σ; ± 310 yrs when including a 2.1% production-rate (PR) uncertainty] and 13,140 ± 250 (±370) yrs ago, in positions consistent with mean annual temperature approximately 2 °C cooler than modern values. The formation of distinct, widely-spaced moraines at 12,140 ± 200 (±320) and 11,620 ± 160 (±290) yrs ago on Meins Knob, 2 km up-valley from the Reischek knob moraines, indicates that the glacier thinned by ∼250 m during Heinrich Stadial 0 (HS 0, coeval with the Younger Dryas 12,900 to 11,600 yrs ago). The glacier-inferred temperature rise in the upper Rakaia valley during HS 0 was about 1 °C. Because a similar pattern is documented by well-dated glacial geomorphologic records from the Andes of South America, the implication is that this late-glacial atmospheric climate signal extended from 79°S north to at least 36°S, and thus was a major feature of Southern Hemisphere paleoclimate during the last glacial termination

Fitting the integrated Spectral Energy Distributions of Galaxies

Fitting the spectral energy distributions (SEDs) of galaxies is an almost universally used technique that has matured significantly in the last decade. Model predictions and fitting procedures have improved significantly over this time, attempting to keep up with the vastly increased volume and quality of available data. We review here the field of SED fitting, describing the modelling of ultraviolet to infrared galaxy SEDs, the creation of multiwavelength data sets, and the methods used to fit model SEDs to observed galaxy data sets. We touch upon the achievements and challenges in the major ingredients of SED fitting, with a special emphasis on describing the interplay between the quality of the available data, the quality of the available models, and the best fitting technique to use in order to obtain a realistic measurement as well as realistic uncertainties. We conclude that SED fitting can be used effectively to derive a range of physical properties of galaxies, such as redshift, stellar masses, star formation rates, dust masses, and metallicities, with care taken not to over-interpret the available data. Yet there still exist many issues such as estimating the age of the oldest stars in a galaxy, finer details ofdust properties and dust-star geometry, and the influences of poorly understood, luminous stellar types and phases. The challenge for the coming years will be to improve both the models and the observational data sets to resolve these uncertainties. The present review will be made available on an interactive, moderated web page (sedfitting.org), where the community can access and change the text. The intention is to expand the text and keep it up to date over the coming years.Comment: 54 pages, 26 figures, Accepted for publication in Astrophysics & Space Scienc