Influence of total solids concentration on membrane permeability in a submerged hollow-fibre anaerobic membrane bioreactor

The main aim of this work was to study the influence of the mixed liquor total solids (MLTS) concentration on membrane permeability (K 20) in a submerged anaerobic membrane bioreactor (SAnMBR) pilot plant, which is equipped with industrial hollow-fibre membranes and treats urban wastewater. This pilot plant was operated at 33°C and 70 days of SRT. Two different transmembrane fluxes (13.3 and 10 LMH) were tested with a gas sparging intensity of 0.23 Nm 3 m -2 h -1 (measured as Specific Gas Demand referred to membrane area). A linear dependence of K 20 on MLTS concentration was observed within a range of MLTS concentration from 13 to 32 g L -1 and J 20 of 10 LMH. K 20 was maintained at sustainable values (about 100 LMH bar -1) even at high MLTS concentrations (up to 20 g L -1). In addition, several short-tests were carried out when the membranes were operated at high MLTS concentrations in order to assess the effect of the physical cleaning strategies (relaxation and back-flush) on membrane performance. It was observed that, with the applied gas sparging intensity, the duration of the relaxation stage did not critically affect the membrane performance. On the other hand, the required back-flush frequency was considerably affected by the MLTS concentration. © IWA Publishing 2012.This research work has been supported by the Spanish Research Foundation (CICYT Projects CTM2008-06809-C02-01 and CTM2008-06809-C02-02, and MICINN FPI grant BES-2009-023712) and Generalitat Valenciana (Projects GVA-ACOMP2010/130 and GVA-ACOMP2011/182), which are gratefully acknowledged.Robles Martínez, Á.; Durán Pinzón, F.; Ruano García, MV.; Ribes Bertomeu, J.; Ferrer Polo, J. (2012). Influence of total solids concentration on membrane permeability in a submerged hollow-fibre anaerobic membrane bioreactor. Water Science and Technology. 66(2):377-384. doi:10.2166/wst.2012.196S37738466

Anaerobic membrane bioreactors (AnMBR) treating urban wastewater in mild climates

Feasibility of an AnMBR demonstration plant treating urban wastewater (UWW) at temperatures around 25-30 ºC was assessed during a 350-day experimental period. The plant was fitted with industrial-scale hollow-fiber membranes and fed with the effluent from the pre-treatment of a full-scale municipal WWTP. Biodegradability of the UWW reached values up to 87%, although a portion of the biodegradable COD was consumed by sulfate reducing organisms. Effluent COD remained below effluent discharge limits, achieving COD removals above 90%. System operation resulted in a reduction of sludge production of 36-58% compared to theoretical aerobic sludge productions. The membranes were operated at gross transmembrane fluxes above 20 LMH maintaining low membrane fouling propensities for more than 250 days without chemical cleaning requirements. Thus, the system resulted in net positive energy productions and GHG emissions around zero. The results obtained confirm the feasibility of UWW treatment in AnMBR under mild and warm climates

A semi-industrial AnMBR plant for urban wastewater treatment at ambient temperature: Analysis of the filtration process, energy balance and quantification of GHG emissions

A semi-industrial scale AnMBR urban wastewater treatment plant was operated for 580 days at ambient temperature (ranging from 10-30 ○C) to assess its long-term filtration performance, energy balance and GHG emissions. The applied 20ºC-standardized transmembrane flux (J20) was varied between 15 and 25 LMH and the specific gas demand per m2 of membrane (SGDm) was modified between 0.10 to 0.40 Nm3·m-2·h-1 (corresponding to a specific gas demand per permeate volume (SGDP) between 10 to 20 Nm3·m-3). The filtration strategy allowed successful long-term operations without any chemical cleaning requirements and little fouling for 233 days. The plant operated as a net energy producer for more than 50 % of the experimental period, with an average net energy demand of -0.169±0.341, -0.190±0.376 and -0.205±0.447 kWh·m-3, considering 0 %, 50 % and 70 % of dissolved methane recovery, respectively. Finally, demethanization of AnMBR effluent is needed to achieve an environmentally sustainable operation of the technology. Therefore, the combination of AnMBR with degassing membranes appears as a suitable alternative to conventional wastewater treatment

