Ação de fitoreguladores na produtividade da soja cultivar Davis

This research deals with the effects of exogenous growth regulators on production of soybean plant (Glycine max cv.. Davis) under greenhouse conditions, At the flower anthesis, 2,3,5-triiodobenzoic acid (TIBA) 20 ppm was applied. Other two applications with TiBA, with intervals of four days, were realized. Before flowering, Agrostemin (1 g/10 ml/3 1), gibberellic acid (GA) 100 ppm, and (2-chloroethyl) trimethylammonium chloride (CCC) 2,000 ppm were applied. It was observed that CCC and TIBA reduced stem dry weight. Soybean plants treated with TIBA reduced weight of pods without seeds , seed number and seed weight.Verificou-se em condições de casa de vegetação o efeito de fitoreguladores na produtividade da soja (Glycine max cv. Davis). Em prê-florescência aplicou-se através de pulverização Agrostemin (1 g/10 ml/3 l), ácido giberélico (GA) 100 ppm e cloreto (2-cloroe til) trimetilamónio (CCC) 2.000 ppm, além do controle. Foi também pulverizado o ácido 2,3,5 - triiodobenzõico (TIBA) 20 ppm, por três vezes, com quatro dias de intervalo a partir do início da florescência. Observou-se que tratamento com CCC e TIBA reduzi ramo peso da matéria seca do caule da soja. Aplicação de TIBA diminuiu o peso da palha das vagens, número e peso das sementes de soja 'Davis'

Conditional Cash Transfers for Women and Spousal Violence: Evidence of the Long-Term Relationship from the Oportunidades Program in Rural Mexico

This paper provides evidence of the long-term relationship between male-to-female spousal violence and the Oportunidades conditional cash transfer program. It uses data from three nationally representative surveys that include detailed information on the prevalence of spousal abuse and threats of violence against women. Constructing comparable groups of beneficiary and nonbeneficiary households within each village to minimize potential selection biases, the present study finds that, in contrast to the short-run estimates, physical and emotional abuse rates over the long term do not differ significantly between existing beneficiary and nonbeneficiary couples. The paper examines possible causes for the difference, most importantly, the role that marital selection and the diffusion of norms rejecting intimate partner violence may play in explaining these effects

Increasing the dimension of linear systems solved by classical or quantum binary optimization: A new method to solve large linear equation systems

Recently, binary optimization has become an attractive research topic due to the development of quantum computing and specialized classical systems inspired by quantum computing. These hardware systems promise to speed up the computation significantly. In this work, we propose a new method to solve linear systems written as a binary optimization problem. The procedure solves the problem efficiently and allows it to handle large linear systems. Our approach is founded on the geometry of the original linear problem and resembles the gradient conjugate method. The conjugated directions used can significantly improve the algorithm's convergence rate. We also show that a partial knowledge of the intrinsic geometry of the problem can divide the original problem into independent sub-problems of smaller dimensions. These sub-problems can then be solved using quantum or classical solvers. Although determining the geometry of the problem has an additional computational cost, it can substantially improve the performance of our method compared to previous implementations.Comment: 12 pages, 10 figure

Action of growth regulators on flowering and pod production of soybean cultivar Davis

This research deals with the effects of growth regulators on flowering and pod formation in soybean plant (Glycine max cv. Davis). Under greenhouse conditions, soybean plants were sprayed with 2,3,5-triiodobenzoic acid (TIBA) 20 ppm, Agrostemmin (1g/10 ml/3 l) gibberellic acid (GA) 100 ppm, and (2-chloroethyl) trimethylammonium chloride (CCC) 2,000 ppm. Application of TIBA increased number of flowers. 'Davis' soybean treated with CCC and TIBA presented a tendency to produce a lower number of pods.Observou-se em condições de casa de vegetação o efeito de fitoreguladores na florescência e produção de vagens da soja (Glycine max cv. Davis). Antes da florescência, a plicou-se em pulverização foliar Agrostemin (1 g/10 ml/3 D, ácido giberélico (GA) 100 ppm e cloreto (2-cloroetil) trimetilamonio(CCC) 2.000 ppm, além do controle. Foi também aplicado o ácido 2,3,5 - triiodobenzóico (TIBA) 20 ppm, por três vezes, com quatro dias de intervalo a partir do início do florescimento. Verificou-se que o TIBA aumentou a florescência das plantas de soja. Tratamento com CCC e TIBA reduziram o número de vagens produzidas pela soja 'Davis'

