Growth, Conductivity, and Vapor Response Properties of Metal Ion-Carboxylate linked Nanoparticle Films

Nanoparticles of metals (Au, Ag, Pd, alloys) in the size range 1–3 nm diameter can be stabilized against aggregation of the metal particles by coating the metal surface with a dense monolayer of ligands (thiolates). The stabilization makes it possible to analytically define the nanoparticle composition (for example, Au140(hexanethiolate)53, I) and to elaborate the chemical functionality of the protecting monolayer (for example, Au140(C6)35(MUA)18, II, where C6 = hexanethiolate and MUA = mercaptoundecanoic acid). Network polymer films (IIfilm) on interdigitated array electrodes can be prepared from II, based on cation coordination (i.e., Cu2+, Zn2+, Ag+, methyl viologen) by the carboxylates of MUA. The electronic conductivity of the IIfilm network polymer films occurs by electron hopping between the Au140 nanoparticle cores, and offers an avenue for investigation of metal-to-metal nanoparticle electron transfer chemistry. The report begins with a brief summary of what is known about metal nanoparticle electron transfer chemistry. The investigation goes on to assess factors that influence the dynamics of film formation as well as film conductivity, in the interest of better understanding the parameters affecting electron hopping rates in IIfilm network polymer films. Finally, sorption of organic vapors into IIfilm causes a decreased electronic conductivity and increased mass that can be assessed using quartz crystal microbalance measurements. The change in electronic conductivity can be exploited for the sensing of organic vapors

Search for the Standard Model Higgs Boson with the OPAL Detector at LEP

This paper summarises the search for the Standard Model Higgs boson in e+e- collisions at centre-of-mass energies up to 209 GeV performed by the OPAL Collaboration at LEP. The consistency of the data with the background hypothesis and various Higgs boson mass hypotheses is examined. No indication of a signal is found in the data and a lower bound of 112.7GeV/C^2 is obtained on the mass of the Standard Model Higgs boson at the 95% CL.Comment: 51 pages, 21 figure

Measurement of the Hadronic Photon Structure Function F_2^gamma at LEP2

The hadronic structure function of the photon F_2^gamma is measured as a function of Bjorken x and of the factorisation scale Q^2 using data taken by the OPAL detector at LEP. Previous OPAL measurements of the x dependence of F_2^gamma are extended to an average Q^2 of 767 GeV^2. The Q^2 evolution of F_2^gamma is studied for average Q^2 between 11.9 and 1051 GeV^2. As predicted by QCD, the data show positive scaling violations in F_2^gamma. Several parameterisations of F_2^gamma are in agreement with the measurements whereas the quark-parton model prediction fails to describe the data.Comment: 4 pages, 2 figures, to appear in the proceedings of Photon 2001, Ascona, Switzerlan

Search for R-Parity Violating Decays of Scalar Fermions at LEP

A search for pair-produced scalar fermions under the assumption that R-parity is not conserved has been performed using data collected with the OPAL detector at LEP. The data samples analysed correspond to an integrated luminosity of about 610 pb-1 collected at centre-of-mass energies of sqrt(s) 189-209 GeV. An important consequence of R-parity violation is that the lightest supersymmetric particle is expected to be unstable. Searches of R-parity violating decays of charged sleptons, sneutrinos and squarks have been performed under the assumptions that the lightest supersymmetric particle decays promptly and that only one of the R-parity violating couplings is dominant for each of the decay modes considered. Such processes would yield final states consisting of leptons, jets, or both with or without missing energy. No significant single-like excess of events has been observed with respect to the Standard Model expectations. Limits on the production cross- section of scalar fermions in R-parity violating scenarios are obtained. Constraints on the supersymmetric particle masses are also presented in an R-parity violating framework analogous to the Constrained Minimal Supersymmetric Standard Model.Comment: 51 pages, 24 figures, Submitted to Eur. Phys. J.

Determination of the b Quark Mass at the Z Mass Scale

In hadronic decays of Z bosons recorded with the OPAL detector at LEP, events containing b quarks were selected using the long lifetime of b flavoured hadrons. Comparing the 3-jet rate in b events with that in d u,s and c quark events, a significant difference was observed. Using Order(alpha_s squared) calculations for massive quarks, this difference was used to determine the b quark mass in the MSbar renormalisation scheme at the scale of the Z boson mass. By combining the results from seven different jet finders the running b quark mass was determined to be mb(MZ) = (2.67 +/- 0.03(stat) +0.29/-0.37(syst) +/- 0.19(theo.)) GeV. Evolving this value to the b quark mass scale itself yields mb(mb) = (3.95 +0.52/-0.62) GeV, consistent with results obtained at the b quark production threshold. This determination confirms the QCD expectation of a scale dependent quark mass. A constant mass is ruled out by 3.9 standard deviations

A Search for a Narrow Radial Excitation of the D∗±D^{*\pm} Meson

A sample of 3.73 million hadronic Z decays, recorded with the OPAL detector at LEP in the years 1991-95, has been used to search for a narrow resonance corresponding to the decay of the D*'+/-(2629) meson into D*+/- pi+ pi-. The D*+ mesons are reconstructed in the decay channel D*+ -> D0 pi+ with D0 -> K- pi+. No evidence for a narrow D*'+/-(2629) resonance is found. A limit on the production of D*'+/-(2629) in hadronic Z decays is derived: f(Z -> D*'+/-(2629)) x Br(D*'+ -> D*+ pi+ pi-) D0 pi+ with D0 -> K- pi+. No evidence for a narrow D*'+/-(2629) resonance is found. A limit on the production of D*'+/-(2629) in hadronic Z decays is derived: f(Z -> D*'+/-(2629)) x Br(D*'+ -> D*+ pi+ pi-) < 3.1 x 10^{-3} (95% C.L.

