High Spectral and Spatial Resolution Observations of the PDR Emission in the NGC2023 Reflection Nebula with SOFIA and APEX

We have mapped the NGC 2023 reflection nebula in [CII] and CO(11--10) with the heterodyne receiver GREAT on SOFIA and obtained slightly smaller maps in 13CO(3--2), CO(3--2), CO(4--3), CO(6--5), and CO(7--6) with APEX in Chile. We use these data to probe the morphology, kinematics, and physical conditions of the C II region, which is ionized by FUV radiation from the B2 star HD37903. The [CII] emission traces an ellipsoidal shell-like region at a position angle of ~ -50 deg, and is surrounded by a hot molecular shell. In the southeast, where the C II region expands into a dense, clumpy molecular cloud ridge, we see narrow and strong line emission from high-J CO lines, which comes from a thin, hot molecular shell surrounding the [CII] emission. The [CII] lines are broader and show photo evaporating gas flowing into the C II region. Based on the strength of the [13CII] F=2--1 line, the [CII] line appears to be somewhat optically thick over most of the nebula with an optical depth of a few. We model the physical conditions of the surrounding molecular cloud and the PDR emission using both RADEX and simple PDR models. The temperature of the CO emitting PDR shell is ~ 90 -- 120 K, with densities of 10^5 -- 10^6 cm^-3, as deduced from RADEX modeling. Our PDR modeling indicates that the PDR layer where [CII] emission dominates has somewhat lower densities, 10^4 to a few times 10^5 cm^-3Comment: Accepted by A&

Organic Molecules in the Galactic Center. Hot Core Chemistry without Hot Cores

We study the origin of large abundances of complex organic molecules in the Galactic center (GC). We carried out a systematic study of the complex organic molecules CH3OH, C2H5OH, (CH3)2O, HCOOCH3, HCOOH, CH3COOH, H2CO, and CS toward 40 GC molecular clouds. Using the LTE approximation, we derived the physical properties of GC molecular clouds and the abundances of the complex molecules.The CH3OH abundance between clouds varies by nearly two orders of magnitude from 2.4x10^{-8} to 1.1x10^{-6}. The abundance of the other complex organic molecules relative to that of CH3OH is basically independent of the CH3OH abundance, with variations of only a factor 4-8. The abundances of complex organic molecules in the GC are compared with those measured in hot cores and hot corinos, in which these complex molecules are also abundant. We find that both the abundance and the abundance ratios of the complex molecules relative to CH3OH in hot cores are similar to those found in the GC clouds. However, hot corinos show different abundance ratios than observed in hot cores and in GC clouds. The rather constant abundance of all the complex molecules relative to CH3OH suggests that all complex molecules are ejected from grain mantles by shocks. Frequent (similar 10^{5}years) shocks with velocities >6km/s are required to explain the high abundances in gas phase of complex organic molecules in the GC molecular clouds. The rather uniform abundance ratios in the GC clouds and in Galactic hot cores indicate a similar average composition of grain mantles in both kinds of regions. The Sickle and the Thermal Radio Arches, affected by UV radiation, show different relative abundances in the complex organic molecules due to the differentially photodissociation of these molecules.Comment: 18 pages, 10 Postscript figures, uses aa.cls, aa.bst, 10pt.rtx, natbib.sty, revsymb.sty revtex4.cls, aps.rtx and aalongtabl.sty. Accepted in A&A 2006. version 2. relocated figures and tables. Language editor suggestions. added reference

