151 research outputs found
Magnetometry with nitrogen-vacancy defects in diamond
The isolated electronic spin system of the Nitrogen-Vacancy (NV) centre in
diamond offers unique possibilities to be employed as a nanoscale sensor for
detection and imaging of weak magnetic fields. Magnetic imaging with nanometric
resolution and field detection capabilities in the nanotesla range are enabled
by the atomic-size and exceptionally long spin-coherence times of this
naturally occurring defect. The exciting perspectives that ensue from these
characteristics have triggered vivid experimental activities in the emerging
field of "NV magnetometry". It is the purpose of this article to review the
recent progress in high-sensitivity nanoscale NV magnetometry, generate an
overview of the most pertinent results of the last years and highlight
perspectives for future developments. We will present the physical principles
that allow for magnetic field detection with NV centres and discuss first
applications of NV magnetometers that have been demonstrated in the context of
nano magnetism, mesoscopic physics and the life sciences.Comment: Review article, 28 pages, 16 figure
Magnetic-field-dependent photodynamics of single NV defects in diamond: Application to qualitative all-optical magnetic imaging
Magnetometry and magnetic imaging with nitrogen-vacancy (NV) defects in
diamond rely on the optical detection of electron spin resonance (ESR).
However, this technique is inherently limited to magnetic fields that are weak
enough to avoid electron spin mixing. Here we focus on the high off-axis
magnetic field regime for which spin mixing alters the NV defect spin dynamics.
We first study in a quantitative manner the dependence of the NV defect optical
properties on the magnetic field vector B. Magnetic-field-dependent
time-resolved photoluminescence (PL) measurements are compared to a seven-level
model of the NV defect that accounts for field-induced spin mixing. The model
reproduces the decreases in (i) ESR contrast, (ii) PL intensity and (iii)
excited level lifetime with an increasing off-axis magnetic field. We next
demonstrate that those effects can be used to perform all-optical magnetic
imaging in the high off-axis magnetic field regime. Using a scanning NV defect
microscope, we map the stray field of a magnetic hard disk through both PL and
fluorescence lifetime imaging. This all-optical method for high magnetic field
imaging at the nanoscale might be of interest in the field of nanomagnetism,
where samples producing fields in excess of several tens of milliteslas are
typical
Quantitative stray field imaging of a magnetic vortex core
Thin-film ferromagnetic disks present a vortex spin structure whose dynamics,
added to the small size (~10 nm) of their core, earned them intensive study.
Here we use a scanning nitrogen-vacancy (NV) center microscope to
quantitatively map the stray magnetic field above a 1 micron-diameter disk of
permalloy, unambiguously revealing the vortex core. Analysis of both
probe-to-sample distance and tip motion effects through stroboscopic
measurements, allows us to compare directly our quantitative images to
micromagnetic simulations of an ideal structure. Slight perturbations with
respect to the perfect vortex structure are clearly detected either due to an
applied in-plane magnetic field or imperfections of the magnetic structures.
This work demonstrates the potential of scanning NV microscopy to map tiny
stray field variations from nanostructures, providing a nanoscale,
non-perturbative detection of their magnetic texture.Comment: 5 pages, 4 figure
Avoiding power broadening in optically detected magnetic resonance of single NV defects for enhanced DC-magnetic field sensitivity
We report a systematic study of the magnetic field sensitivity of a magnetic
sensor based on a single Nitrogen-Vacancy (NV) defect in diamond, by using
continuous optically detected electron spin resonance (ESR) spectroscopy. We
first investigate the behavior of the ESR contrast and linewidth as a function
of the microwave and optical pumping power. The experimental results are in
good agreement with a simplified model of the NV defect spin dynamics, yielding
to an optimized sensitivity around 2 \mu T/\sqrt{\rm Hz}. We then demonstrate
an enhancement of the magnetic sensitivity by one order of magnitude by using a
simple pulsed-ESR scheme. This technique is based on repetitive excitation of
the NV defect with a resonant microwave \pi-pulse followed by an optimized
read-out laser pulse, allowing to fully eliminate power broadening of the ESR
linewidth. The achieved sensitivity is similar to the one obtained by using
Ramsey-type sequences, which is the optimal magnetic field sensitivity for the
detection of DC magnetic fields
Spin relaxometry of single nitrogen-vacancy defects in diamond nanocrystals for magnetic noise sensing
