315 research outputs found
Photodissociation of interstellar ArH+
Aims. Following the recent detection of 36ArH+ in the Crab nebula spectrum,
we have computed the photodissociation rate of ArH+ in order to constrain the
physical processes at work in this environment. Methods. Photodissociation
cross sections of ArH+ are computed in an ab initio approach including explicit
account of spin-orbit coupling. Results. We report the photodissociation cross
section of ArH+ as a function of wavelength. Photodissociation probabilities
are derived for different impinging radiation fields.The photodissociation
probability of for a very small unshielded cloud surrounded on all sides by the
unshielded InterStellar Radiation Field (ISRF) model described by Draine (1978)
is equal to 9.9e-12 s-1 and 1.9e-9 s-1 in the Crab nebula conditions. The
dependence on the visual extinction is obtained by using the Meudon Photon
Dominated Region (PDR) code and corresponding analytical fits are provided.
Conclusions. These data will help to produce a realistic chemical network to
interpret the observations. Photodissociation of ArH+ is found to be moderate
and the presence of this molecular ion is mainly dependent on the molecular
fractionComment: 11 pages, 6 Figures, Accepted in Astronomy Astrophysic
Asymptotic behavior of the quadratic variation of the sum of two Hermite processes of consecutive orders
Hermite processes are self--similar processes with stationary increments
which appear as limits of normalized sums of random variables with long range
dependence. The Hermite process of order is fractional Brownian motion and
the Hermite process of order is the Rosenblatt process. We consider here
the sum of two Hermite processes of order and and of different
Hurst parameters. We then study its quadratic variations at different scales.
This is akin to a wavelet decomposition. We study both the cases where the
Hermite processes are dependent and where they are independent. In the
dependent case, we show that the quadratic variation, suitably normalized,
converges either to a normal or to a Rosenblatt distribution, whatever the
order of the original Hermite processes
Collisional excitation of singly deuterated ammonia NHD by H
The availability of collisional rate coefficients with H is a
pre-requisite for interpretation of observations of molecules whose energy
levels are populated under non local thermodynamical equilibrium conditions. In
the current study, we present collisional rate coefficients for the NHD /
para--H() collisional system, for energy levels up to (735 K) and for gas temperatures in the range K. The
cross sections are obtained using the essentially exact close--coupling (CC)
formalism at low energy and at the highest energies, we used the
coupled--states (CS) approximation. For the energy levels up to
(215 K), the cross sections obtained through the CS formalism are
scaled according to a few CC reference points. These reference points are
subsequently used to estimate the accuracy of the rate coefficients for higher
levels, which is mainly limited by the use of the CS formalism. Considering the
current potential energy surface, the rate coefficients are thus expected to be
accurate to within 5\% for the levels below , while we estimate
an accuracy of 30\% for higher levels
CH2D+, the Search for the Holy Grail
CH2D+, the singly deuterated counterpart of CH3+, offers an alternative way
to mediate formation of deuterated species at temperatures of several tens of
K, as compared to the release of deuterated species from grains. We report a
longstanding observational search for this molecular ion, whose rotational
spectroscopy is not yet completely secure. We summarize the main spectroscopic
properties of this molecule and discuss the chemical network leading to the
formation of CH2D+, with explicit account of the ortho/para forms of H2, H3+
and CH3+. Astrochemical models support the presence of this molecular ion in
moderately warm environments at a marginal level.Comment: 25 pages, 6 Figures Accepted in Journal of Physical Chemistry A. "Oka
Festschrift: Celebrating 45 years of Astrochemistry
The IRAM-30m line survey of the Horsehead PDR: III. High abundance of complex (iso-)nitrile molecules in UV-illuminated gas
Complex (iso-)nitrile molecules, such as CH3CN and HC3N, are relatively
easily detected in our Galaxy and in other galaxies. We constrain their
chemistry through observations of two positions in the Horsehead edge: the
photo-dissociation region (PDR) and the dense, cold, and UV-shielded core just
behind it. We systematically searched for lines of CH3CN, HC3N, C3N, and some
of their isomers in our sensitive unbiased line survey at 3, 2, and 1mm. We
derived column densities and abundances through Bayesian analysis using a large
velocity gradient radiative transfer model. We report the first clear detection
of CH3NC at millimeter wavelength. We detected 17 lines of CH3CN at the PDR and
