Design of slurries for 3D printing of sodium-ion battery electrodes

Additive manufacturing of battery electrodes, using syringe deposition 3D printing or direct ink writing methods, enables intricate microstructural design. This process differs from traditional blade or slot-die coating methods, necessitating tailored physical properties of composite slurries to ensure successful deposition. Inadequately optimised slurries result in non-uniform extrusion, and challenges such as nozzle swelling or slumping, result in compromised structural integrity of the print, limiting the resolution. This study focuses on developing slurry design principles by thoroughly characterising the rheology of several water-based hard carbon anode slurry, both in shear and extension. Hard carbon is chosen as a material of significant importance for future sodium-ion batteries, and an example for this optimisation. The slurry composition is tailored to introduce yield stress by incorporating network-forming binder (carrageenan) and additive (carbon nanotubes), effectively reducing spreading, and preserving the printed coating's structure. Validation is performed through printing a large width line and evaluating spread. The same slurry is deposited on a smaller 150 μm nozzle, which introduces die swell and spreading effects. This offers insights for further optimization strategies. The strategies developed in this research for characterizing and optimizing the rheology through formulation lay the groundwork for the advancement of detailed 3D printed electrodes, contributing to the progress of additive manufacturing technologies in the field of battery manufacturing.</p

A review of metrology in lithium-ion electrode coating processes

Lithium-ion battery electrode design and manufacture is a multi-faceted process where the link between underlying physical processes and manufacturing outputs is not yet fully understood. This is in part due to the many parameters and variables involved and the lack of complete data sets under different processing conditions. The slurry coating step has significant implications for electrode design and advanced metrology offers opportunities to improve understanding and control at this stage. Here, metrology options for slurry coating are reviewed as well as opportunities for in-line integration, discussing the benefits of combining advanced metrology to provide comprehensive characterisation, improve understanding and feed into predictive design models. There is a comprehensive range of metrology which needs little improvement to provide the relevant quantifiable measures during coating, with one exception of particle sizing, where more precise, in-line measurement would be beneficial. However, there is a lack of studies that bring together the latest advancements in electrode coating metrology which is crucial to understanding the interdependency of myriad processing and product parameters. This review highlights the need for a comprehensive metrological picture whose value would be much greater than the sum of its parts for the next generation of multiphysics and data-driven models

Sampling a Littoral Fish Assemblage: Comparison of Small-Mesh Fyke Netting and Boat Electrofishing

We compared small-mesh (4-mm) fyke netting and boat electrofishing for sampling a littoral fish assemblage in Muskegon Lake, Michigan. We hypothesized that fyke netting selects for small-bodied fishes and electrofishing selects for large-bodied fishes. Three sites were sampled during May (2004 and 2005), July (2005 only), and September (2004 and 2005). We found that the species composition of captured fish differed considerably between fyke netting and electrofishing based on nonmetric multidimensional scaling (NMDS). Species strongly associated with fyke netting (based on NMDS and relative abundance) included the brook silverside Labidesthes sicculus, banded killifish Fundulus diaphanus, round goby Neogobius melanostomus, mimic shiner Notropis volucellus, and bluntnose minnow Pimephales notatus, whereas species associated with electrofishing included the Chinook salmon Oncorhynchus tshawytscha, catostomids (Moxostoma spp. and Catostomus spp.), freshwater drum Aplodinotus grunniens, walleye Sander vitreus, gizzard shad Dorosoma cepedianum, and common carp Cyprinus carpio. The total length of fish captured by electrofishing was 12.8 cm (95% confidence interval ¼ 5.5– 17.2 cm) greater than that of fish captured by fyke netting. Size selectivity of the gears contributed to differences in species composition of the fish captured, supporting our initial hypothesis. Thus, small-mesh fyke nets and boat electrofishers provided complementary information on a littoral fish assemblage. Our results support use of multiple gear types in monitoring and research surveys of fish assemblages. Copyright by the American Fisheries Society 2007, Originally published in the North American Journal of Fisheries Management 27: 825-831, 2007

Granite–a new telescope for TeV gamma ray astronomy

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/87435/2/253_1.pd

Applications of advanced metrology for understanding the effects of drying temperature in the lithium-ion battery electrode manufacturing process

The performance of lithium-ion batteries is determined by the architecture and properties of electrodes formed during manufacturing, particularly in the drying process when solvent is removed and the electrode structure is formed. Temperature is one of the most dominant parameters that influences the process, and therefore a comparison of temperature effects on both NMC622-based cathodes (PVDF-based binder) and graphite-based anodes (water-based binder) dried at RT, 60, 80, 100 and 120 °C has been undertaken. X-ray computed tomography showed that NMC622 particles concentrated at the surface of the cathode coating except when dried at 60 °C. However, anodes showed similar graphite distributions at all temperatures. The discharge capacities for the cathodes dried at 60, 80, 100 and 120 °C displayed the following trend: 60 °C < 80 °C < 100 °C < 120 °C as C-rate was increased which was consistent with the trends found in adhesion testing between 60 and 120 °C. Focused-ion beam scanning electrode microscopy and energy-dispersive X-ray spectroscopy suggested that the F-rich binder distribution was largely insensitive to temperature for cathodes. In contrast, conductivity enhancing fine carbon agglomerated on the upper surface of the active NMC particles in the cathode as temperature increased. The cathode dried at RT had the highest adhesion force of 0.015 N mm−1 and the best electrochemical rate performance. Conversely, drying temperature had no significant effect on the electrochemical performance of the anode, which was consistent with only a relatively small change in the adhesion, related to the use of lower adhesion water-based binders