We report an experimental study of the longitudinal relaxation time ()
of the electron spin associated with single nitrogen-vacancy (NV) defects
hosted in nanodiamonds (ND). We first show that decreases over three
orders of magnitude when the ND size is reduced from 100 to 10 nm owing to the
interaction of the NV electron spin with a bath of paramagnetic centers lying
on the ND surface. We next tune the magnetic environment by decorating the ND
surface with Gd ions and observe an efficient -quenching, which
demonstrates magnetic noise sensing with a single electron spin. We estimate a
sensitivity down to electron spins detected within 10 s, using a
single NV defect hosted in a 10-nm-size ND. These results pave the way towards
-based nanoscale imaging of the spin density in biological samples.Comment: Main text with 4 figures together with supplemental informatio
Nanoscale magnetic field mapping with a single spin scanning probe magnetometer
We demonstrate quantitative magnetic field mapping with nanoscale resolution,
by applying a lock-in technique on the electron spin resonance frequency of a
single nitrogen-vacancy defect placed at the apex of an atomic force microscope
tip. In addition, we report an all-optical magnetic imaging technique which is
sensitive to large off-axis magnetic fields, thus extending the operation range
of diamond-based magnetometry. Both techniques are illustrated by using a
magnetic hard disk as a test sample. Owing to the non-perturbing and
quantitative nature of the magnetic probe, this work should open up numerous
perspectives in nanomagnetism and spintronics
Surface-induced charge state conversion of nitrogen-vacancy defects in nanodiamonds
We present a study of the charge state conversion of single nitrogen-vacancy
(NV) defects hosted in nanodiamonds (NDs). We first show that the proportion of
negatively-charged NV defects, with respect to its neutral counterpart
NV, decreases with the size of the ND. We then propose a simple model
based on a layer of electron traps located at the ND surface which is in good
agreement with the recorded statistics. By using thermal oxidation to remove
the shell of amorphous carbon around the NDs, we demonstrate a significant
increase of the proportion of NV defects in 10-nm NDs. These results are
invaluable for further understanding, control and use of the unique properties
of negatively-charged NV defects in diamondComment: 6 pages, 4 figure
Quantitative nanoscale vortex-imaging using a cryogenic quantum magnetometer
Microscopic studies of superconductors and their vortices play a pivotal role
in our understanding of the mechanisms underlying superconductivity. Local
measurements of penetration depths or magnetic stray-fields enable access to
fundamental aspects of superconductors such as nanoscale variations of
superfluid densities or the symmetry of their order parameter. However,
experimental tools, which offer quantitative, nanoscale magnetometry and
operate over the large range of temperature and magnetic fields relevant to
address many outstanding questions in superconductivity, are still missing.
Here, we demonstrate quantitative, nanoscale magnetic imaging of Pearl vortices
in the cuprate superconductor YBCO, using a scanning quantum sensor in form of
a single Nitrogen-Vacancy (NV) electronic spin in diamond. The sensor-to-sample
distance of ~10nm we achieve allows us to observe striking deviations from the
prevalent monopole approximation in our vortex stray-field images, while we
find excellent quantitative agreement with Pearl's analytic model. Our
experiments yield a non-invasive and unambiguous determination of the system's
local London penetration depth, and are readily extended to higher temperatures
and magnetic fields. These results demonstrate the potential of quantitative
quantum sensors in benchmarking microscopic models of complex electronic
systems and open the door for further exploration of strongly correlated
electron physics using scanning NV magnetometry.Comment: Main text (5 pages, 4 figures) plus supplementary material (5 pages,
6 figures). Comments welcome. Further information under
http://www.quantum-sensing.c
Engineered arrays of NV color centers in diamond based on implantation of CN- molecules through nanoapertures
We report a versatile method to engineer arrays of nitrogen-vacancy (NV)
color centers in dia- mond at the nanoscale. The defects were produced in
parallel by ion implantation through 80 nm diameter apertures patterned using
electron beam lithography in a PMMA layer deposited on a diamond surface. The
implantation was performed with CN- molecules which increased the NV defect
formation yield. This method could enable the realization of a solid-state
coupled-spin array and could be used for positioning an optically active NV
center on a photonic microstructure.Comment: 12 pages, 3 figure
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