A semi-industrial scale AnMBR for municipal wastewater treatment at ambient temperature: performance of the biological process

A semi-industrial scale AnMBR plant was operated for more than 600 days to evaluate the long-term operation of this technology at ambient temperature (ranging from 10 to 27 ºC), variable hydraulic retention times (HRT) (from 25 to 41 h) and influent loads (mostly between 15 and 45 kg COD·d−1). The plant was fed with sulfate-rich high-loaded municipal wastewater from the pre-treatment of a full-scale WWTP. The results showed promising AnMBR performance as the core technology for wastewater treatment, obtaining an average 87.2 ± 6.1 % COD removal during long-term operation, with 40 % of the data over 90%. Five periods were considered to evaluate the effect of HRT, influent characteristics, COD/-S ratio and temperature on the biological process. In the selected periods, methane yields varied from 70.2±36.0 to 169.0±95.1 STP L CH4·kg−1 CODinf, depending on the influent sulfate concentration, and wasting sludge production was reduced by between 8 % and 42 % compared to conventional activated sludge systems. The effluent exhibited a significant nutrient recovery potential. Temperature, HRT, SRT and influent COD/-S ratio were corroborated as crucial parameters to consider in maximizing AnMBR performance

El Aprendizaje Activo en Primer Curso de Ingeniería desde la Perspectiva de los Estudiantes

[ES] En este trabajo se analiza la valoración que realizan estudiantes de primer curso de diferentes títulos de Grado, que se imparten en la Universitat Politècnica de València, sobre el uso de diferentes técnicas de aprendizaje activo y cooperativo, como herramientas para su formación en competencias. Se ha realizado un cuestionario para conocer su opinión respecto al grado de satisfacción y la utilidad para el aprendizaje sobre las actividades de enseñanza-aprendizaje realizadas, así como un cuestionario de incidencias críticas, sobre la actuación docente del profesor y la implicación del estudiante. Del análisis de datos se puede destacar que los alumnos aprecian la labor del profesor en el diseño y aplicación de metodologías basadas en el aprendizaje, que se muestran especialmente satisfechos de participar activamente y que les es de mucha utilidad para aprender. Respecto al aprendizaje cooperativo en equipos existen opiniones diversas, en función del grado de autonomía del estudiante y de la dificultad de las tareas a realizar: valoran positivamente la resolución de problemas y se muestran más reacios cuando han de elaborar trabajos y exponerlos oralmente. Esta experiencia nos ha permitido detectar puntos fuertes y débiles y obtener la retroalimentación necesaria para reorientar y adaptar las estrategias metodológicas utilizadas.Bautista, I.; Atienza Boronat, MJ.; Climent Olmedo, MJ.; Iborra Chornet, S.; Morera Bertomeu, IM.; Ribes-Greus, A. (2014). El Aprendizaje Activo en Primer Curso de Ingeniería desde la Perspectiva de los Estudiantes. Editorial Universitat Politècnica de València. 802-814. http://hdl.handle.net/10251/168622S80281

New frontiers from removal to recycling of nitrogen and phosphorus from wastewater in the Circular Economy

[EN] Nutrient recovery technologies are rapidly expanding due to the need for the appropriate recycling of key elements from waste resources in order to move towards a truly sustainable modern society based on the Circular Economy. Nutrient recycling is a promising strategy for reducing the depletion of non-renewable resources and the environmental impact linked to their extraction and manufacture. However, nutrient recovery technologies are not yet fully mature, as further research is needed to optimize process efficiency and enhance their commercial applicability. This paper reviews state-of-the-art of nutrient recovery, focusing on frontier technological advances and economic and environmental innovation perspectives. The potentials and limitations of different technologies are discussed, covering systems based on membranes, photosynthesis, crystallization and other physical and biological nutrient recovery systems (e.g. incineration, composting, stripping and absorption and enhanced biological phosphorus recovery).Robles Martínez, Á.; Aguado García, D.; Barat, R.; Borrás Falomir, L.; Bouzas Blanco, A.; Bautista-Giménez, J.; Martí Ortega, N.... (2020). New frontiers from removal to recycling of nitrogen and phosphorus from wastewater in the Circular Economy. Bioresource Technology. 300:1-18. https://doi.org/10.1016/j.biortech.2019.122673S11830