Ionized gas at the edge of the Central Molecular Zone

To determine the properties of the ionized gas at the edge of the CMZ near Sgr E we observed a small portion of the edge of the CMZ near Sgr E with spectrally resolved [C II] 158 micron and [N II] 205 micron fine structure lines at six positions with the GREAT instrument on SOFIA and in [C II] using Herschel HIFI on-the-fly strip maps. We use the [N II] spectra along with a radiative transfer model to calculate the electron density of the gas and the [C II] maps to illuminate the morphology of the ionized gas and model the column density of CO-dark H2. We detect two [C II] and [N II] velocity components, one along the line of sight to a CO molecular cloud at -207 km/s associated with Sgr E and the other at -174 km/s outside the edge of another CO cloud. From the [N II] emission we find that the average electron density is in the range of about 5 to 25 cm{-3} for these features. This electron density is much higher than that of the warm ionized medium in the disk. The column density of the CO-dark H$_2$ layer in the -207 km/s cloud is about 1-2X10{21} cm{-2} in agreement with theoretical models. The CMZ extends further out in Galactic radius by 7 to 14 pc in ionized gas than it does in molecular gas traced by CO. The edge of the CMZ likely contains dense hot ionized gas surrounding the neutral molecular material. The high fractional abundance of N+ and high electron density require an intense EUV field with a photon flux of order 1e6 to 1e7 photons cm{-2} s{-1}, and/or efficient proton charge exchange with nitrogen, at temperatures of order 1e4 K, and/or a large flux of X-rays. Sgr E is a region of massive star formation which are a potential sources of the EUV radiation that can ionize the gas. In addition X-ray sources and the diffuse X-ray emission in the CMZ are candidates for ionizing nitrogen.Comment: 12 pages, 9 figure

The thermal state of molecular clouds in the Galactic Center: evidence for non-photon-driven heating

We used the Atacama Pathfinder Experiment (APEX) 12 m telescope to observe the J_KaKc=3_03-2_02, 3_22-2_21, and 3_21-2_20 transitions of para-H_2CO at 218 GHz simultaneously to determine kinetic temperatures of the dense gas in the central molecular zone (CMZ) of our Galaxy. The map extends over approximately 40 arcmin x 8 arcmin (~100x20 pc^2) along the Galactic plane with a linear resolution of 1.2 pc. The strongest of the three lines, the H_2CO (3_03-2_02) transition, is found to be widespread, and its emission shows a spatial distribution similar to ammonia. The relative abundance of para-H_2CO is 0.5-1.2 10^{-9}, which is consistent with results from lower frequency H_2CO absorption lines. Derived gas kinetic temperatures for individual molecular clouds range from 50 K to values in excess of 100 K. While a systematic trend toward (decreasing) kinetic temperature versus (increasing) angular distance from the Galactic center (GC) is not found, the clouds with highest temperature (T_kin > 100 K) are all located near the nucleus. For the molecular gas outside the dense clouds, the average kinetic temperature is 65+/-10 K. The high temperatures of molecular clouds on large scales in the GC region may be driven by turbulent energy dissipation and/or cosmic-rays instead of photons. Such a non-photon-driven thermal state of the molecular gas provides an excellent template for the more distant vigorous starbursts found in ultraluminous infrared galaxies (ULIRGs).Comment: 23 pages, 11 figures, A&A in pres

Radiative and mechanical feedback into the molecular gas of NGC 253

Starburst galaxies are undergoing intense periods of star formation. Understanding the heating and cooling mechanisms in these galaxies can give us insight to the driving mechanisms that fuel the starburst. Molecular emission lines play a crucial role in the cooling of the excited gas. With SPIRE on the Herschel Space Observatory we have observed the rich molecular spectrum towards the central region of NGC 253. CO transitions from J=4-3 to 13-12 are observed and together with low-J line fluxes from ground based observations, these lines trace the excitation of CO. By studying the CO excitation ladder and comparing the intensities to models, we investigate whether the gas is excited by UV radiation, X-rays, cosmic rays, or turbulent heating. Comparing the $^{12}$CO and $^{13}$CO observations to large velocity gradient models and PDR models we find three main ISM phases. We estimate the density, temperature,and masses of these ISM phases. By adding $^{13}$CO, HCN, and HNC line intensities, we are able to constrain these degeneracies and determine the heating sources. The first ISM phase responsible for the low-J CO lines is excited by PDRs, but the second and third phases, responsible for the mid to high-J CO transitions, require an additional heating source. We find three possible combinations of models that can reproduce our observed molecular emission. Although we cannot determine which of these are preferable, we can conclude that mechanical heating is necessary to reproduce the observed molecular emission and cosmic ray heating is a negligible heating source. We then estimate the mass of each ISM phase; $6\times 10^7$ M$_\odot$ for phase 1 (low-J CO lines), $3\times 10^7$ M$_\odot$ for phase 2 (mid-J CO lines), and $9\times 10^6$ M$_\odot$ for phase 3 (high-J CO lines) for a total system mass of $1\times10^{8}$ M$_\odot$

