Imaging sub-milliarcsecond stellar features with intensity interferometry using air Cherenkov telescope arrays

Recent proposals have been advanced to apply imaging air Cherenkov telescope arrays to stellar intensity interferometry (SII). Of particular interest is the possibility of model-independent image recovery afforded by the good (u, v)-plane coverage of these arrays, as well as recent developments in phase retrieval techniques. The capabilities of these instruments used as SII receivers have already been explored for simple stellar objects, and here the focus is on reconstructing stellar images with non-uniform radiance distributions. We find that hot stars (T > 6000 K) containing hot and/or cool localized regions (T \sim 500 K) as small as \sim 0.1 mas can be imaged at short wavelengths ({\lambda} = 400 nm).Comment: Accepted for publication in MNRAS. 6 pages, 10 figure

Stellar Intensity Interferometry: Imaging capabilities of air Cherenkov telescope arrays

Sub milli-arcsecond imaging in the visible band will provide a new perspective in stellar astrophysics. Even though stellar intensity interferometry was abandoned more than 40 years ago, it is capable of imaging and thus accomplishing more than the measurement of stellar diameters as was previously thought. Various phase retrieval techniques can be used to reconstruct actual images provided a sufficient coverage of the interferometric plane is available. Planned large arrays of Air Cherenkov telescopes will provide thousands of simultaneously available baselines ranging from a few tens of meters to over a kilometer, thus making imaging possible with unprecedented angular resolution. Here we investigate the imaging capabilities of arrays such as CTA or AGIS used as Stellar Intensity Interferometry receivers. The study makes use of simulated data as could realistically be obtained from these arrays. A Cauchy-Riemann based phase recovery allows the reconstruction of images which can be compared to the pristine image for which the data were simulated. This is first done for uniform disk stars with different radii and corresponding to various exposure times, and we find that the uncertainty in reconstructing radii is a few percent after a few hours of exposure time. Finally, more complex images are considered, showing that imaging at the sub-milli-arc-second scale is possible.Comment: 10 pages, 6 figures; presented at the SPIE conference "Optical and Infrared Interferometry II", San Diego, CA, USA (June 2010

Synthesis and catalytic properties of highly branched palladium nanostructures using seeded growth

In order to develop nanocatalysts with enhanced catalytic performance, it is important to be able to synthesize nanocrystals enclosed by high-index surface facets, due to their high density of low coordinated atoms at step, ledge and kink sites. Here, we report a facile seed-mediated route to the synthesis of highly branched Pd nanostructures with a combination of {113}, {115} and {220} high-index surface planes. The size of these nanostructures is readily controlled by a simple manipulation of the seed concentration. The selective use of oleylamine and oleic acid was also found to be critical to the synthesis of these structures, with Pd icosahedra enclosed by low-index {111} facets being produced when hexadecylamine was employed as capping ligand. The structure–property relationship of these nanostructures as catalysts in Suzuki-cross coupling reactions was then investigated and compared, with the high-index faceted branched Pd nanostructures found to be the most effective catalysts

Paleocene Cyclic Sedimentation in the Western North Atlantic, ODP Site 1051, Blake Nose

Upper Paleocene (zone CP8b) cyclic sediment from Ocean Drilling Program (ODP) Site 1051 on Blake Nose, western North Atlantic, alternates from white carbonate-rich to green carbonate-poor in response to precessional forcing. Compositional differences between the two bed types are minor: mineral and nannofossil composition of the beds vary subtly, but grain size of the terrigenous component and biogenic silica content remain constant. Iron content determined by sediment magnetic susceptibility and iron intensity determined by a core-scanning XRF correlates negatively with carbonate content and are higher in green beds. Kaolinite content of green beds is slightly higher as well. Green beds exhibit lower evenness values than white beds for nannofossil assemblages and are more dominated by the species Coccolithus. Dominance by Coccolithus indicates more mesotrophic conditions over Blake Nose during deposition of the green beds, which correlates with slightly higher iron and kaolinite contents. The absence of change in terrigenous grain size and the absence of any indication of planktonic blooms indicate that there was a minor, most likely eolian, input of iron and kaolinite during deposition of the green beds. The source area was most likely northwest Africa, which supplied iron and kaolinite when source areas deflated under drier conditions. With this scenario, kaolinite is an indicator of drier climate and source area erosion, rather than the warmer and/or wetter conditions under which it forms in soils. During precessional minima or perihelion summer (the opposite of our current configuration), there was an increased range of seasonal temperatures and an increase in the intensity of summer and winter monsoon circulation. As a consequence, there was more rainfall in northern Africa and drier conditions in the continental interiors at mid-latitudes. Green bed deposition occurred during precessional maxima when the North Atlantic was cooler, northwest Africa drier, and the eolian flux to the western North Atlantic slightly increased

Conserving Migratory Land Birds in the New World: Do We Know Enough?

