Protonated CO2 in massive star-forming clumps

Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated form, HOCO+, is believed to be a good proxy for gaseous CO2. However, it has been detected in only a few star-forming regions so far, so that its interstellar chemistry is not well understood. We present new detections of HOCO+ lines in 11 high-mass star-forming clumps. Our observations increase by more than three times the number of detections in star-forming regions so far. We have derived beam-averaged abundances relative to H2 in between 0.3 and 3.8 x 10^{-11}. We have compared these values with the abundances of H13CO+, a possible gas-phase precursor of HOCO+, and CH3OH, a product of surface chemistry. We have found a positive correlation with H13CO+, while with CH3OH there is no correlation. We suggest that the gas-phase formation route starting from HCO+ plays an important role in the formation of HOCO+, perhaps more relevant than protonation of CO2 (upon evaporation of this latter from icy dust mantles).Comment: 5 pages, 4 figures, 1 table, accepted for publication in MNRA

ALMA Observations of Ethyl Formate toward Orion KL

Orion KL is one of the prime templates of astrochemical and prebiotic chemical studies. We wish to explore more organic molecules with increasing complexity in this region. In particular, we have searched for one of the most complex organic molecules detected in space so far, ethyl formate (C$_{2}$H$_{5}$OCHO). This species is the next step in chemical complexity after the simplest member of esters (methyl formate, CH$_{3}$OCHO). The mechanisms leading to its formation are still poorly known. We have used high angular resolution ($\sim$ 1.$^{\prime\prime}$5) ALMA observations covering a large bandwidth from 214 to 247 GHz. We have detected 82 unblended lines of C$_{2}$H$_{5}$OCHO (49 and 33 of the trans and gauche conformers, respectively). The line images showed that C$_{2}$H$_{5}$OCHO arises mainly from the compact ridge and the hot core-southwest regions. The derived rotational temperatures and column densities are 122 $\pm$ 34 K, (0.9 $\pm$ 0.3) $\times$ 10$^{16}$ cm$^{-2}$ for the hot core-SW, and 103 $\pm$ 13 K, (0.6 $\pm$ 0.3) $\times$ 10$^{16}$ cm$^{-2}$ for the compact ridge. The comparison of spatial distribution and abundance ratios with chemically related molecules (methyl formate, ethanol and formic acid) indicates that C$_{2}$H$_{5}$OCHO is likely formed on the surface of dust grains by addition of CH$_{3}$ to functional-group radicals (CH$_{2}$OCHO) derived from methyl formate (CH$_{3}$OCHO)

The role of low-mass star clusters in massive star formation. The Orion Case

To distinguish between the different theories proposed to explain massive star formation, it is crucial to establish the distribution, the extinction, and the density of low-mass stars in massive star-forming regions. We analyze deep X-ray observations of the Orion massive star-forming region using the Chandra Orion Ultradeep Project (COUP) catalog. We studied the stellar distribution as a function of extinction, with cells of 0.03 pc x 0.03 pc, the typical size of protostellar cores. We derived stellar density maps and calculated cluster stellar densities. We found that low-mass stars cluster toward the three massive star-forming regions: the Trapezium Cluster (TC), the Orion Hot Core (OHC), and OMC1-S. We derived low-mass stellar densities of 10^{5} stars pc^{-3} in the TC and OMC1-S, and of 10^{6} stars pc^{-3} in the OHC. The close association between the low-mass star clusters with massive star cradles supports the role of these clusters in the formation of massive stars. The X-ray observations show for the first time in the TC that low-mass stars with intermediate extinction are clustered toward the position of the most massive star, which is surrounded by a ring of non-extincted low-mass stars. This 'envelope-core' structure is also supported by infrared and optical observations. Our analysis suggests that at least two basic ingredients are needed in massive star formation: the presence of dense gas and a cluster of low-mass stars. The scenario that better explains our findings assumes high fragmentation in the parental core, accretion at subcore scales that forms a low-mass stellar cluster, and subsequent competitive accretion. Finally, although coalescence does not seem a common mechanism for building up massive stars, we show that a single stellar merger may have occurred in the evolution of the OHC cluster, favored by the presence of disks, binaries, and gas accretion.Comment: 17 pages, 11 figures, 3 Tables. Accepted for publication in A&

On the chemical ladder of esters. Detection and formation of ethyl formate in the W51 e2 hot molecular core

The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of molecules with astrobiological interest are the esters, whose simplest member, methyl formate, is rather abundant in star-forming regions. The next step in the chemical complexity of esters is ethyl formate, C$_2$H$_5$OCHO. Only two detections of this species have been reported so far, which strongly limits our understanding of how complex molecules are formed in the interstellar medium. We have searched for ethyl formate towards the W51 e2 hot molecular core, one of the most chemically rich sources in the Galaxy and one of the most promising regions to study prebiotic chemistry, especially after the recent discovery of the P$-$O bond, key in the formation of DNA. We have analyzed a spectral line survey towards the W51 e2 hot molecular core, which covers 44 GHz in the 1, 2 and 3 mm bands, carried out with the IRAM 30m telescope. We report the detection of the trans and gauche conformers of ethyl formate. A Local Thermodynamic Equilibrium analysis indicates that the excitation temperature is 78$\pm$10 K and that the two conformers have similar source-averaged column densities of (2.0$\pm$0.3)$\times$10$^{16}$ cm$^{-2}$ and an abundance of $\sim$10$^{-8}$. We compare the observed molecular abundances of ethyl formate with different competing chemical models based on grain surface and gas-phase chemistry. We propose that grain-surface chemistry may have a dominant role in the formation of ethyl formate (and other complex organic molecules) in hot molecular cores, rather than reactions in the gas phase.Comment: Accepted in A&A; 11 pages, 6 figures, 7 Table

First ALMA maps of HCO, an important precursor of complex organic molecules, towards IRAS 16293-2422

The formyl radical HCO has been proposed as the basic precursor of many complex organic molecules such as methanol (CH$_3$OH) or glycolaldehyde (CH$_2$OHCHO). Using ALMA, we have mapped, for the first time at high angular resolution ($\sim$1$^{\prime\prime}$, $\sim$140 au), HCO towards the Solar-type protostellar binary IRAS 16293$-$2422, where numerous complex organic molecules have been previously detected. We also detected several lines of the chemically related species H$_2$CO, CH$_3$OH and CH$_2$OHCHO. The observations revealed compact HCO emission arising from the two protostars. The line profiles also show redshifted absorption produced by foreground material of the circumbinary envelope that is infalling towards the protostars. Additionally, IRAM 30m single-dish data revealed a more extended HCO component arising from the common circumbinary envelope. The comparison between the observed molecular abundances and our chemical model suggests that whereas the extended HCO from the envelope can be formed via gas-phase reactions during the cold collapse of the natal core, the HCO in the hot corinos surrounding the protostars is predominantly formed by the hydrogenation of CO on the surface of dust grains and subsequent thermal desorption during the protostellar phase. The derived abundance of HCO in the dust grains is high enough to produce efficiently more complex species such as H$_2$CO, CH$_3$OH, and CH$_2$OHCHO by surface chemistry. We found that the main formation route of CH$_2$OHCHO is the reaction between HCO and CH$_2$OH.Comment: Accepted in Monthly Notices of the Royal Astronomical Society; 19 pages, 12 figures, 7 table

Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.Comment: Accepted in Monthly Notices of the Royal Astronomical Society Letter