Analytical Study of Solution-Processed Tin Oxide as Electron Transport Layer in Printed Perovskite Solar Cells

Solution‐processed tin oxide (SnO$_{x}$ ) electron transport layers demonstrate excellent performance in various optoelectronic devices and offer the ease of facile and low cost deposition by various printing techniques. The most common precursor solution for the preparation of SnO$_{x}$ thin films is SnCl$_{2}$ dissolved in ethanol. In order to elucidate the mechanism of the precursor conversion at different annealing temperatures and the optoelectronic performance of the SnO$_{x}$ electron transport layer, phonon and vibrational infrared and photoelectron spectroscopies as well as atomic force microscopy are used to probe the chemical, physical, and morphological properties of the SnO$_{x}$ thin films. The influence of two different solvents on the layer morphology of SnO$_{x}$ thin films is investigated. In both cases, an increasing annealing temperature not only improves the structural and chemical properties of solution‐processed SnO$_{x}$, but also reduces the concentration of tin hydroxide species in the bulk and on the surface of these thin films. As a prototypical example for the high potential of printed SnO$_{x}$ layers for solar cells, high performance perovskite solar cells with a stabilized power conversion efficiency of over 15% are presented

Tetrapodal Diazatriptycene Enforces Orthogonal Orientation in Self-Assembled Monolayers

none17Conformationally rigid multipodal molecules should control the orientation and packing density of functional head groups upon self-assembly on solid supports. Common tripods frequently fail in this regard because of inhomogeneous bonding configuration and stochastic orientation. These issues are circumvented by a suitable tetrapodal diazatriptycene moiety, bearing four thiol-anchoring groups, as demonstrated in the present study. Such molecules form well-defined self-assembled monolayers (SAMs) on Au(111) substrates, whereby the tetrapodal scaffold enforces a nearly upright orientation of the terminal head group with respect to the substrate, with at least three of the four anchoring groups providing thiolate-like covalent attachment to the surface. Functionalization by condensation chemistry allows a large variety of functional head groups to be introduced to the tetrapod, paving the path toward advanced surface engineering and sensor fabrication.NEXUSnoneBenneckendorf, Frank S; Rohnacher, Valentina; Sauter, Eric; Hillebrandt, Sabina; Münch, Maybritt; Wang, Can; Casalini, Stefano; Ihrig, Katharina; Beck, Sebastian; Jänsch, Daniel; Freudenberg, Jan; Jaegermann, Wolfram; Samorì, Paolo; Pucci, Annemarie; Bunz, Uwe H F; Zharnikov, Michael; Müllen, KlausBenneckendorf, Frank S; Rohnacher, Valentina; Sauter, Eric; Hillebrandt, Sabina; Münch, Maybritt; Wang, Can; Casalini, Stefano; Ihrig, Katharina; Beck, Sebastian; Jänsch, Daniel; Freudenberg, Jan; Jaegermann, Wolfram; Samorì, Paolo; Pucci, Annemarie; Bunz, Uwe H F; Zharnikov, Michael; Müllen, Klau