Estrategias Participativas para el Desarrollo y Evaluación de Competencias Transversales

[EN] The need to advance the planning, development and evaluation of skills has led to the Grupo de Innovación e Investigación en Metodologías Activas (GIIMA), to consider a project with the aim of developing a methodology that is valid and applicable to a set of cross-disciplinary skills in first degree courses. Participatory methodologies are an effective alternative to facilitate the development of attitudes, skills and abilities, hence the desirability of providing students opportunities and strategies that motivate them in the execution of their tasks, allow them to learn from experience and mistakes, and conclude that in learning how to. These actions, accompanied by a monitoring and evaluation process, may certify skills acquired with the implementation of participatory strategies conveniently chosen by teachers to achieve the results of apprentice. So, it is necessary to design and put in place processes of evaluation and accreditation of skills, and that this type of learning outcomes acquired by the students, also have their social recognition and are valued by employers. The project involves 11 subjects that are taught in 13 undergraduate degrees of the UPV[ES] La necesidad de avanzar en la planificación, desarrollo y evaluación de competencias transversales ha motivado al GRUPO DE INNOVACIÓN E INVESTIGACIÓN EN METODOLOGÍAS ACTIVAS (GIIMA) a plantear un proyecto con el objetivo de desarrollar una metodología que resulte válida y aplicable a un conjunto de competencias transversales en los primeros cursos del Grado. Las metodologías participativas son una alternativa eficaz para facilitar el desarrollo de actitudes, habilidades y destrezas, de ahí la conveniencia de proporcionar a los estudiantes universitarios oportunidades y estrategias que les motiven en la ejecución de sus tareas, les permitan aprender de la experiencia y de los errores, y que concluyan en aprender a hacer. Estas acciones, acompañadas de un seguimiento y evaluación del proceso, podrán acreditar las competencias transversales adquiridas con la implementación de estrategias participativas convenientemente elegidas por los profesores para alcanzar los resultados de aprendizaje deseados. Para ello es necesario diseñar y poner en marcha procesos de evaluación y acreditación de las competencias transversales, y que este tipo de resultados de aprendizaje, adquiridos también por los estudiantes, tengan su reconocimiento social y sean valorados por los empleadores. En el proyecto participan 11 asignaturas que se imparten en 13 titulaciones de Grado de la UPV.Monreal Mengual, L.; Atienza Boronat, MJ.; Badía Valiente, JD.; Bautista, I.; Climent Olmedo, MJ.; Gómez Ángel, B.; Iborra Chornet, S.... (2015). Estrategias Participativas para el Desarrollo y Evaluación de Competencias Transversales. En In-Red 2015 - CONGRESO NACIONAL DE INNOVACIÓN EDUCATIVA Y DE DOCENCIA EN RED. Editorial Universitat Politècnica de València. https://doi.org/10.4995/INRED2015.2015.1626OC

Maximizing resource recovery from urban wastewater through an innovative facility layout

[EN] This research work proposes an innovative layout for urban wastewater treatment based on anaerobic technology, microalgal cultivation and membrane technology. The proposed Water Resource Recovery Facility (WRRF) system can treat urban wastewater efficiently, complying with legal discharge limits and allowing for resource recovery, i.e. energy, nutrients and reclaimed water. In addition, the proposed layout produces less solid wastes than a conventional wastewater treatment plant (WWTP) and it is possible to recover energy as biogas, not only from the original wastewater sources but also from the biomass generated in the WRRF system

Resource recovery from sulphate-rich sewage through an innovative anaerobic-based water resource recovery facility (WRRF)

