The Influence of Galactic Cosmic Rays on Ion-Neutral Hydrocarbon Chemistry in the Upper Atmospheres of Free-Floating Exoplanets

Cosmic rays may be linked to the formation of volatiles necessary for prebiotic chemistry. We explore the effect of cosmic rays in a hydrogen-dominated atmosphere, as a proof-of-concept that ion-neutral chemistry may be important for modelling hydrogen-dominated atmospheres. In order to accomplish this, we utilize Monte Carlo cosmic ray transport models with particle energies of $10^6$ eV $< E < 10^{12}$ eV in order to investigate the cosmic ray enhancement of free electrons in substellar atmospheres. Ion-neutral chemistry is then applied to a Drift-Phoenix model of a free-floating giant gas planet. Our results suggest that the activation of ion-neutral chemistry in the upper atmosphere significantly enhances formation rates for various species, and we find that C$_2$H$_2$, C$_2$H$_4$, NH$_3$, C$_6$H$_6$ and possibly C$_{10}$H are enhanced in the upper atmospheres because of cosmic rays. Our results suggest a potential connection between cosmic ray chemistry and the hazes observed in the upper atmospheres of various extrasolar planets. Chemi-ionization reactions are briefly discussed, as they may enhance the degree of ionization in the cloud layer.Comment: 22 pages, 4 figures. Accepted to the International Journal of Astrobiolog

Lightning and charge processes in brown dwarf and exoplanet atmospheres

The study of the composition of brown dwarf atmospheres helped to understand their formation and evolution. Similarly, the study of exoplanet atmospheres is expected to constrain their formation and evolutionary states. We use results from 3D simulations, kinetic cloud formation and kinetic ion-neutral chemistry to investigate ionisation processes which will affect their atmosphere chemistry: The dayside of super-hot Jupiters is dominated by atomic hydrogen, and not H$_2$O. Such planetary atmospheres exhibit a substantial degree of thermal ionisation and clouds only form on the nightside where lightning leaves chemical tracers (e.g. HCN) for possibly long enough to be detectable. External radiation may cause exoplanets to be enshrouded in a shell of highly ionised, H$_3^+$-forming gas and a weather-driven aurora may emerge. Brown dwarfs enable us to study the role of electron beams for the emergence of an extrasolar, weather-system driven aurora-like chemistry, and the effect of strong magnetic fields on cold atmospheric gases. Electron beams trigger the formation of H$_3^+$ in the upper atmosphere of a brown dwarf (e.g. LSR-J1835) which may react with it to form hydronium, H$_3$O$^+$, as a longer lived chemical tracer. Brown dwarfs and super-hot gas giants may be excellent candidates to search for H$_3$O$^+$ as an H$_3^+$ product.Comment: 16 pages, accepted for publication in the Philosophical Transactions A of the Royal Society, (some typos corrected

Exo-lightning radio emission: the case study of HAT-P-11b

Lightning induced radio emission has been observed on solar system planets. Lecavelier des Etangs et al. [2013] carried out radio transit observations of the exoplanet HAT-P-11b, and suggested a tentative detection of a radio signal. Here, we explore the possibility of the radio emission having been produced by lightning activity on the exoplanet, following and expanding the work of Hodos\'an et al. [2016a]. After a summary of our previous work [Hodos\'an et al. 2016a], we extend it with a parameter study. The lightning activity of the hypothetical storm is largely dependent on the radio spectral roll-off, $n$, and the flash duration, $\tau_\mathrm{fl}$. The best-case scenario would require a flash density of the same order of magnitude as can be found during volcanic eruptions on Earth. On average, $3.8 \times 10^6$ times larger flash densities than the Earth-storms with the largest lightning activity is needed to produce the observed signal from HAT-P-11b. Combined with the results of Hodos\'an et al. [2016a] regarding the chemical effects of planet-wide thunderstorms, we conclude that future radio and infrared observations may lead to lightning detection on planets outside the solar system.Comment: Accepted to the Conference Proceedings of the 8th International Workshop on Planetary, Solar and Heliospheric Radio Emissions (PRE 8), held in Seggauberg near Leibnitz/Graz, Austria, October 25-27, 2016. 12 pages, 2 figure

The US economy from 1992 to 1998: historical and decomposition simulations with the USAGE model

USAGE is a 500 industry dynamic computable general equilibrium model of the US economy being developed at Monash University in collaboration with the US International Trade Commission. In common with the MONASH model of Australia, USAGE is designed for four modes of analysis: Historical, where we estimate changes in technology and consumer preferences; Decomposition, where we explain periods of economic history in terms of driving factors such as changes in technology and consumer preferences; Forecast, where we derive basecase forecasts for industries, occupations and regions that are consistent with trends from historical simulations and with available expert opinions; and Policy, where we derive deviations from basecase forecast paths caused by assumed policies. This paper reports our first set of historical and decomposition results. The historical results quantify several aspects of technical change in US industries for the period 1992 to 1998 including: intermediate-input-saving technical change; primary-factor-saving technical change; labor-capital bias in technical change; and import- domestic bias in technical change. The historical results also quantify shifts in consumer preferences between commodities. The decomposition results are applied in illustrative analyses of growth in US international trade between 1992 and 1998 and of growth in the US steel industry for this period.