Migratory bird needs must be met during four phases of the year: breeding season, fall migration, wintering, and spring migration; thus, management may be needed during all four phases. The bulk of research and management has focused on the breeding season, although several issues remain unsettled, including the spatial extent of habitat influences on fitness and the importance of habitat on the breeding grounds used after breeding. Although detailed investigations have shed light on the ecology and population dynamics of a few avian species, knowledge is sketchy for most species. Replication of comprehensive studies is needed for multiple species across a range of areas. Information deficiencies are even greater during the wintering season, when birds require sites that provide security and food resources needed for survival and developing nutrient reserves for spring migration and, possibly, reproduction. Research is needed on many species simply to identify geographic distributions, wintering sites, habitat use, and basic ecology. Studies are complicated, however, by the mobility of birds and by sexual segregation during winter. Stable-isotope methodology has offered an opportunity to identify linkages between breeding and wintering sites, which facilitates understanding the complete annual cycle of birds. The twice-annual migrations are the poorest-understood events in a bird\u27s life. Migration has always been a risky undertaking, with such anthropogenic features as tall buildings, towers, and wind generators adding to the risk. Species such as woodland specialists migrating through eastern North America have numerous options for pausing during migration to replenish nutrients, but some species depend on limited stopover locations. Research needs for migration include identifying pathways and timetables of migration, quality and distribution of habitats, threats posed by towers and other tall structures, and any bottlenecks for migration. Issues such as human population growth, acid deposition, climate change, and exotic diseases are global concerns with uncertain consequences to migratory birds and even less-certain remedies. Despite enormous gaps in our understanding of these birds, research, much of it occurring in the past 30 years, has provided sufficient information to make intelligent conservation efforts but needs to expand to handle future challenges

Selective sidewall wetting of polymer blocks in hydrogen silsesquioxane directed self-assembly of PS-b-PDMS

We show the importance of sidewall chemistry for the graphoepitaxial alignment of PS-b-PDMS using prepatterns fabricated by electron beam lithography of hydrogen silsesquioxane (HSQ) and by deep ultraviolet (DUV) lithography on SiO2 thin films. Density multiplication of polystyrene-block-polydimethylsiloxane (PS-b-PDMS) within both prepatterns was achieved by using a room temperature dynamic solvent annealing environment. Selective tuning of PS and PDMS wetting on the HSQ template sidewalls was also achieved through careful functionalization of the template and substrate surface using either brush or a self-assembled trimethylsilyl monolayer. PDMS selectively wets HSQ sidewalls treated with a brush layer of PDMS, whiereas PS is found to selectively wet HSQ sidewalls treated with hexamethyldisilazane (HMDS) to produce a trimethylsilyl-terminated surface. The etch resistance of the aligned polymer was also evaluated to understand the implications of using block copolymer patterns which have high etch resistance, self-forming (PDMS) wetting layers at both interfaces. The results outlined in this work may have direct applications in nanolithography for continued device scaling toward the end-of-roadmap era

Application of serial sectioning FIB/SEM tomography in the comprehensive analysis of arrays of metal nanotubes

The ever‐increasing interest in nanostructured materials and shrinking dimensions of state‐of‐the‐art devices pose new challenges both in synthesis and metrology. Although an extensive range of nanotubular materials of different compositions and for various applications are reported in the literature, often detailed structural characterisation of these materials is limited. This is due to the fact that techniques and characterisation protocols for structural analysis of ‘buried’ nano‐scale features, defects or inhomogenities that are difficult to obtain by conventional imaging methods, are still not fully developed. In the case of 1D nanoporous structures, the continuity of the nano‐tubular channels, their uniformity and orientation is of particular interest. Herein, we employ a serial sectioning technique on a dual beam FIB followed by 3D volume reconstruction for comprehensive analysis of tubular metal nanostructures encapsulated within porous anodic alumina. Using this technique, we demonstrate a nano‐tomography characterisation protocol that can be used for analysis of nanoporous structures with emphasis on their channel uniformity and orientation. We demonstrate that high‐resolution nano‐tomography can be performed to visualise pores as small as 60 nm in diameter, with conical or globular shapes, and to quantitatively estimate their localisation and distribution along one‐dimensional metal structures. We specifically chose to examine Cu‐nanotubes, deposited electrochemically within anodic alumina template, because there is a great deal of debate regarding the deposition process. Hence, the comprehensive analysis shown here is not only demonstrating the applicability of the developed characterisation methodology but it is also, in conjunction with other advanced electron microscopy methods such as elemental nano‐scale STEM/EDX mapping, providing conclusive evidence of the key factors at play during the deposition process

Synthesis and magnetic characterization of co-axial Ge1-xMnx/a-Si heterostructures

A method for synthesizing Ge1–xMnx/a-Si core–shell nanowires (x = 0.3(1)–1.0(2)) using a supercritical fluid deposition technique, with a homogeneous distribution of manganese along the entire lengths of the crystalline Ge cores but not in the a-Si shells, is reported. Investigations into the magnetic properties of the heterostructured nanowires revealed a significant influence of the amorphous Si shell covering the surface of the core Ge0.997Mn0.003 nanowires compared to pristine Ge0.997Mn0.003 nanowires with no a-Si coating. The magnetic data revealed diminished values of both the remanence and the saturation magnetization for pristine Mn-doped Ge nanowires at higher temperatures when compared to the Ge1–xMnx/a-Si core–shell nanowires, whereas both parameters increased as the temperature dropped down to 5 K. Differences in the temperature-dependent evolution of the coercivity were observed in the magnetically harder core–shell nanowires compared to the pristine Ge0.997Mn0.003 nanowires, showing a drop of 26% at 5 K vs room temperature compared to a drop of 66% for the pristine nanowires. The low dopant concentration (0.3(1)%) of Mn in the core–shell nanowires, combined with the observed ferromagnetic properties, suggests a combination of hole-mediated exchange and confinement processes are responsible for the observed properties. Our observations show the importance of a protective layer in covering the oxidation-sensitive dilute magnetic semiconductor nanowires