[EN] This research work proposes an innovative water resource recovery facility (WRRF) for the recovery of energy, nutrients and reclaimed water from sewage, which represents a promising approach towards enhanced circular economy scenarios. To this aim, anaerobic technology, microalgae cultivation, and membrane technology were combined in a dedicated platform. The proposed platform produces a high-quality solid- and coliform-free effluent that can be directly discharged to receiving water bodies identified as sensitive areas. Specifically, the content of organic matter, nitrogen and phosphorus in the effluent was 45 mg COD.L-1 , 14.9 mg N.L-1 and 0.5 mg P.L-1 , respectively. Harvested solar energy and carbon dioxide biofixation in the form of microalgae biomass allowed remarkable methane yields (399 STP L CH 4.kg(-1) CODinf ) to be achieved, equivalent to theoretical electricity productions of around 0.52 kWh per m 3 of wastewater entering the WRRF. Furthermore, 26.6% of total nitrogen influent load was recovered as ammonium sulphate, while nitrogen and phosphorus were recovered in the biosolids produced (650 +/- 77 mg N.L-1 and 121.0 +/- 7.2 mg P.L-1).This research was supported by the Spanish Ministry of Economy and Competitiveness (MINECO, Projects CTM2014-54980-C2-1-R and CTM2014-54980-C2-2-R) jointly with the European Regional Development Fund (ERDF), which are gratefully acknowledged. This research was also supported by the Spanish Ministry of Education, Culture and Sport via two pre-doctoral FPU fellowships (FPU14/05082 and FPU15/02595) and by the Spanish Ministry of Economy and Competitiveness via two pre-doctoral FPI fellowships (BES-2015-071884, BES-2015-073403) and one Juan de la Cierva contract (FJCI-2014-21616). The authors would also like to acknowledge the support received from Generalitat Valenciana via two VALithornd post-doctoral grants (APOSTD/2014/049 and APOSTD/2016/104) and via the fellowships APOTI/2016/059 and CPI-16-155, as well as the financial aid received from the European Climate KIC association for the 'MAB 2.0' Project (APIN0057_ 2015-3.6-230_ P066-05) and Universitat Politecnica de Valencia via a pre-doctoral FPI fellowship to the seventh author.Seco Torrecillas, A.; Aparicio Antón, SE.; Gonzalez-Camejo, J.; Jiménez Benítez, AL.; Mateo-Llosa, O.; Mora-Sánchez, JF.; Noriega-Hevia, G.... (2018). Resource recovery from sulphate-rich sewage through an innovative anaerobic-based water resource recovery facility (WRRF). Water Science & Technology. 78(9):1925-1936. https://doi.org/10.2166/wst.2018.492S19251936789Bair, R. A., Ozcan, O. O., Calabria, J. L., Dick, G. H., & Yeh, D. H. (2015). Feasibility of anaerobic membrane bioreactors (AnMBR) for onsite sanitation and resource recovery (nutrients, energy and water) in urban slums. Water Science and Technology, 72(9), 1543-1551. doi:10.2166/wst.2015.349Barat, R., Serralta, J., Ruano, M. V., Jiménez, E., Ribes, J., Seco, A., & Ferrer, J. (2013). Biological Nutrient Removal Model No. 2 (BNRM2): a general model for wastewater treatment plants. Water Science and Technology, 67(7), 1481-1489. doi:10.2166/wst.2013.004Batstone, D. J., Hülsen, T., Mehta, C. M., & Keller, J. (2015). Platforms for energy and nutrient recovery from domestic wastewater: A review. Chemosphere, 140, 2-11. doi:10.1016/j.chemosphere.2014.10.021Bilad, M. R., Arafat, H. A., & Vankelecom, I. F. J. (2014). Membrane technology in microalgae cultivation and harvesting: A review. Biotechnology Advances, 32(7), 1283-1300. doi:10.1016/j.biotechadv.2014.07.008Carrington E.-G. 2001 Evaluation of Sludge Treatments for Pathogen Reduction. http://europa.eu.int/comm/environment/pubs/home.htm.Cookney, J., Mcleod, A., Mathioudakis, V., Ncube, P., Soares, A., Jefferson, B., & McAdam, E. J. (2016). Dissolved methane recovery from anaerobic effluents using hollow fibre membrane contactors. Journal of Membrane Science, 502, 141-150. doi:10.1016/j.memsci.2015.12.037De Morais, M. G., & Costa, J. A. V. (2007). Biofixation of carbon dioxide by Spirulina sp. and Scenedesmus obliquus cultivated in a three-stage serial tubular photobioreactor. Journal of Biotechnology, 129(3), 