Jupiter as a Giant Cosmic Ray Detector

We explore the feasibility of using the atmosphere of Jupiter to detect Ultra-High-Energy Cosmic Rays (UHECR's). The large surface area of Jupiter allows us to probe cosmic rays of higher energies than previously accessible. Cosmic ray extensive air showers in Jupiter's atmosphere could in principle be detected by the Large Area Telescope (LAT) on the Fermi observatory. In order to be observed, these air showers would need to be oriented toward the Earth, and would need to occur sufficiently high in the atmosphere that the gamma rays can penetrate. We demonstrate that, under these assumptions, Jupiter provides an effective cosmic ray "detector" area of $3.3 \times 10^7$ km$^2$. We predict that Fermi-LAT should be able to detect events of energy $>10^{21}$ eV with fluence $10^{-7}$ erg cm$^{-2}$ at a rate of about one per month. The observed number of air showers may provide an indirect measure of the flux of cosmic rays $\gtrsim 10^{20}$ eV. Extensive air showers also produce a synchrotron signature that may be measurable by ALMA. Simultaneous observations of Jupiter with ALMA and Fermi-LAT could be used to provide broad constraints on the energies of the initiating cosmic rays.Comment: 8 pages, 5 figures. Accepted for publication in the Astrophysical Journal Letter

Symmetry violation in quark models of mesons

Constituent and current quark models are employed to discuss many of the SU(3) and SU(2) violating strong and electromagnetic properties of pseudo scalar and vector mesons. The conventional ground state isoscalar meson mixing models are reviewed and extended to include radial excitations in the mass matrix. A phenomenological analysis of symmetry breaking in the models allows a successful simultaneous description of both the vector and pseudoscalar mass spectra, although attempts made to include the high statistics Crystal Ball result for the ratio o = ɼ (Ψ → η 'γ) /ɼ (Ψ → ηγ) = 5.88 ± 1.46 fail. A detailed description of meson radiative decay processes and the ratio of strong production amplitudes a o (π(^-)p→ η 'n) / o(π(^-)p→ηn) in a linear radial mixing model indicates that a consistent description of isoscalar meson properties can be made when p = 3.1, a value considerably less than the Crystal Ball result but in agreement with that obtained by the Dasp collaboration. The model parameters obtained in this analysis allow a satisfactory description of strong two body vector to pseudoscalar meson decays, and subsequent prediction of relationships between amplitudes forsimilar decays of the radial states. The model does not, however, provide an adequate account of the I ≠ O D, D(^*), F, F(^*) and to a lesser extent K and K(^*) meson states, a failing shared by all similar constituent models which are examined. Deficiencies in this description of meson structure which may explain the discrepancies are discussed. "The linear mass model used to predict p = 3.1 provides an ideal frame work for an examination of isospin violating meson properties. The phenomenological addition of strong and electromagnetic isospin violating parameters to the mass matrix allows the prediction of pseudoscalar and vector isoscalar- isovector mixing angles and isomultiplet mass differences. A satisfactory description of these mass differences and the branching ratio B(w → 2π) results, however, a prediction made for the ratio R = ɼ(Ψ'→ π(^o)Ψ) /ɼ(Ψ'→ η Ψ) is much smaller than measured values. The importance of contributions to these results from the isospin violating strong interactions is stressed. A current algebra approach to the ratios p and R is also undertaken. Axial Ward identities which include contributions from the triangle anomaly yield relations between the pseudoscalar meson masses and decay constants. These are included with equations describing P → 2γ decays and the ratio p which together are solved for the decay constants and topological charge components of the π(^o),η and η'. These allow a prediction for the ratio R which agrees with that obtained using the constituent quark model approach but is only half the magnitude of present experimental measurements

