Non-reciprocal light scattering by lattice of magnetic vortices

We report on experimental study of optical properties of two-dimensional square lattice of triangle Co and CoFe nanoparticles with a vortex magnetization distribution. We demonstrate that intensity of light scattered in diffraction maxima depends on the vorticity of the particles magnetization and it can be manipulated by applying an external magnetic field. The experimental results can be understood in terms of phenomenological theory.Comment: 10 pages, 4 figure

Impedimetric determination of kanamycin in milk with aptasensor based on carbon black‐oligolactide composite

The determination of antibiotics in food is important due to their negative effect on human health related to antimicrobial resistance problem, renal toxicity, and allergic effects. We propose an impedimetric aptasensor for the determination of kanamycin A (KANA), which was assembled on the glassy carbon electrode by the deposition of carbon black in a chitosan matrix followed by carbodiimide binding of aminated aptamer mixed with oligolactide derivative of thiacalix[4]arene in a cone configuration. The assembling was monitored by cyclic voltammetry, electrochemical impedance spectroscopy, and scanning electron microscopy. In the presence of the KANA, the charge transfer resistance of the inner interface surprisingly decreased with the analyte concentration within 0.7 and 50 nM (limit of detection 0.3 nM). This was attributed to the partial shielding of the negative charge of the aptamer and of its support, a highly porous 3D structure of the surface layer caused by a macrocyclic core of the carrier. The use of electrostatic assembling in the presence of cationic polyelectrolyte decreased tenfold the detectable concentration of KANA. The aptasensor was successfully tested in the determination of KANA in spiked milk and yogurt with recoveries within 95% and 115%. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.Russian Science Foundation, RSF: 16‐13‐000051/0419/20Funding: I.S. acknowledges financial support from the Russian Science Foundation (grant no. 16‐13‐00005) in the synthesis and application in the biosensor platform of the oligolactides bearing thiacalix[4]arene fragments. T.H. acknowledges funding from the European Union’s Horizon 2020 Research and Innovation Program underthe Marie Sklodowska‐Curie grant agreement no. 690898 and from the Science Grant Agency VEGA, project No.1/0419/20

Electrochemical DNA Sensor Based on Acridine Yellow Adsorbed on Glassy Carbon Electrode

Electrochemical DNA sensors offer unique opportunities for the sensitive detection of specific DNA interactions. In this work, a voltametric DNA sensor is proposed on the base of glassy carbon electrode modified with carbon black, adsorbed acridine yellow and DNA for highly sensitive determination of doxorubicin antitumor drug. The signal recorded by cyclic voltammetry was attributed to irreversible oxidation of the dye. Its value was altered by aggregation of the hydrophobic dye molecules on the carbon black particles. DNA molecules promote disaggregation of the dye and increased the signal. This effect was partially suppressed by doxorubicin compensate for the charge of DNA in the intercalation. Sensitivity of the signal toward DNA and doxorubicin was additionally increased by treatment of the layer with dimethylformamide. In optimal conditions, the linear range of doxorubicin concentrations determined was 0.1 pM–1.0 nM, and the detection limit was 0.07 pM. No influence of sulfonamide medicines and plasma electrolytes on the doxorubicin determination was shown. The DNA sensor was tested on two medications (doxorubicin-TEVA and doxorubicin-LANS) and showed recoveries of 102–105%. The DNA sensor developed can find applications in the determination of drug residues in blood and for the pharmacokinetics studies. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.This research was funded by the Russian Science Foundation (A.P., grant no. 17-73-20024, investigations of DNA adsorption DMF influence and DNA-doxorubicin interactions) and the Russian Foundation for Basic Research (G.E., grant no. 20-03-00207, investigation of the AY electrochemical properties and its transfer on the electrode interface)

Investigation of interaction femtosecond laser pulses with skin and eyes mathematical model