439-445. doi:10.1016/j.jbiotec.2007.01.009Giménez, J. B., Robles, A., Carretero, L., Durán, F., Ruano, M. V., Gatti, M. N., … Seco, A. (2011). Experimental study of the anaerobic urban wastewater treatment in a submerged hollow-fibre membrane bioreactor at pilot scale. Bioresource Technology, 102(19), 8799-8806. doi:10.1016/j.biortech.2011.07.014Giménez, J. B., Martí, N., Ferrer, J., & Seco, A. (2012). Methane recovery efficiency in a submerged anaerobic membrane bioreactor (SAnMBR) treating sulphate-rich urban wastewater: Evaluation of methane losses with the effluent. Bioresource Technology, 118, 67-72. doi:10.1016/j.biortech.2012.05.019Giménez, J. B., Bouzas, A., Carrere, H., Steyer, J.-P., Ferrer, J., & Seco, A. (2018). Assessment of cross-flow filtration as microalgae harvesting technique prior to anaerobic digestion: Evaluation of biomass integrity and energy demand. Bioresource Technology, 269, 188-194. doi:10.1016/j.biortech.2018.08.052González-Camejo, J., Serna-García, R., Viruela, A., Pachés, M., Durán, F., Robles, A., … Seco, A. (2017). Short and long-term experiments on the effect of sulphide on microalgae cultivation in tertiary sewage treatment. Bioresource Technology, 244, 15-22. doi:10.1016/j.biortech.2017.07.126Martí, N., Barat, R., Seco, A., Pastor, L., & Bouzas, A. (2017). Sludge management modeling to enhance P-recovery as struvite in wastewater treatment plants. Journal of Environmental Management, 196, 340-346. doi:10.1016/j.jenvman.2016.12.074Moosbrugger R. , WentzelM. & EkamaG.1992Simple Titration Procedures to Determine H2CO3 Alkalinity and Short-chain Fatty Acids in Aqueous Solutions Containing Known Concentrations of Ammonium, Phosphate and Sulphide Weak Acid/Bases. Water. Res. Commission, Report, No. TT 57/92.Morales, N., Boehler, M., Buettner, S., Liebi, C., & Siegrist, H. (2013). Recovery of N and P from Urine by Struvite Precipitation Followed by Combined Stripping with Digester Sludge Liquid at Full Scale. Water, 5(3), 1262-1278. doi:10.3390/w5031262Pretel, R., Durán, F., Robles, A., Ruano, M. V., Ribes, J., Serralta, J., & Ferrer, J. (2015). Designing an AnMBR-based WWTP for energy recovery from urban wastewater: The role of primary settling and anaerobic digestion. Separation and Purification Technology, 156, 132-139. doi:10.1016/j.seppur.2015.09.047Pretel, R., Robles, A., Ruano, M. V., Seco, A., & Ferrer, J. (2016). Economic and environmental sustainability of submerged anaerobic MBR-based (AnMBR-based) technology as compared to aerobic-based technologies for moderate-/high-loaded urban wastewater treatment. Journal of Environmental Management, 166, 45-54. doi:10.1016/j.jenvman.2015.10.004Sharma, B., Sarkar, A., Singh, P., & Singh, R. P. (2017). Agricultural utilization of biosolids: A review on potential effects on soil and plant grown. Waste Management, 64, 117-132. doi:10.1016/j.wasman.2017.03.002Sialve, B., Bernet, N., & Bernard, O. (2009). Anaerobic digestion of microalgae as a necessary step to make microalgal biodiesel sustainable. 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Modelling of an activated primary settling tank including the fermentation process and VFA elutriation

A complete model of a primary settler including both sedimentation and biological processes is presented. It is a one-dimensional model based on the solids flux concept and the conservation of mass that uses the Takács model for the settling velocity, which is corrected by a compression function in the lower layers. The biological model is based on the ASM2 and enlarged with the fermentation model proposed by this research group. The settler was split in ten layers and the flux terms in the mass balance for each layer is obtained by means of the settling model. A pilot plant has been operated to study the primary sludge fermentation and volatile fatty acids (VFA) elutriation in a primary settler tank. The model has been tested with pilot plant experimental data with very good results. It has been able to simulate the VFA production in the settler and their elutriation with the influent wastewater for all the studied experiments. The developed model is easily applicable to secondary settlers and thickeners, also taking into account biological activity inside them