30,447 research outputs found

    Polar communications: Status and recommendations. Report of the Science Working Group

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    The capabilities of the existing communication links within the polar regions, as well as between the polar regions and the continental United States, are summarized. These capabilities are placed in the context of the principal scientific disciplines that are active in polar research, and in the context of how scientists both utilize and are limited by present technologies. Based on an assessment of the scientific objectives potentially achievable with improved communication capabilities, a list of requirements on and recommendations for communication capabilities necessary to support polar science over the next ten years is given

    Nd:Glass-Raman laser for water vapor dial

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    A tunable solid-state Raman shifted laser which was used in a water vapor Differential Absorption Lidar (DIAL) system at 9400 A is described. The DIAL transmitter is based on a tunable glass laser operating at 1.06 microns, a hydrogen Raman cell to shift the radiation to 1.88 microns, and a frequency doubling crystal. The results of measurements which characterize the output of the laser with respect to optimization of optical configuration and of Raman parameters were reported. The DIAL system was also described and preliminary atmospheric returns shown

    Carbon-13 nuclear magnetic resonance spectra and mechanism of bridge–terminal carbonyl exchange in di-µ-carbonyl-bis[carbonyl(η-cyclopentadienyl)iron](Fe–Fe)[{(η-C5H5)Fe(CO)2}2]; cd-di-µ-carbonyl-f-carbonyl-ae-di(η-cyclopentadienyl)-b-(triethyl -phosphite)di-iron(Fe–Fe)[(η-C5H5)2Fe2(CO)3P(OEt)3], and some related complexes

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    A mechanism involving carbonyl-bridge breaking, rotation about the Fe–Fe bond, and bridge reformation is shown to account qualitatively for changes in the carbonyl region of the 13C n.m.r spectrum of the complex [(cp)(OC)[graphic omitted]e(cp){P(OEt)3}] and quantitatively for [(cp)(OC)[graphic omitted]e(CO)(cp)](cp =η-cyclopentadienyl).The activation energy for this process, 49.0 ± 4 kJ mol^–1(11.7 ± 1 kcal mol^–1), is close to that reported for cis–trans-isomerization of the cp groups, in accord with this mechanism. Variable-temperature 13C n.m.r. spectra of the complexes [(cp)(OC)[graphic omitted]u(CO)(cp)] and [(cp)(OC)[graphic omitted]i(cp)] are also reported

    Helicity dynamics in stratified turbulence in the absence of forcing

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    A numerical study of decaying stably-stratified flows is performed. Relatively high stratification and moderate Reynolds numbers are considered, and a particular emphasis is placed on the role of helicity (velocity-vorticity correlations). The problem is tackled by integrating the Boussinesq equations in a periodic cubical domain using different initial conditions: a non-helical Taylor-Green (TG) flow, a fully helical Beltrami (ABC) flow, and random flows with a tunable helicity. We show that for stratified ABC flows helicity undergoes a substantially slower decay than for unstratified ABC flows. This fact is likely associated to the combined effect of stratification and large scale coherent structures. Indeed, when the latter are missing, as in random flows, helicity is rapidly destroyed by the onset of gravitational waves. A type of large-scale dissipative "cyclostrophic" balance can be invoked to explain this behavior. When helicity survives in the system it strongly affects the temporal energy decay and the energy distribution among Fourier modes. We discover in fact that the decay rate of energy for stratified helical flows is much slower than for stratified non-helical flows and can be considered with a phenomenological model in a way similar to what is done for unstratified rotating flows. We also show that helicity, when strong, has a measurable effect on the Fourier spectra, in particular at scales larger than the buoyancy scale for which it displays a rather flat scaling associated with vertical shear

    What's Been Happening to Charitable Giving Recently? A Look at the Data

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    Examines the impact of the recession on giving by individuals, foundations, bequests, and corporations; the effects of tax policy changes on individual giving and bequests; and the potential effects of capping the charitable deduction at 28 percent
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