A Study of One-Prong Tau Decays with a Charged Kaon

From an analysis of the ionisation energy loss of charged particles selected from 110326 e+e- -> tau+tau- candidates recorded by the OPAL detector at e+e- centre-of-mass energies near the Z0 resonance, we determine the one-prong tau decay branching ratios: Br(tau- -> nu_tau K- >=0h0) = 1.528 +- 0.039 +- 0.040 % Br(tau- -> nu_tau K-) = 0.658 +- 0.024 +- 0.029 % where the h0 notation refers to a pi0, an eta, a K^0_S, or a K^0_L, and where the first uncertainty is statistical and the second is systematic.From an analysis of the ionisation energy loss of charged particles selected from 110326 e+e- -> tau+tau- candidates recorded by the OPAL detector at e+e- centre-of-mass energies near the Z0 resonance, we determine the one-prong tau decay branching ratios: Br(tau- -> nu_tau K- >=0h0) = 1.528 +- 0.039 +- 0.040 % Br(tau- -> nu_tau K-) = 0.658 +- 0.024 +- 0.029 % where the h0 notation refers to a pi0, an eta, a K^0_S, or a K^0_L, and where the first uncertainty is statistical and the second is systematic

First Measurement of the Inclusive Branching Ratio of b Hadrons →ϕ\to \phi Mesons in Z0Z^{0} Decays

The inclusive production rate of phi mesons from the decay of b hadrons produced in Z0 decays was measured to be Br(b->phi+X) = 0.0282+-0.0013(stat.)+-0.0019(syst.), using data collected by the OPAL detector at LEP.The inclusive branching fraction of φ mesons from the decay of b hadrons produced in Z decays was measured to be Br(b→ φ X)=0.0282±0.0013 (stat.)±0.0019 (syst.), using data collected by the OPAL detector at LEP.The inclusive production rate of phi mesons from the decay of b hadrons produced in Z0 decays was measured to be Br(b->phi+X) = 0.0282+-0.0013(stat.)+-0.0019(syst.), using data collected by the OPAL detector at LEP

Multiplicities of π0\pi^{0}, η\eta, K0K^{0} and of charged particles in quark and gluon jets

We compared the multiplicities of pizero, eta, Kzero and of charged particles in quark and gluon jets in 3-jet events, as measured by the OPAL experiment at LEP. The comparisons were performed for distributions unfolded to 100% pure quark and gluon jets, at an effective scale Qjet which took into account topological dependences of the 3-jet environment. The ratio of particle multiplicity in gluon jets to that in quark jets as a function of Qjet for pizero, eta and Kzero was found to be independent of the particle species. This is consistent with the QCD prediction that the observed enhancement in the mean particle rate in gluon jets with respect to quark jets should be independent of particle species. In contrast to some theoretical predictions and previous observations, we observed no evidence for an enhancement of eta meson production in gluon jets with respect to quark jets, beyond that observed for charged particles. We measured the ratio of the slope of the average charged particle multiplicity in gluon jets to that in quark jets, C, and we compared it to a next-to-next-to-next-to leading order calculation. Our result, C=2.27+-0.20(stat+syst),is about one standard deviation higher than the perturbative prediction.We compared the multiplicities of pizero, eta, Kzero and of charged particles in quark and gluon jets in 3-jet events, as measured by the OPAL experiment at LEP. The comparisons were performed for distributions unfolded to 100% pure quark and gluon jets, at an effective scale Qjet which took into account topological dependences of the 3-jet environment. The ratio of particle multiplicity in gluon jets to that in quark jets as a function of Qjet for pizero, eta and Kzero was found to be independent of the particle species. This is consistent with the QCD prediction that the observed enhancement in the mean particle rate in gluon jets with respect to quark jets should be independent of particle species. In contrast to some theoretical predictions and previous observations, we observed no evidence for an enhancement of eta meson production in gluon jets with respect to quark jets, beyond that observed for charged particles. We measured the ratio of the slope of the average charged particle multiplicity in gluon jets to that in quark jets, C, and we compared it to a next-to-next-to-next-to leading order calculation. Our result, C=2.27+-0.20(stat+syst),is about one standard deviation higher than the perturbative prediction

Measurements of RbR_{b}, AFBbA_{FB}^{b} and AFBcA_{FB}^{c} in e+e−e^{+}e^{-} Collisions at 130-189 GeV

The cross-section ratio Rb=sigma(e+e- to b-antib)/sigma(e+e- to q-antiq) andthe bottom and charm forward-backward asymmetries AFB^b and AFB^c are measuredusing event samples collected by the OPAL detector at centre-of-mass energiesbetween 130 and 189 GeV. Events with bottom quark production are selected witha secondary vertex tag, and a hemisphere charge algorithm is used to extractAFB^b. In addition, the bottom and charm asymmetries are measured using leptonsfrom semileptonic decays of heavy hadrons and pions from D*+ to D0pi+ decays.The results are in agreement with the Standard Model predictions.The cross-section ratio Rb=sigma(e+e- to b-antib)/sigma(e+e- to q-antiq) and the bottom and charm forward-backward asymmetries AFB^b and AFB^c are measured using event samples collected by the OPAL detector at centre-of-mass energies between 130 and 189 GeV. Events with bottom quark production are selected with a secondary vertex tag, and a hemisphere charge algorithm is used to extract AFB^b. In addition, the bottom and charm asymmetries are measured using leptons from semileptonic decays of heavy hadrons and pions from D*+ to D0pi+ decays. The results are in agreement with the Standard Model predictions