We present a mathematical model of linear and nonlinear processes that takes place under the action of femtosecond laser radiation on the cutaneous covering. The study is carried out and the analytical solution of the set of equations describing the dynamics of the electron and atomic subsystems and investigated the processes of linear and nonlinear interaction of femtosecond laser pulses in the vitreous of the human eye, revealed the dependence of the pulse duration on the retina of the duration of the input pulse and found the value of the radiation power density, in which there is a self-focusing is obtained. The results of the work can be used to determine the maximum acceptable energy, generated by femtosecond laser systems, and to develop Russian laser safety standards for femtosecond laser systems

Thermal Analysis of EPOS components

We present a simulation study of the thermal behaviour of essential parts of the electron-positron converter of the positron source EPOS at the Research Center Dresden-Rossendorf. The positron moderator foil and the upper tube element of the electrostatic extraction einzellens are directly exposed to the primary electron beam (40 MeV, 40 kW). Thus, it was necessary to prove by sophisticated simulations that the construction can stand the evolving temperatures. It was found that thin moderator foils (< 20...40 µm) will not show a too strong heating. Moreover, the temperature can be varied in a wide range by choosing an appropriate thickness. Thus, the radiation-induced lattice defects can at least partly be annealed during operation. The wall of the extraction lens which is made from a stainless steel tube must be distinctly thinned to avoid damage temperatures. The simulations were performed time dependent. We found that the critical parts reach their final temperature after less than a minute

Impedimetric DNA Sensors for Epirubicin Detection Based on Polythionine Films Electropolymerized from Deep Eutectic Solvent

An electrochemically active polymer, polythionine (PTN), was synthesized in natural deep eutectic solvent (NADES) via multiple potential scans and characterized using cyclic voltammetry and electrochemical impedance spectroscopy (EIS). NADES consists of citric acid monohydrate, glucose, and water mixed in the molar ratio of 1:1:6. Electrodeposited PTN film was then applied for the electrostatic accumulation of DNA from salmon sperm and used for the sensitive detection of the anticancer drug epirubicin. Its reaction with DNA resulted in regular changes in the EIS parameters that made it possible to determine 1.0–100 µM of epirubicin with the limit of detection (LOD) of 0.3 µM. The DNA sensor developed was successfully applied for the detection of epirubicin in spiked samples of artificial and natural urine and saliva, with recovery ranging from 90 to 109%. The protocol of the DNA sensor assembling utilized only one drop of reactants and was performed with a minimal number of steps. Together with a simple measurement protocol requiring 100 µL of the sample, this offers good opportunities for the further use of the DNA sensor in monitoring the drug level in biological samples, which is necessary in oncology treatment and for the pharmacokinetics studies of new antitumor drugs. © 2023 by the authors.Russian Science Foundation, RSF: 23-13-00163This research was funded by the Russian Science Foundation (grant No. 23-13-00163, https://www.rscf.ru/en/project/23-13-00163 (assessed on 17 August 2023)

dS-AdS structures in the non-commutative Minkowski spaces

We consider a family of non-commutative 4d Minkowski spaces with the signature (1,3) and two types of spaces with the signature (2,2). The Minkowski spaces are defined by the common reflection equation and differ in anti-involutions. There exist two Casimir elements and the fixing of one of them leads to non-commutative "homogeneous" spaces $H_3$, $dS_3$, $AdS_3$ and light-cones. We present the quasi-classical description of the Minkowski spaces. There are three compatible Poisson structures - quadratic, linear and canonical. The quantization of the former leads to the considered Minkowski spaces. We introduce the horospheric generators of the Minkowski spaces. They lead to the horospheric description of $H_3$, $dS_3$ and $AdS_3$. The irreducible representations of Minkowski spaces $H_3$ and $dS_3$ are constructed. We find the eigen-functions of the Klein-Gordon equation in the terms of the horospheric generators of the Minkowski spaces. They give rise to eigen-functions on the $H_3$, $dS_3$, $AdS_3$ and light-cones.Comment: 31 pages, LateX, typos corrected, references adde