A Surface Hydrothermal Source of Nitriles and Isonitriles

Giant impacts can generate transient hydrogen-rich atmospheres, reducing atmospheric carbon. The reduced carbon will form hazes that rain out onto the surface and can become incorporated into the crust. Once heated, a large fraction of the carbon would be converted into graphite. The result is that local regions of the Hadean crust were plausibly saturated with graphite. We explore the consequences of such a crust for a prebiotic surface hydrothermal vent scenario. We model a surface vent fed by nitrogen-rich volcanic gas from high-temperature magmas passing through graphite-saturated crust. We consider this occurring at pressures of 1-1000 bar and temperatures of 1500-1700 degC. The equilibrium with graphite purifies the left-over gas, resulting in substantial quantities of nitriles (0.1% HCN and 1 ppm HC3N) and isonitriles (0.01% HNC) relevant for prebiotic chemistry. We use these results to predict gas-phase concentrations of methyl isonitrile of ~ 1 ppm. Methyl isocyanide can participate in the non-enzymatic activation and ligation of the monomeric building blocks of life, and surface, or shallow, hydrothermal environments provide its only known equilibrium geochemical source.Comment: 26 pages, 17 figures, 2 tables. Accepted for publication in Life (MDPI Journal

Ionisation and discharge in cloud-forming atmospheres of brown dwarfs and extrasolar planets

Brown dwarfs and giant gas extrasolar planets have cold atmospheres with rich chemical compositions from which mineral cloud particles form. Their properties, like particle sizes and material composition, vary with height, and the mineral cloud particles are charged due to triboelectric processes in such dynamic atmospheres. The dynamics of the atmospheric gas is driven by the irradiating host star and/or by the rotation of the objects that changes during its lifetime. Thermal gas ionisation in these ultra-cool but dense atmospheres allows electrostatic interactions and magnetic coupling of a substantial atmosphere volume. Combined with a strong magnetic field , a chromosphere and aurorae might form as suggested by radio and x-ray observations of brown dwarfs. Non-equilibrium processes like cosmic ray ionisation and discharge processes in clouds will increase the local pool of free electrons in the gas. Cosmic rays and lighting discharges also alter the composition of the local atmospheric gas such that tracer molecules might be identified. Cosmic rays affect the atmosphere through air showers in a certain volume which was modelled with a 3D Monte Carlo radiative transfer code to be able to visualise their spacial extent. Given a certain degree of thermal ionisation of the atmospheric gas, we suggest that electron attachment to charge mineral cloud particles is too inefficient to cause an electrostatic disruption of the cloud particles. Cloud particles will therefore not be destroyed by Coulomb explosion for the local temperature in the collisional dominated brown dwarf and giant gas planet atmospheres. However, the cloud particles are destroyed electrostatically in regions with strong gas ionisation. The potential size of such cloud holes would, however, be too small and might occur too far inside the cloud to mimic the effect of, e.g. magnetic field induced star spots

Nitrogen Oxide Concentrations in Natural Waters on Early Earth

A key challenge in origins-of-life studies is estimating the abundances of species relevant to the chemical pathways proposed to have contributed to the emergence of life on early Earth. Dissolved nitrogen oxide anions (NO$_{X}^{-}$), in particular nitrate (NO$_{3}^{-}$) and nitrite (NO$_{2}^{-}$), have been invoked in diverse origins-of-life chemistry, from the oligomerization of RNA to the emergence of protometabolism. Recent work has calculated the supply of NO$_{X}^{-}$ from the prebiotic atmosphere to the ocean, and reported steady-state [NO$_{X}^{-}$] to be high across all plausible parameter space. These findings rest on the assumption that NO$_{X}^{-}$ is stable in natural waters unless processed at a hydrothermal vent. Here, we show that NO$_{X}^{-}$ is unstable in the reducing environment of early Earth. Sinks due to UV photolysis and reactions with reduced iron (Fe$^{2+}$) suppress [NO$_{X}^{-}$] by several orders of magnitude relative to past predictions. For pH$=6.5-8$ and $T=0-50^\circ$C, we find that it is most probable that NO$_{X}^{-}$]$<1~\mu$M in the prebiotic ocean. On the other hand, prebiotic ponds with favorable drainage characteristics may have sustained [NO$_{X}^{-}$]$\geq 1~\mu$M. As on modern Earth, most NO$_{X}^{-}$ on prebiotic Earth should have been present as NO$_{3}^{-}$, due to its much greater stability. These findings inform the kind of prebiotic chemistries that would have been possible on early Earth. We discuss the implications for proposed prebiotic chemistries, and highlight the need for further studies of NO$_{X}^{-}$ kinetics to reduce the considerable uncertainties in predicting [NO$_{X}^{-}$] on early Earth.Comment: In review for publication at Geochemistry, Geophysics, and Geosystems (G-cubed). Comments, questions, and criticism solicited; please contact corresponding author at [email protected]. SI at: https://web-cert.mit.edu/sukrit/Public/nox_si.pdf. GitHub at: https://github.com/sukritranjan/no