Observations of TeV photons at the Whipple Observatory

The Whipple Observatory 10 m gamma‐ray telescope has been used to search for TeV gamma‐ray emission from a number of objects. This paper reports observations of six galactic and three extragalactic objects using the Cherenkov image technique. With the introduction of a high‐resolution camera (1/4° pixel) in 1988, the Crab Nebula was detected at a significance level of 20 σ in 30 hours of on‐source observation. Upper limits at a fraction of the Crab flux are set for most of the other objects, based on the absence of any significant dc excess or periodic effect when an a priori Monte Carlo determined imaging selection criterion (the ‘‘azwidth cut’’) is employed. There are weak indications that one source, Hercules X‐1, may be an episodic emitter. The Whipple detection system will be improved shortly with the addition of a second reflector 11 m in diameter (GRANITE) for stereoscopic viewing of showers. The combination of the two‐reflector system should have a signal‐to‐noise advantage of 103 over a simple nonimaging Cherenkov receiver.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/87437/2/47_1.pd

Dataset of RNA-Seq transcriptome of the fetal liver at day 83 of gestation associated with periconceptual maternal nutrition in beef heifers

Herein, we present a dataset based on the RNA-Seq analysis of liver tissue from bovine female fetuses at day 83 of gestation. The findings were reported in the main article, “Periconceptual maternal nutrition affects fetal liver programming of energy- and lipid-related genes”[1] . These data were generated to investigate the effects of periconceptual maternal vitamin and mineral supplementation and rates of body weight gain on the transcript abundance of genes associated with fetal hepatic metabolism and function. To this end, crossbred Angus beef heifers ( n = 35) were randomly assigned to 1 of 4 treatments in a 2 × 2 factorial design. The main effects tested were vitamin and mineral supplementation (VTM or NoVTM –at least 71 days pre-breeding to day 83 of gestation) and rate of weight gain (low (LG –0.28 kg/d) or moderate (MG – 0.79 kg/d) – from breeding to day 83). The fetal liver was collected on day 83 ± 0.27 of gestation. After total RNA isolation and quality control, strand-specific RNA libraries were prepared and sequenced on the Illumina® NovaSeq 60 0 0 platform to generate paired-end 150-bp reads. After read mapping and counting, differential expression analysis was performed with edgeR. We identified 591 unique differentially expressed genes across all six vitamin- gain contrasts (FDR ≤ 0.1). To our knowledge, this is the first dataset investigating the fetal liver transcriptome in response to periconceptual maternal vitamin and mineral supplementation and/or the rate of weight gain. The data described in this article provides genes and molecular pathways differentially programming liver development and function

Impact of formulation and slurry properties on lithium-ion electrode manufacturing

The characteristics and performance of lithium-ion batteries typically rely on the precise combination of materials in their component electrodes. Understanding the impact of this formulation and the interdependencies between each component is critical in optimising cell performance. Such optimisation is difficult as the cost and effort for the myriad of possible combinations is too high. This problem is addressed by combining a design of experiments (DoE) and advanced statistical machine learning approach with comprehensive experimental characterisation of electrode slurries and coatings. An industry relevant graphite anode system is used, and with the aid of DoE, less than 30 experiments are defined to map impact of different weight fractions of active material (80–96 wt%), conductive additive (Carbon Black at 1–10 wt%) and a two-component binder system (Carboxymethyl Cellulose (CMC) at 1–3 wt% and Styrene Butadiene Rubber (SBR), at 1–7 wt%). Using Explainable Machine Learning (XML) methods, correlations between the formulation, slurry weight percentage (30–50 wt% in water) and coating speed (1–15 m/min) are quantified. Slurry viscosity, while known to depend on the CMC concentration, is also heavily influenced by carbon black and SBR when at high concentration, as is common in research. Viscosity increasing components also improve adhesion, by improving dispersion and hindering binder migration. Conductivity of the coating on current collector is sensitive to the current collector-coating interface, which makes it a highly useful probe. Improvements in cell capacity are observed with higher viscosity formulations (High weight percentage, CMC content), attributed to reduction in migration and slumping of the slurry on the current collector. SBR had a negative impact at any concentration due to its insulating nature, and carbon black reduces gravimetric capacity when included at high concentrations. The insights from this study facilitate the formulation optimisation of electrodes providing improved slurry design rules for future high performance electrode manufacturing

Maternal Vitamin and Mineral Supplementation and Rate of Maternal Weight Gain Affects Placental Expression of Energy Metabolism and Transport-Related Genes

Maternal nutrients are essential for proper fetal and placental development and function. However, the effects of vitamin and mineral supplementation under two rates of maternal weight gain on placental genome-wide gene expression have not been investigated so far. Furthermore, biological processes and pathways in the placenta that act in response to early maternal nutrition are yet to be elucidated. Herein, we examined the impact of maternal vitamin and mineral supplementation (from pre-breeding to day 83 post-breeding) and two rates of gain during the first 83 days of pregnancy on the gene expression of placental caruncles (CAR; maternal placenta) and cotyledons (COT; fetal placenta) of crossbred Angus beef heifers. We identified 267 unique differentially expressed genes (DEG). Among the DEGs from CAR, we identified ACAT2, SREBF2, and HMGCCS1 that underlie the cholesterol biosynthesis pathway. Furthermore, the transcription factors PAX2 and PAX8 were over-represented in biological processes related to kidney organogenesis. The DEGs from COT included SLC2A1, SLC2A3, SLC27A4, and INSIG1. Our over-representation analysis retrieved biological processes related to nutrient transport and ion homeostasis, whereas the pathways included insulin secretion, PPAR signaling, and biosynthesis of amino acids. Vitamin and mineral supplementation and rate of gain were associated with changes in gene expression, biological processes, and KEGG pathways in beef cattle placental tissues