Imide/arylene ether copolymers

Imide/arylene ether block copolymers are prepared by reacting anhydride terminated poly(amic acids) with amine terminated poly(arylene ethers) in polar aprotic solvents and by chemically or thermally cyclodehydrating the resulting intermediate poly(amic acids). The resulting block copolymers have one glass transition temperature or two, depending upon the particular structure and/or the compatibility of the block units. Most of these block copolymers form tough, solvent resistant films with high tensile properties

A LANCASTERIAN APPROACH FOR SPECIFYING DERIVED DEMANDS FOR RECREATIONAL ACTIVITIES

Demand and Price Analysis,

Telepresence and Space Station Freedom workstation operations

The Space Station Freedom workstation system is a distributed network of computer based workstations that provides the man-machine interfaces for controlling space station systems. This includes control of external manipulator, robotic and free flyer devices by crewmembers in the space station's pressurized shirt-sleeve environment. These remotely controlled devices help minimize the requirement for costly crew extravehicular activity (EVA) time for such tasks as station assembly and payload support. Direct window views may be used for controlling some of the systems, but many activities will be remote or require levels of detail not possible by direct observation. Since controlling remote devices becomes more difficult when direct views are inadequate or unavailable, many performance enhancing techniques have been considered for representing information about remote activities to the operator. Described here are the telepresence techniques under consideration to support operations and training. This includes video enhancements (e.g., graphic and text overlays and stereo viewing), machine vision systems, remote activity animation, and force reflection representation

Spin dynamics in the ordered spin ice Tb2_2Sn2_2O7_7

Geometrical frustration is a central challenge in contemporary condensed matter physics, a crucible favourable to the emergence of novel physics. The pyrochlore magnets, with rare earth magnetic moments localized at the vertices of corner-sharing tetrahedra, play a prominent role in this field, with a rich variety of exotic ground states ranging from the "spin ices" \hoti\ and \dyti\ to the "spin liquid" and "ordered spin ice" ground states in \tbti\ and \tbsn. Inelastic neutron scattering provides valuable information for understanding the nature of these ground states, shedding light on the crystal electric field (CEF) level scheme and on the interactions between magnetic moments. We have performed such measurements with unprecedented neutron flux and energy resolution, in the "ordered spin ice" \tbsn. We argue that a new interaction, which involves the spin lattice coupling through a low temperature distortion of the trigonal crystal field, is necessary to account for the data

Kinks in the Presence of Rapidly Varying Perturbations

Dynamics of sine-Gordon kinks in the presence of rapidly varying periodic perturbations of different physical origins is described analytically and numerically. The analytical approach is based on asymptotic expansions, and it allows to derive, in a rigorous way, an effective nonlinear equation for the slowly varying field component in any order of the asymptotic procedure as expansions in the small parameter $\omega^{-1}$, $\omega$ being the frequency of the rapidly varying ac driving force. Three physically important examples of such a dynamics, {\em i.e.}, kinks driven by a direct or parametric ac force, and kinks on rotating and oscillating background, are analysed in detail. It is shown that in the main order of the asymptotic procedure the effective equation for the slowly varying field component is {\em a renormalized sine-Gordon equation} in the case of the direct driving force or rotating (but phase-locked to an external ac force) background, and it is {\em the double sine-Gordon equation} for the parametric driving force. The properties of the kinks described by the renormalized nonlinear equations are analysed, and it is demonstrated analytically and numerically which kinds of physical phenomena may be expected in dealing with the renormalized, rather than the unrenormalized, nonlinear dynamics. In particular, we predict several qualitatively new effects which include, {\em e.g.}, the perturbation-inducedComment: New copy of the paper of the above title to replace the previous one, lost in the midst of the bulletin board. RevTeX 3.

Phenylethynyl terminated reactive oligomer

A composition of matter having the general structure: ##STR1## (wherein X is F, Cl, or NO.sub.2, and Y is CO, SO.sub.2 or C(CF.sub.3).sub.2) is employed to terminate a nucleophilic reagent, resulting in the exclusive production of phenylethynyl terminated reactive oligomers which display unique thermal characteristics. A reactive diluent having the general structure: ##STR2## (wherein R is any aliphatic or aromatic moiety) is employed to decrease the melt viscosity of a phenylethynyl terminated reactive oligomer and to subsequently react therewith to provide a thermosetting material of enhanced density. These materials have features which make them attractive candidates for use as composite matrices and adhesives

Condicionamento operante e autisrno infantil

Este artigo propõe-se dar uma perspectiva funcional ou comportamental como método, na alteração do comportamento de crianças autistas. Princípios do condicionamento operante: quando os condicionadores operantes se referem ao comportamento, estão-se a referir a um tipo específico de comportamento, isto é, um comportamento que é emitido ou evocado. O condicionador operante fala do comportamento que ocorre na presença de acontecimentos ambientais. Para ele, o comportamento observável torna-se num dos elementos dominantes da sua matéria de estudo. Todos os Programas de Tratamento para crianças autistas, devem ter em conta a relação entre acontecimentos antecedentes e o comportamento dessas crianças, devendo também incluir o controlo de estímulos através de um programa que discrimine certos aspectos do ambiente. O método de modificação do comportamento insiste na observação e registo de comportamentos claramente definidos. Contudo, essa observação e registo não indicam apenas a intensidade, fraqueza ou alterações deste, mas também se o comportamento varia muito de um para o outro com frequência

Phenylethynyl reactive diluents

A composition of matter having a specified general structure is employed to terminate a nucleophilic reagent, resulting in the exclusive production of phenylethynyl terminated reactive oligomers which display unique thermal characteristics. A reactive diluent having a specified general structure is employed to decrease the melt viscosity of a phenylethynyl terminated reactive oligomer and to subsequently react with to provide a thermosetting material of enhanced density. These materials have features which make them attractive candidates for use as composite matrices and adhesives

Phenylethynyl endcapping reagents and reactive diluents

A phenylethynyl composition which can be used to endcap nucleophilic species is employed in the production of phenylethynyl terminated reactive oligomers exclusively. These phenylethynyl terminated reactive oligomers display unique thermal characteristics, as exemplified by the model compound, 4-phenoxy 4'-phenylethynylbenzophenone, which is relatively stable at 200 C, but reacts at 350 C. In addition, a reactive diluent was prepared which decreases the melt viscosity of the phenylethynyl terminated oligomers and subsequently reacts therewith to increase density of the resulting thermoset. The novelty of this invention resides in the phenylethynyl composition used to terminate a nucleophilic reagent, resulting in the exclusive production of phenylethynyl terminated reactive oligomers which display unique thermal characteristics. A reactive diluent was also employed to decrease the melt viscosity of a phenylethynyl terminated reactive oligomer and to subsequently react therewith to increase the crosslink density of the resulting thermoset. These materials have features which make them attractive candidates for use as composite matrices and adhesives