1,313 research outputs found
Correlation between molecular orbitals and doping dependence of the electrical conductivity in electron-doped Metal-Phthalocyanine compounds
We have performed a comparative study of the electronic properties of six
different electron-doped metal phthalocyanine (MPc) compounds (ZnPc, CuPc,
NiPc, CoPc, FePc, and MnPc), in which the electron density is controlled by
means of potassium intercalation. In spite of the complexity of these systems,
we find that the nature of the underlying molecular orbitals produce observable
effects in the doping dependence of the electrical conductivity of the
materials. For all the MPc's in which the added electrons are expected to
occupy orbitals centered on the ligands (ZnPc, CuPc, and NiPc), the doping
dependence of the conductivity has an essentially identical shape. This shape
is different from that observed in MPc materials in which electrons are also
added to orbitals centered on the metal atom (CoPc, FePc, and MnPc). The
observed relation between the macroscopic electronic properties of the MPc
compounds and the properties of the molecular orbitals of the constituent
molecules, clearly indicates the richness of the alkali-doped
metal-phthalocyanines as a model class of compounds for the investigation of
the electronic properties of molecular systems
Local Guided Wavefield Analysis for Characterization of Delaminations in Composites
Delaminations in composite laminates resulting from impact events may be accompanied by minimal indication of damage at the surface. As such, inspection techniques are required to ensure defects are within allowable limits. Conventional ultrasonic scanning techniques have been shown to effectively characterize the size and depth of delaminations but require physical contact with the structure. Alternatively, a noncontact scanning laser vibrometer may be used to measure guided wave propagation in the laminate structure. A local Fourier domain analysis method is presented for processing guided wavefield data to estimate spatially-dependent wavenumber values, which can be used to determine delamination depth. The technique is applied to simulated wavefields and results are analyzed to determine limitations of the technique with regards to determining defect size and depth. Finally, experimental wavefield data obtained in quasi-isotropic carbon fiber reinforced polymer (CFRP) laminates with impact damage is analyzed and wavenumber is measured to an accuracy of 8.5% in the region of shallow delaminations. Keywords: Ultrasonic wavefield imaging, Windowed Fourier transforms, Guided waves, Structural health monitoring, Nondestructive evaluatio
Interface-induced heavy-hole/light-hole splitting of acceptors in silicon
The energy spectrum of spin-orbit coupled states of individual sub-surface
boron acceptor dopants in silicon have been investigated using scanning
tunneling spectroscopy (STS) at cryogenic temperatures. The spatially resolved
tunnel spectra show two resonances which we ascribe to the heavy- and
light-hole Kramers doublets. This type of broken degeneracy has recently been
argued to be advantageous for the lifetime of acceptor-based qubits [Phys. Rev.
B 88 064308 (2013)]. The depth dependent energy splitting between the heavy-
and light-hole Kramers doublets is consistent with tight binding calculations,
and is in excess of 1 meV for all acceptors within the experimentally
accessible depth range (< 2 nm from the surface). These results will aid the
development of tunable acceptor-based qubits in silicon with long coherence
times and the possibility for electrical manipulation
Balanced ternary addition using a gated silicon nanowire
We demonstrate the proof of principle for a ternary adder using silicon
metal-on-insulator single electron transistors (SET). Gate dependent rectifying
behavior of a single electron transistor results in a robust three-valued
output as a function of the potential of the SET island. Mapping logical,
ternary inputs to the three gates controlling the potential of the SET island
allows us to perform complex, inherently ternary operations, on a single
transistor
Evidence for a Second Order Phase Transition in Glasses at Very Low Temperatures -- A Macroscopic Quantum State of Tunneling Systems
Dielectric measurements at very low temperature indicate that in a glass with
the eutectic composition BaO-AlO-SiO a phase transition occurs at
5.84 mK. Below that temperature small magnetic fields of the order of 10 T
cause noticeable changes of the dielectric constant although the glass is
insensitive to fields up to 20 T above 10 mK. The experimental findings may be
interpreted as the signature of the formation of a new phase in which many
tunneling systems perform a coherent motion resulting in a macroscopic wave
function.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let
Improved Sizing of Impact Damage in Composites Based on Thermographic Response
Impact damage in thin carbon fiber reinforced polymer composites often results in a relatively small region of damage at the front surface, with increasing damage near the back surface. Conventional methods for reducing the pulsed thermographic responses of the composite tend to underestimate the size of the back surface damage, since the smaller near surface damage gives the largest thermographic indication. A method is presented for reducing the thermographic data to produce an estimated size for the impact damage that is much closer to the size of the damage estimated from other NDE techniques such as microfocus x-ray computed tomography and pulse echo ultrasonics. Examples of the application of the technique to experimental data acquired on specimens with impact damage are presented. The method is also applied to the results of thermographic simulations to investigate the limitations of the technique
Spatial adiabatic passage in a realistic triple well structure
We investigate the evolution of an electron undergoing coherent tunneling via
adiabatic passage (CTAP) using the solution of the one-dimensional Schroedinger
equation in both space and time for a triple well potential. We find the
eigenspectrum and complete time evolution for a range of different pulsing
schemes. This also provides an example of a system that can be described with
the tools from both quantum optics and condensed matter. We find that while the
quantum optics description of the process captures most of the key physics,
there are important effects that can only be correctly described by a more
complete representation. This is an important point for applications such as
quantum information processing or quantum control where it is common practice
to use a reduced state space formulation of the quantum system in question.Comment: 10 pages, 12 figures (color online) - Published Versio
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