The largest oxigen bearing organic molecule repository

We present the first detection of complex aldehydes and isomers in three typical molecular clouds located within 200pc of the center of our Galaxy. We find very large abundances of these complex organic molecules (COMs) in the central molecular zone (CMZ), which we attribute to the ejection of COMs from grain mantles by shocks. The relative abundances of the different COMs with respect to that of CH3OH are strikingly similar for the three sources, located in very different environments in the CMZ. The similar relative abundances point toward a unique grain mantle composition in the CMZ. Studying the Galactic center clouds and objects in the Galactic disk having large abundances of COMs, we find that more saturated molecules are more abundant than the non-saturated ones. We also find differences between the relative abundance between COMs in the CMZ and the Galactic disk, suggesting different chemical histories of the grain mantles between the two regions in the Galaxy for the complex aldehydes. Different possibilities for the grain chemistry on the icy mantles in the GC clouds are briefly discussed. Cosmic rays can play an important role in the grain chemistry. With these new detections, the molecular clouds in the Galactic center appear to be one of the best laboratories for studying the formation of COMs in the Galaxy.Comment: 20 pages, 4 figures, accepted in Ap

Disentangling the excitation conditions of the dense gas in M17 SW

We probe the chemical and energetic conditions in dense gas created by radiative feedback through observations of multiple CO, HCN and HCO$^+$ transitions toward the dense core of M17 SW. We used the dual band receiver GREAT on board the SOFIA airborne telescope to obtain maps of the $J=16-15$, $J=12-11$, and $J=11-10$ transitions of $^{12}$CO. We compare these maps with corresponding APEX and IRAM 30m telescope data for low- and mid-$J$ CO, HCN and HCO$^+$ emission lines, including maps of the HCN $J=8-7$ and HCO$^+$ $J=9-8$ transitions. The excitation conditions of $^{12}$CO, HCO$^+$ and HCN are estimated with a two-phase non-LTE radiative transfer model of the line spectral energy distributions (LSEDs) at four selected positions. The energy balance at these positions is also studied. We obtained extensive LSEDs for the CO, HCN and HCO$^+$ molecules toward M17 SW. The LSED shape, particularly the high-$J$ tail of the CO lines observed with SOFIA/GREAT, is distinctive for the underlying excitation conditions. The critical magnetic field criterion implies that the cold cloudlets at two positions are partially controlled by processes that create and dissipate internal motions. Supersonic but sub-Alfv\'enic velocities in the cold component at most selected positions indicates that internal motions are likely MHD waves. Magnetic pressure dominates thermal pressure in both gas components at all selected positions, assuming random orientation of the magnetic field. The magnetic pressure of a constant magnetic field throughout all the gas phases can support the total internal pressure of the cold components, but it cannot support the internal pressure of the warm components. If the magnetic field scales as $B \propto n^{2/3}$, then the evolution of the cold cloudlets at two selected positions, and the warm cloudlets at all selected positions, will be determined by ambipolar diffusion.Comment: 26 pages, 13 figures, A&A accepte

Abundant Z-cyanomethanimine in the interstellar medium: paving the way to the synthesis of adenine