Kinetic Approach to Multilayer Sorption: Equations of Isotherm and Applications

An analytical isotherm equation that describes the multilayer adsorption on fractal surfaces with adsorbate-adsorbate interactions (measured in terms of free energy) different from that of bulk liquid was developed. Assuming mathematical functionalities for the variation of the free energy, it is possible to evaluate the influence of the adsorbate-adsorbate interactions on the adsorption capacity of solids of high degree of surface irregularity. For those surfaces with relatively low degree of irregularity, it results that the free energy variation with the layer number in the multilayer region affects considerably the sorption capacity of the adsorbent, even for water activities lower than those corresponding to the monolayer moisture content. The energy interactions between adjacent adsorbate layers become less important as the fractal dimension of the adsorbent increases. For a fractal surface, the growing of the multilayer seems to mainly controlled by the degree of surface roughness characteristic of microporous adsorbents, where the volume and pore dimension are the true limitants to the sorption capacity. The isotherm equations obtained were tested fitting published experimental equilibrium data of various water vapor-biopolymer systems

Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells

Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFil: D'Urso, C.. Centro Nazionale della Ricerca. ITAE; ItaliaFil: Bonesi, Alejandro Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Triaca, Walter Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Castro Luna Berenguer, Ana Maria del Carmen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico la Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina. Universidad Nacional de La Plata; ArgentinaFil: Baglio, V.. Centro Nazionale della Ricerca. ITAE; Italia; ItaliaFil: Aricò, A. S.. Centro Nazionale della Ricerca. ITAE; Italia; Itali

Pt–Fe cathode catalysts to improve the oxygen reduction reaction and methanol tolerance in direct methanol fuel cells

High surface area carbon-supported Pt and bimetallic Pt–Fe catalysts are investigated for the oxygen electro-reduction reaction (ORR) in low-temperature direct methanol fuel cells (60 °C). The electrocatalysts are prepared using a combination of colloidal and incipient wetness methods allowing the synthesis of carbon-supported bimetallic nanoparticles with a particle size of about 2–3 nm. These materials are studied in terms of structure, morphology and composition using X-ray diffraction, X-ray fluorescence and transmission electron microscopy techniques. The electrocatalytic behaviour of these catalysts for ORR is investigated by employing the rotating disc technique. An enhancement of the ORR is observed with the bimetallic Pt–Fe catalyst in the oxygen-saturated electrolyte solution, with and without methanol.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicada

Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells

Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFacultad de Ciencias ExactasInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicada

Synthesis, Characterization and Electrocatalytic Activity of Bi- and Tri-metallic Pt-Based Anode Catalysts for Direct Ethanol Fuel Cells

Three Pt-based anode catalysts supported on Vulcan XC-72R (VC) were prepared by using a modified polyol process. These materials were characterized and tested by X-Ray Diffraction (XRD), X-Ray Fluorescence (XRF) and Transmission Electron Microscopy (TEM). XRD and TEM analysis indicated that especially the ternary anode catalysts consisted of uniform nanosized particles with sharp distribution. The Pt lattice parameter was smaller, in the ternary PtSnIr catalyst whereas it increased with the addition of Sn and Rh, in the corresponding binary and ternary catalysts. Cyclic voltammetry (CV) measurements showed that Sn, Ir and Rh may act as promoter of Pt enhancing ethanol electro-oxidation activity. It was found that the direct ethanol fuel cell (DEFC) performances were significantly improved with these modified anode catalysts. This effect on the DEFC performance is attributed to the so-called bi-tri-functional mechanism and to the electronic interaction between Pt and additives. The performance increased significantly with the temperature. However, it was also possible to observe some decay with time for all catalysts due to the formation of surface poisons, probably consisting in CO-like species. At 60 °C, the PtSnIr catalyst showed the best performance, as a result of a proper morphology and promoting effectFacultad de Ciencias ExactasInstituto de Investigaciones Fisicoquímicas Teóricas y Aplicada