Retrieving Decadal Climate Change from Satellite Radiance Observations-A 100-year CO2 Doubling OSSE Demonstration.

Preparing for climate change depends on the observation and prediction of decadal trends of the environmental variables, which have a direct impact on the sustainability of resources affecting the quality of life on our planet. The NASA Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission is proposed to provide climate quality benchmark spectral radiance observations for the purpose of determining the decadal trends of climate variables, and validating and improving the long-range climate model forecasts needed to prepare for the changing climate of the Earth. The CLARREO will serve as an in-orbit, absolute, radiometric standard for the cross-calibration of hyperspectral radiance spectra observed by the international system of polar operational satellite sounding sensors. Here, we demonstrate that the resulting accurately cross-calibrated polar satellite global infrared spectral radiance trends (e.g., from the Metop IASI instrument considered here) can be interpreted in terms of temperature and water vapor profile trends. This demonstration is performed using atmospheric state data generated for a 100-year period from 2000-2099, produced by a numerical climate model prediction that was forced by the doubling of the global average atmospheric CO2 over the 100-year period. The vertical profiles and spatial distribution of temperature decadal trends were successfully diagnosed by applying a linear regression profile retrieval algorithm to the simulated hyperspectral radiance spectra for the 100-year period. These results indicate that it is possible to detect decadal trends in atmospheric climate variables from high accuracy all-sky satellite infrared radiance spectra using the linear regression retrieval technique

Earth radiation budget measurement from a spinning satellite: Conceptual design of detectors

The conceptual design, sensor characteristics, sensor performance and accuracy, and spacecraft and orbital requirements for a spinning wide-field-of-view earth energy budget detector were investigated. The scientific requirements for measurement of the earth's radiative energy budget are presented. Other topics discussed include the observing system concept, solar constant radiometer design, plane flux wide FOV sensor design, fast active cavity theory, fast active cavity design and error analysis, thermopile detectors as an alternative, pre-flight and in-flight calibration plane, system error summary, and interface requirements

Cloud-top meridional momentum transports on Saturn and Jupiter

Cloud-tracked wind measurements reported by Sromovsky et al. were analyzed to determine meridional momentum transports in Saturn's northern middle latitudes. Results are expressed in terms of eastward and northward velocity components (u and v), and eddy components u and v. At most latitudes between 13 and 44 deg N (planetocentric), the transport by the mean flow () is measurably southward, tending to support Saturn's large equatorial jet, and completely dominating the eddy transport. Meridional velocities are near zero at the peak of the relatively weak westward jet; along the flanks of that jet, measurements indicate divergent flow out of the jet. In this region the dominant eddy transport () is northward on the north side of the jet, but not resolvable on the south side. Eddy transports at most other latitudes are not significantly different from measurement error. The conversion of eddy kinetic energy to mean kinetic energy, indicated by the correlation between and d/dy (where y is meridional distance) is clearly smaller than various values reported for Jupiter, and not significantly different from zero. Both Jovian and Saturnian results may be biased by the tendency for cloud tracking to favor high contrast features, and thus may not be entirely representative of the cloud level motions as a whole

Multi-spectral window radiance observations of Cirrus from satellite and aircraft, November 2, 1986 Project FIRE

High resolution infrared radiance spectra achieved from the NASA ER2 airborne HIS experiment are used to analyze the spectral emissivity properties of cirrus clouds within the 8 to 12 micron atmospheric window region. Observations show that the cirrus emissivity generally decreases with increasing wavenumber (i.e., decreasing wavelength) within this band. A very abrupt decrease in emissivity (increase in brightness temperature) exists between 930/cm (10.8 microns) and 1000/cm (10.0 microns), the magnitude of the change being associated with the cirrus optical thickness as observed by lidar. The HIS observations are consistent with theoretical calculations of the spectral absorption coefficient for ice. The HIS observations imply that cirrus clouds can be detected unambiguously from the difference in brightness temperatures observed within the 8.2 and 11.0 micron window regions of the HIRS sounding radiometer flying on the operational NOAA satellites. This ability is demonstrated using simultaneous 25 km resolution HIRS observations and 1 km resolution AVHRR imagery achieved from the NOAA-9 satellite. Finally, the cirrus cloud location estimates combined with the 6.7 micron channel moisture imagery portray the boundaries of the ice/vapor phase of the upper troposphere moisture. This phase distinction is crucial for infrared radiative transfer considerations for weather and climate models, since upper tropospheric water vapor has little effect on the Earth's outgoing radiation whereas cirrus clouds have a very large attenuating effect

IASI spectral radiance validation inter-comparisons: case study assessment from the JAIVEx field campaign

Advanced satellite sensors are tasked with improving global-scale measurements of the Earth's atmosphere, clouds, and surface to enable enhancements in weather prediction, climate monitoring, and environmental change detection. Measurement system validation is crucial to achieving this goal and maximizing research and operational utility of resultant data. Field campaigns employing satellite under-flights with well-calibrated Fourier Transform Spectrometer (FTS) sensors aboard high-altitude aircraft are an essential part of this validation task. The National Polar-orbiting Operational Environmental Satellite System (NPOESS) Airborne Sounder Testbed-Interferometer (NAST-I) has been a fundamental contributor in this area by providing coincident high spectral and spatial resolution observations of infrared spectral radiances along with independently-retrieved geophysical products for comparison with like products from satellite sensors being validated. This manuscript focuses on validating infrared spectral radiance from the Infrared Atmospheric Sounding Interferometer (IASI) through a case study analysis using data obtained during the recent Joint Airborne IASI Validation Experiment (JAIVEx) field campaign. Emphasis is placed upon the benefits achievable from employing airborne interferometers such as the NAST-I since, in addition to IASI radiance calibration performance assessments, cross-validation with other advanced sounders such as the AQUA Atmospheric InfraRed Sounder (AIRS) is enabled

Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS): Imaging and Tracking Capability

The geosynchronous-imaging Fourier transform spectrometer (GIFTS) engineering demonstration unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. It measures the infrared spectrum in two spectral bands (14.6 to 8.8 microns, 6.0 to 4.4 microns) using two 128 128 detector arrays with a spectral resolution of 0.57/cm with a scan duration of approx. 11 seconds. From a geosynchronous orbit, the instrument will have the capability of taking successive measurements of such data to scan desired regions of the globe, from which atmospheric status, cloud parameters, wind field profiles, and other derived products can be retrieved. The GIFTS EDU provides a flexible and accurate testbed for the new challenges of the emerging hyperspectral era. The EDU ground-based measurement experiment, held in Logan, Utah during September 2006, demonstrated its extensive capabilities and potential for geosynchronous and other applications (e.g., Earth observing environmental measurements). This paper addresses the experiment objectives and overall performance of the sensor system with a focus on the GIFTS EDU imaging capability and proof of the GIFTS measurement concept

Public Opinion

Previous research has found that many U.S. college students believe that politics is not about solving problems; rather, research has found that such students see politics as complicated, untrustworthy, pressuring, and often counterproductive to acting on the ills of society. There has been an array of survey research, policy analysis, and commentary that attempts to define, understand, and document the political engagement of young people since this portrayal of college students’ views of politics in the early 1990s. Some additional research has found that, among the greatest dangers for American political stability, is that politics in the minds and actions of the youth has become a nothing more than a negative, uninteresting topic that typically lacks significant representation. Furthermore, some argue that part of increasing political interest is focused towards the global political arena, the US engagement in a number of foreign wars, and the global economic crisis. Additional findings suggest that US college students have turned dramatically more negative in their view of the political trajectory of the United States, due to a feeling of higher connectivity between one another and a lack of faith in traditional politics. When focusing on US college student views on US foreign policy, students were dissatisfied and skeptical. We are assessing these findings in the context of a small, liberal arts, faith based institution. Thus, we consider the views of Hope College students on the issue of the immigration of Syrian refugees to the United States

Ground-Based Measurement Experiment and First Results with Geosynchronous-Imaging Fourier Transform Spectrometer Engineering Demonstration Unit

The geosynchronous-imaging Fourier transform spectrometer (GIFTS) engineering demonstration unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. It measures the infrared spectrum in two spectral bands (14.6 to 8.8 microns, 6.0 to 4.4 microns) using two 128 x 128 detector arrays with a spectral resolution of 0.57 cm(exp -1) with a scan duration of approximately 11 seconds. From a geosynchronous orbit, the instrument will have the capability of taking successive measurements of such data to scan desired regions of the globe, from which atmospheric status, cloud parameters, wind field profiles, and other derived products can be retrieved. The GIFTS EDU provides a flexible and accurate testbed for the new challenges of the emerging hyperspectral era. The EDU ground-based measurement experiment, held in Logan, Utah during September 2006, demonstrated its extensive capabilities and potential for geosynchronous and other applications (e.g., Earth observing environmental measurements). This paper addresses the experiment objectives and overall performance of the sensor system with a focus on the GIFTS EDU imaging capability and proof of the GIFTS measurement concept

GIFTS EDU Ground-based Measurement Experiment

Geosynchronous Imaging Fourier Transform Spectrometer (GIFTS) Engineering Demonstration Unit (EDU) is an imaging infrared spectrometer designed for atmospheric soundings. The EDU groundbased measurement experiment was held in Logan, Utah during September 2006 to demonstrate its extensive capabilities for geosynchronous and other applications

Conformational Space and Stability of ETD Charge Reduction Products of Ubiquitin

Owing to its versatility, electron transfer dissociation (ETD) has become one of the most commonly utilized fragmentation techniques in both native and non-native top-down mass spectrometry. However, several competing reactions—primarily different forms of charge reduction—occur under ETD conditions, as evidenced by the distorted isotope patterns usually observed. In this work, we analyze these isotope patterns to compare the stability of nondissociative electron transfer (ETnoD) products, specifically noncovalent c/z fragment complexes, across a range of ubiquitin conformational states. Using ion mobility, we find that more extended states are more prone to fragment release. We obtain evidence that for a given charge state, populations of ubiquitin ions formed either directly by electrospray ionization or through collapse of more extended states upon charge reduction, span a similar range of collision cross-sections. Products of gas-phase collapse are, however, less stabilized towards unfolding than the native conformation, indicating that the ions retain a memory of previous conformational states. Furthermore, this collapse of charge-reduced ions is promoted if the ions are ‘preheated’ using collisional activation, with possible implications for the kinetics of gas-phase compaction