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of E-cyanomethanimine, using IRAM 30m observations towards the Galactic Center quiescent molecular cloud G+0.693. The Z-isomer has a column density of (2.0$\pm$0.6)$\times$10$^{14}$ cm$^{-2}$ and an abundance of 1.5$\times$10$^{-9}$. The relative abundance ratio between the isomers is [Z/E]$\sim$6. This value cannot be explained by the two chemical formation routes previously proposed (gas-phase and grain surface), which predicts abundances ratios between 0.9 and 1.5. The observed [Z/E] ratio is in good agreement with thermodynamic equilibrium at the gas kinetic temperature (130$-$210 K). Since isomerization is not possible in the ISM, the two species may be formed at high temperature. New chemical models, including surface chemistry on dust grains and gas-phase reactions, should be explored to explain our findings. Whatever the formation mechanism, the high abundance of Z-HNCHCN shows that precursors of adenine are efficiently formed in the ISM.Comment: Accepted in Monthly Notices of the Royal Astronomical Society Letter

Complex organic molecules in the Galactic Centre: the N-bearing family

We present an unbiased spectral line survey toward the Galactic Centre (GC) quiescent giant molecular cloud (QGMC), G+0.693 using the GBT and IRAM 30$\,$ telescopes. Our study highlights an extremely rich organic inventory of abundant amounts of nitrogen (N)-bearing species in a source without signatures of star formation. We report the detection of 17 N-bearing species in this source, of which 8 are complex organic molecules (COMs). A comparison of the derived abundances relative to H$_2$ is made across various galactic and extragalactic environments. We conclude that the unique chemistry in this source is likely to be dominated by low-velocity shocks with X-rays/cosmic rays also playing an important role in the chemistry. Like previous findings obtained for O-bearing molecules, our results for N-bearing species suggest a more efficient hydrogenation of these species on dust grains in G+0.693 than in hot cores in the Galactic disk, as a consequence of the low dust temperatures coupled with energetic processing by X-ray/cosmic ray radiation in the GC.Comment: 24 pages, 23 figures, 7 tables, accepted for publication in MNRA

Chemical Features in the Circumnuclear Disk of the Galactic Center

The circumnuclear disk (CND) of the Galactic Center is exposed to many energetic phenomena coming from the supermassive black hole Sgr A* and stellar activities. These energetic activities can affect the chemical composition in the CND by the interaction with UV-photons, cosmic-rays, X-rays, and shock waves. We aim to constrain the physical conditions present in the CND by chemical modeling of observed molecular species detected towards it. We analyzed a selected set of molecular line data taken toward a position in the southwest lobe of the CND with the IRAM 30m and APEX 12-meter telescopes and derived the column density of each molecule using a large velocity gradient (LVG) analysis. The determined chemical composition is compared with a time-dependent gas-grain chemical model based on the UCL\_CHEM code that includes the effects of shock waves with varying physical parameters. Molecules such as CO, HCN, HCO$^+$, HNC, CS, SO, SiO, NO, CN, H$_2$CO, HC$_3$N, N$_2$H$^+$ and H$_3$O$^+$ are detected and their column densities are obtained. Total hydrogen densities obtained from LVG analysis range between $2 \times 10^4$ and $1 \times 10^6\,$cm$^{-3}$ and most species indicate values around several $\times 10^5\,$cm$^{-3}$, which are lower than values corresponding to the Roche limit, which shows that the CND is tidally unstable. The chemical models show good agreement with the observations in cases where the density is $\sim10^4\,$cm$^{-3}$, the cosmic-ray ionization rate is high, $>10^{-15} \,$s$^{-1}$, or shocks with velocities $> 40\,$km s$^{-1}$ have occurred. Comparison of models and observations favors a scenario where the cosmic-ray ionization rate in the CND is high, but precise effects of other factors such as shocks, density structures, UV-photons and X-rays from the Sgr A* must be examined with higher spatial resolution data.Comment: 17 Pages, 13 figures, accepted for publication in A&