600 research outputs found
Interference effects in electronic transport through metallic single-wall carbon nanotubes
In a recent paper Liang {\it et al.} [Nature {\bf 411}, 665 (2001)] showed
experimentally, that metallic nanotubes, strongly coupled to external
electrodes, may act as coherent molecular waveguides for electronic transport.
The experimental results were supported by theoretical analysis based on the
scattering matrix approach. In this paper we analyze theoretically this problem
using a real-space approach, which makes it possible to control quality of
interface contacts. Electronic structure of the nanotube is taken into account
within the tight-binding model. External electrodes and the central part
(sample) are assumed to be made of carbon nanotubes, while the contacts between
electrodes and the sample are modeled by appropriate on-site (diagonal) and
hopping (off-diagonal) parameters. Conductance is calculated by the Green
function technique combined with the Landauer formalism. In the plots
displaying conductance {\it vs.} bias and gate voltages, we have found typical
diamond structure patterns, similar to those observed experimentally. In
certain cases, however, we have found new features in the patterns, like a
double-diamond sub-structure.Comment: 15 pages, 4 figures. To apear in Phys. Rev.
Conductance of Distorted Carbon Nanotubes
We have calculated the effects of structural distortions of armchair carbon
nanotubes on their electrical transport properties. We found that the bending
of the nanotubes decreases their transmission function in certain energy ranges
and leads to an increased electrical resistance. Electronic structure
calculations show that these energy ranges contain localized states with
significant - hybridization resulting from the increased curvature
produced by bending. Our calculations of the contact resistance show that the
large contact resistances observed for SWNTs are likely due to the weak
coupling of the NT to the metal in side bonded NT-metal configurations.Comment: 5 pages RevTeX including 4 figures, submitted to PR
Enhanced thermal stability and spin-lattice relaxation rate of N@C60 inside carbon nanotubes
We studied the temperature stability of the endohedral fullerene molecule,
N@C60, inside single-wall carbon nanotubes using electron spin resonance
spectroscopy. We found that the nitrogen escapes at higher temperatures in the
encapsulated material as compared to its pristine, crystalline form. The
temperature dependent spin-lattice relaxation time, T_1, of the encapsulated
molecule is significantly shorter than that of the crystalline material, which
is explained by the interaction of the nitrogen spin with the conduction
electrons of the nanotubes.Comment: 5 pages, 4 figures, 1 tabl
Interrupteur optique réversible constitué d'une monocouche auto-assemblée de dérivés thiophène-azobenzène
High on-off conductance switching ratio in light-driven self-assembled molecular devices
Date du colloque : 5-9/01/2010International audienc
Reversible Band Gap Engineering in Carbon Nanotubes by Radial Deformation
We present a systematic analysis of the effect of radial deformation on the
atomic and electronic structure of zigzag and armchair single wall carbon
nanotubes using the first principle plane wave method. The nanotubes were
deformed by applying a radial strain, which distorts the circular cross section
to an elliptical one. The atomic structure of the nanotubes under this strain
are fully optimized, and the electronic structure is calculated
self-consistently to determine the response of individual bands to the radial
deformation. The band gap of the insulating tube is closed and eventually an
insulator-metal transition sets in by the radial strain which is in the elastic
range. Using this property a multiple quantum well structure with tunable and
reversible electronic structure is formed on an individual nanotube and its
band-lineup is determined from first-principles. The elastic energy due to the
radial deformation and elastic constants are calculated and compared with
classical theories.Comment: To be appear in Phys. Rev. B, Apr 15, 200
Temperature dependence of the charge carrier mobility in gated quasi-one-dimensional systems
The many-body Monte Carlo method is used to evaluate the frequency dependent
conductivity and the average mobility of a system of hopping charges,
electronic or ionic on a one-dimensional chain or channel of finite length. Two
cases are considered: the chain is connected to electrodes and in the other
case the chain is confined giving zero dc conduction. The concentration of
charge is varied using a gate electrode. At low temperatures and with the
presence of an injection barrier, the mobility is an oscillatory function of
density. This is due to the phenomenon of charge density pinning. Mobility
changes occur due to the co-operative pinning and unpinning of the
distribution. At high temperatures, we find that the electron-electron
interaction reduces the mobility monotonically with density, but perhaps not as
much as one might intuitively expect because the path summation favour the
in-phase contributions to the mobility, i.e. the sequential paths in which the
carriers have to wait for the one in front to exit and so on. The carrier
interactions produce a frequency dependent mobility which is of the same order
as the change in the dc mobility with density, i.e. it is a comparably weak
effect. However, when combined with an injection barrier or intrinsic disorder,
the interactions reduce the free volume and amplify disorder by making it
non-local and this can explain the too early onset of frequency dependence in
the conductivity of some high mobility quasi-one-dimensional organic materials.Comment: 9 pages, 8 figures, to be published in Physical Review
Tunable adsorption on carbon nanotubes
We investigated the adsorption of a single atom, hydrogen and aluminum, on
single wall carbon nanotubes from first-principles. The adsorption is
exothermic, and the associated binding energy varies inversely as the radius of
the zigzag tube. We found that the adsorption of a single atom and related
properties can be modified continuously and reversibly by the external radial
deformation. The binding energy on the high curvature site of the deformed tube
increases with increasing radial deformation. The effects of curvature and
radial deformation depend on the chirality of the tube.Comment: To be appear in Physical Review Letter
Aging Puerto Ricans’ Experiences of Depression Treatment: A New Ethnographic Exploration
PurposeTo examine aging Puerto Ricans’ experiences with and perceptions of depression treatment.Methodology/approachIn-depth analysis of eight exemplary cases from ethnographic interviews with a subsample of 16 aging Puerto Ricans in the Boston area who are part of the Boston Puerto Rican Health Study.FindingsThe results show that respondents were resistant to accepting pharmacological treatment for their depression, and they often characterized antidepressants as “dope.” Moreover, they claimed that in addition to their health problems, social stressors such as financial strain, lack of jobs, housing problems, and social isolation are triggering or contributing to their depression. Because of this, they express reluctance in accepting clinical treatment only, and suggest that broader social issues and other health needs ought to be addressed as part of an effective treatment. For many, pharmacological treatment is acceptable only in the more severe forms of depression.Research limitations/implicationsThese results have important implications for improving the quality of depression treatment and reducing health disparities for mainland Puerto Ricans.Originality/value of chapterEven though recent studies continue to show a high frequency of depression among Puerto Ricans, issues of treatment quality are still understudied and ethnographic accounts are especially lacking. Our study offers an exploratory investigation of this unresolved research issue
Persistent currents in carbon nanotubes based rings
Persistent currents in rings constructed from carbon nanotubes are
investigated theoretically. After studying the contribution of finite
temperature or quenched disorder on covalent rings, the complexity due to the
bundle packing is addressed. The case of interacting nanotori and
self-interacting coiled nanotubes are analyzed in details in relation with
experiments.Comment: 7 sections, 9 figure
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