10,141 research outputs found

    Phase transitions, entanglement and quantum noise interferometry in cold atoms

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    We show that entanglement monotones can characterize the pronounced enhancement of entanglement at a quantum phase transition if they are sensitive to long-range high order correlations. These monotones are found to develop a sharp peak at the critical point and to exhibit universal scaling. We demonstrate that similar features are shared by noise correlations and verify that these experimentally accessible quantities indeed encode entanglement information and probe separability.Comment: 4 pages 4 figure

    Some aspects of analytical chemistry as applied to water quality assurance techniques for reclaimed water: The potential use of X-ray fluorescence spectrometry for automated on-line fast real-time simultaneous multi-component analysis of inorganic pollutants in reclaimed water

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    The potential use of isotopically excited energy dispersive X-ray fluorescence (XRF) spectrometry for automated on line fast real time (5 to 15 minutes) simultaneous multicomponent (up to 20) trace (1 to 10 parts per billion) analysis of inorganic pollutants in reclaimed water was examined. Three anionic elements (chromium 6, arsenic and selenium) were studied. The inherent lack of sensitivity of XRF spectrometry for these elements mandates use of a preconcentration technique and various methods were examined, including: several direct and indirect evaporation methods; ion exchange membranes; selective and nonselective precipitation; and complexation processes. It is shown tha XRF spectrometry itself is well suited for automated on line quality assurance, and can provide a nondestructive (and thus sample storage and repeat analysis capabilities) and particularly convenient analytical method. Further, the use of an isotopically excited energy dispersive unit (50 mCi Cd-109 source) coupled with a suitable preconcentration process can provide sufficient sensitivity to achieve the current mandated minimum levels of detection without the need for high power X-ray generating tubes

    Effects of random localizing events on matter waves: formalism and examples

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    A formalism is introduced to describe a number of physical processes that may break down the coherence of a matter wave over a characteristic length scale l. In a second-quantized description, an appropriate master equation for a set of bosonic "modes" (such as atoms in a lattice, in a tight-binding approximation) is derived. Two kinds of "localizing processes" are discussed in some detail and shown to lead to master equations of this general form: spontaneous emission (more precisely, light scattering), and modulation by external random potentials. Some of the dynamical consequences of these processes are considered: in particular, it is shown that they generically lead to a damping of the motion of the matter-wave currents, and may also cause a "flattening" of the density distribution of a trapped condensate at rest.Comment: v3; a few corrections, especially in Sections IV and

    Stimuli-responsive behavior of PNiPAm microgels under interfacial confinement

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    The volume phase transition of microgels is one of the most paradigmatic examples of stimuli-responsiveness, enabling a collapse from a highly swollen microgel state into a densely coiled state by an external stimulus. Although well characterized in bulk, it remains unclear how the phase transition is affected by the presence of a confining interface. Here, we demonstrate that the temperature-induced volume phase transition of poly(N-isopropylacrylamide) microgels, conventionally considered an intrinsic molecular property of the polymer, is in fact largely suppressed when the microgel is adsorbed to an air/liquid interface. We further observe a hysteresis in core morphology and interfacial pressure between heating and cooling cycles. Our results, supported by molecular dynamics simulations, reveal that the dangling polymer chains of microgel particles, spread at the interface under the influence of surface tension, do not undergo any volume phase transition, demonstrating that the balance in free energy responsible for the volume phase transition is fundamentally altered by interfacial confinement. These results imply that important technological properties of such systems, including the temperature-induced destabilization of emulsions does not occur via a decrease in interfacial coverage of the microgels

    Thermodynamics of quantum degenerate gases in optical lattices

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    The entropy-temperature curves are calculated for non-interacting Bose and Fermi gases in a 3D optical lattice. These curves facilitate understanding of how adiabatic changes in the lattice depth affect the temperature, and we demonstrate regimes where the atomic sample can be significantly heated or cooled by the loading process. We assess the effects of interactions on a Bose gas in a deep optical lattice, and show that interactions ultimately limit the extent of cooling that can occur during lattice loading.Comment: 6 pages, 4 figures. Submitted to proceedings of Laser Physics 2006 Worksho

    Diffusion of hydrogen interstitials in the near-surface region of Pd(111) under the influence of surface coverage and external static electric fields

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    Past scanning tunneling microscopy (STM) experiments of H manipulation on Pd(111), at low temperature, have shown that it is possible to induce diffusion of surface species as well as of those deeply buried under the surface. Several questions remain open regarding the role of subsurface site occupancies. In the present work, the interaction potential of H atoms with Pd(111) under various H coverage conditions is determined by means of density functional theory calculations in order to provide an answer to two of these questions: (i) whether subsurface sites are the final locations for the H impurities that attempt to emerge from bulk regions, and (ii) whether penetration of the surface is a competing route of on-surface diffusion during depletion of surface H on densely covered Pd(111). We find that a high H coverage has the effect of blocking resurfacing of H atoms travelling from below, which would otherwise reach the surface fcc sites, but it hardly alters deeper diffusion energy barriers. Penetration is unlikely and restricted to high occupancies of hcp hollows. In agreement with experiments, the Pd lattice expands vertically as a consequence of H atoms being blocked at subsurface sites, and surface H enhances this expansion. STM tip effects are included in the calculations self-consistently as an external static electric field. The main contribution to the induced surface electric dipoles originates from the Pd substrate polarisability. We find that the electric field has a non- negligible effect on the H-Pd potential in the vicinity of the topmost Pd atomic layer, yet typical STM intensities of 1-2 VÅ−1 are insufficient to invert the stabilities of the surface and subsurface equilibrium sites

    Improving the family orientation process in Cuban Special Schools trough Nearest Prototype classification

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    Cuban Schools for children with Affective – Behavioral Maladies (SABM) have as goal to accomplish a major change in children behavior, to insert them effectively into society. One of the key elements in this objective is to give an adequate orientation to the children’s families; due to the family is one of the most important educational contexts in which the children will develop their personality. The family orientation process in SABM involves clustering and classification of mixed type data with non-symmetric similarity functions. To improve this process, this paper includes some novel characteristics in clustering and prototype selection. The proposed approach uses a hierarchical clustering based on compact sets, making it suitable for dealing with non-symmetric similarity functions, as well as with mixed and incomplete data. The proposal obtains very good results on the SABM data, and over repository databases
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