6 at the dense core position, and we resolved its hyperfine structure for 3
lines. We detected 4 lines of HC3N, and C3N is clearly detected at the PDR
position. We computed new electron collisional rate coefficients for CH3CN, and
we found that including electron excitation reduces the derived column density
by 40% at the PDR position. While CH3CN is 30 times more abundant in the PDR
than in the dense core, HC3N has similar abundance at both positions. The
isomeric ratio CH3NC/CH3CN is 0.15+-0.02. In the case of CH3CN, pure gas phase
chemistry cannot reproduce the amount of CH3CN observed in the UV-illuminated
gas. We propose that CH3CN gas phase abundance is enhanced when ice mantles of
grains are destroyed through photo-desorption or thermal-evaporation in PDRs,
and through sputtering in shocks. (abridged)Comment: Accepted for publication in Astronomy & Astrophysic
Collisional excitation of doubly and triply deuterated ammonia NDH and ND by H
The availability of collisional rate coefficients is a prerequisite for an
accurate interpretation of astrophysical observations, since the observed media
often harbour densities where molecules are populated under non--LTE
conditions. In the current study, we present calculations of rate coefficients
suitable to describe the various spin isomers of multiply deuterated ammonia,
namely the NDH and ND isotopologues. These calculations are based on
the most accurate NH--H potential energy surface available, which has
been modified to describe the geometrical changes induced by the nuclear
substitutions. The dynamical calculations are performed within the
close--coupling formalism and are carried out in order to provide rate
coefficients up to a temperature of = 50K. For the various
isotopologues/symmetries, we provide rate coefficients for the energy levels
below 100 cm. Subsequently, these new rate coefficients are used
in astrophysical models aimed at reproducing the NHD, NDH and ND
observations previously reported towards the prestellar cores B1b and 16293E.
We thus update the estimates of the corresponding column densities and find a
reasonable agreement with the previous models. In particular, the
ortho--to--para ratios of NHD and NHD are found to be consistent with
the statistical ratios
Ionization fraction and the enhanced sulfur chemistry in Barnard 1
Barnard B1b has revealed as one of the most interesting globules from the
chemical and dynamical point of view. It presents a rich molecular chemistry
characterized by large abundances of deuterated and complex molecules.
Furthermore, it hosts an extremely young Class 0 object and one candidate to
First Hydrostatic Core (FHSC). Our aim was to determine the cosmic ray
ionization rate and the depletion factors in this extremely young star forming
region. We carried out a spectral survey towards Barnard 1b as part of the IRAM
Large program ASAI using the IRAM 30-m telescope at Pico Veleta (Spain). This
provided a very complete inventory of neutral and ionic C-, N- and S- bearing
species with, up to our knowledge, the first secure detections of the
deuterated ions DCS+ and DOCO+. We used a state-of-the-art
pseudo-time-dependent gas-phase chemical model to determine the value of the
cosmic ray ionization rate and the depletion factors. The observational data
were well fitted with between 3E-17 s and 1E-16 s.
Elemental depletions were estimated to be ~10 for C and O, ~1 for N and ~25 for
S. Barnard B1b presents similar depletions of C and O than those measured in
pre-stellar cores. The depletion of sulfur is higher than that of C and O but
not as extreme as in cold cores. In fact, it is similar to the values found in
some bipolar outflows, hot cores and photon-dominated regions. Several
scenarios are discussed to account for these peculiar abundances. We propose
that it is the consequence of the initial conditions (important outflows and
enhanced UV fields in the surroundings) and a rapid collapse (~0.1 Myr) that
permits to maintain most S- and N-bearing species in gas phase to great optical
depths. The interaction of the compact outflow associated with B1b-S with the
surrounding material could enhance the abundances of S-bearing molecules, as
well.Comment: Paper accepted in Astronomy and Astrophysics; 28 pags, 21 figure
A model for atomic and molecular interstellar gas: The Meudon PDR code
We present the revised ``Meudon'' model of Photon Dominated Region (PDR
code), presently available on the web under the Gnu Public Licence at:
http://aristote.obspm.fr/MIS. General organisation of the code is described
down to a level that should allow most observers to use it as an interpretation
tool with minimal help from our part. Two grids of models, one for low
excitation diffuse clouds and one for dense highly illuminated clouds, are
discussed, and some new results on PDR modelisation highlighted.Comment: accepted in ApJ sup
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