1,847 research outputs found
Kinetics of the Reactions of CH2Cl, CH3CHCl, and CH3CCl2 Radicals with Cl2 in the Temperature Range 191-363 K
Peer reviewe
MDL Convergence Speed for Bernoulli Sequences
The Minimum Description Length principle for online sequence
estimation/prediction in a proper learning setup is studied. If the underlying
model class is discrete, then the total expected square loss is a particularly
interesting performance measure: (a) this quantity is finitely bounded,
implying convergence with probability one, and (b) it additionally specifies
the convergence speed. For MDL, in general one can only have loss bounds which
are finite but exponentially larger than those for Bayes mixtures. We show that
this is even the case if the model class contains only Bernoulli distributions.
We derive a new upper bound on the prediction error for countable Bernoulli
classes. This implies a small bound (comparable to the one for Bayes mixtures)
for certain important model classes. We discuss the application to Machine
Learning tasks such as classification and hypothesis testing, and
generalization to countable classes of i.i.d. models.Comment: 28 page
Isomeric states close to doubly magic Sn studied with JYFLTRAP
The double Penning trap mass spectrometer JYFLTRAP has been employed to
measure masses and excitation energies for isomers in Cd,
Cd, Cd and Te, for isomers in In and
In, and for isomers in Sn and Sb. These first
direct mass measurements of the Cd and In isomers reveal deviations to the
excitation energies based on results from beta-decay experiments and yield new
information on neutron- and proton-hole states close to Sn. A new
excitation energy of 144(4) keV has been determined for Cd. A good
agreement with the precisely known excitation energies of Cd,
Sn, and Sb has been found.Comment: 10 pages, 6 figures, submitted to Phys. Rev.
An aldehyde as a rapid source of secondary aerosol precursors: theoretical and experimental study of hexanal autoxidation
Aldehydes are common constituents of natural and polluted atmospheres,
and their gas-phase oxidation has recently been reported to yield
highly oxygenated organic molecules (HOMs) that are key players in the
formation of atmospheric aerosol. However, insights into the molecular-level mechanism of this oxidation reaction have been scarce. While OH
initiated oxidation of small aldehydes, with two to five carbon atoms,
under high-NOx conditions generally leads to
fragmentation products, longer-chain aldehydes involving an initial
non-aldehydic hydrogen abstraction can be a path to molecular
functionalization and growth. In this work, we conduct a joint
theoreticalâexperimental analysis of the autoxidation chain reaction
of a common aldehyde, hexanal. We computationally study the initial
steps of OH oxidation at the
RHF-RCCSD(T)-F12a/VDZ-F12//ÏB97X-D/aug-cc-pVTZ level and show that
both aldehydic (on C1) and non-aldehydic (on C4) H-abstraction
channels contribute to HOMs via autoxidation. The oxidation products
predominantly form through the HÂ abstraction from C1 and C4, followed
by fast unimolecular 1,6 H-shifts with rate coefficients of 1.7Ă10-1 and 8.6Ă10-1âsâ1, respectively.
Experimental flow reactor measurements at variable reaction times show
that hexanal oxidation products including HOM monomers up to
C6H11O7 and accretion products C12H22O9â10
form within 3âs reaction time. Kinetic modeling simulations including
atmospherically relevant precursor concentrations agree with the
experimental results and the expected timescales. Finally, we estimate
the hexanal HOM yields up to seven O atoms with mechanistic details
through both C1 and C4 channels.</p
Precision mass measurements of radioactive nuclei at JYFLTRAP
The Penning trap mass spectrometer JYFLTRAP was used to measure the atomic
masses of radioactive nuclei with an uncertainty better than 10 keV. The atomic
masses of the neutron-deficient nuclei around the N = Z line were measured to
improve the understanding of the rp-process path and the SbSnTe cycle.
Furthermore, the masses of the neutron-rich gallium (Z = 31) to palladium (Z =
46) nuclei have been measured. The physics impacts on the nuclear structure and
the r-process paths are reviewed. A better understanding of the nuclear
deformation is presented by studying the pairing energy around A = 100.Comment: 4 pages and 4 figures, RNB7 conf. pro
Mutual Information of Population Codes and Distance Measures in Probability Space
We studied the mutual information between a stimulus and a large system
consisting of stochastic, statistically independent elements that respond to a
stimulus. The Mutual Information (MI) of the system saturates exponentially
with system size. A theory of the rate of saturation of the MI is developed. We
show that this rate is controlled by a distance function between the response
probabilities induced by different stimuli. This function, which we term the
{\it Confusion Distance} between two probabilities, is related to the Renyi
-Information.Comment: 11 pages, 3 figures, accepted to PR
Sequence alignment, mutual information, and dissimilarity measures for constructing phylogenies
Existing sequence alignment algorithms use heuristic scoring schemes which
cannot be used as objective distance metrics. Therefore one relies on measures
like the p- or log-det distances, or makes explicit, and often simplistic,
assumptions about sequence evolution. Information theory provides an
alternative, in the form of mutual information (MI) which is, in principle, an
objective and model independent similarity measure. MI can be estimated by
concatenating and zipping sequences, yielding thereby the "normalized
compression distance". So far this has produced promising results, but with
uncontrolled errors. We describe a simple approach to get robust estimates of
MI from global pairwise alignments. Using standard alignment algorithms, this
gives for animal mitochondrial DNA estimates that are strikingly close to
estimates obtained from the alignment free methods mentioned above. Our main
result uses algorithmic (Kolmogorov) information theory, but we show that
similar results can also be obtained from Shannon theory. Due to the fact that
it is not additive, normalized compression distance is not an optimal metric
for phylogenetics, but we propose a simple modification that overcomes the
issue of additivity. We test several versions of our MI based distance measures
on a large number of randomly chosen quartets and demonstrate that they all
perform better than traditional measures like the Kimura or log-det (resp.
paralinear) distances. Even a simplified version based on single letter Shannon
entropies, which can be easily incorporated in existing software packages, gave
superior results throughout the entire animal kingdom. But we see the main
virtue of our approach in a more general way. For example, it can also help to
judge the relative merits of different alignment algorithms, by estimating the
significance of specific alignments.Comment: 19 pages + 16 pages of supplementary materia
Challenges of Religious Literacy in Education : Islam and the Governance of Religious Diversity in Multi-faith Schools
This chapter seeks take part in an emerging research where religion is approached as a whole school endeavor. Previous research and policy recommendations typically focused on teaching about religion in school, but the accommodation of religious diversity in the wider school culture merits more attention. Based on observations in our multiple case studies, we discuss the multi-level governance of religious diversity in Finnish multi-faith schools with a particular focus on the challenges of religious literacy for educators. The three examples we present focus on the inclusion of Muslims in Finnish schools and in particular on the challenges for educator (1) in interpreting the distinction between religion and culture, (2) in recognizing and handling intra-religious diversity, and (3) in being aware of Protestant conceptions of religion and culture. A theme cutting across these examples is how they reflect the tendencies either to see different situations merely through the lens of religion (religionisation), or not to recognize the importance of religion at all (religion-blindness). We argue that religious literacy should be recognized and developed as a vital part of the intercultural competencies of educators.Peer reviewe
Q_EC values of the Superallowed beta-Emitters 10-C, 34-Ar, 38-Ca and 46-V
The Q_EC values of the superallowed beta+ emitters 10-C, 34-Ar, 38-Ca and
46-V have been measured with a Penning-trap mass spectrometer to be 3648.12(8),
6061.83(8), 6612.12(7) and 7052.44(10) keV, respectively. All four values are
substantially improved in precision over previous results.Comment: 9 pages, 7 figures, 5 table
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