Deep and Shallow-Water Mollusks from the Central Pacific

Recent shelled mollusks were trawled from deep water on four guyots in the Mid-Pacific Mountains and were dredged from shallow waters on Nero Bank and the lee shelf of Kure Island in Hawaii. Seven species of mollusks, six of which are new, have been identified from the deep waters on the guyots : two are trochids, Calliotropis hataii n. sp., and C. abyssicola n. sp., three are turrids, Comitas powelli n. sp., Pleurotomella dubia Schepman and P. allisoni n. sp., one is a bullid, Bulla argoblysis n. sp., and one a scaphopod, Dentalium mediopacificensis n. sp. Five of the seven species are identical or closely related to Indo-Pacific forms, one belongs to a small but cosmopolitan group, one is related to a species living near the Galapagos Islands in the eastern Pacific. Nine species of mollusks are identified from Nero Bank and 41 from Kure\u27s shelf, one being new. A total of 101 species are listed as occurring on these two sites and the Kure beaches and lagoon. More than one-third of the total listed appear to be endemic to Hawaii

Possibilities and pitfalls in quantifying the extent of cysteine sulfenic acid modification of specific proteins within complex biofluids

<p>Abstract</p> <p>Background</p> <p>Cysteine sulfenic acid (Cys-SOH) plays important roles in the redox regulation of numerous proteins. As a relatively unstable posttranslational protein modification it is difficult to quantify the degree to which any particular protein is modified by Cys-SOH within a complex biological environment. The goal of these studies was to move a step beyond detection and into the relative quantification of Cys-SOH within specific proteins found in a complex biological setting--namely, human plasma.</p> <p>Results</p> <p>This report describes the possibilities and limitations of performing such analyses based on the use of thionitrobenzoic acid and dimedone-based probes which are commonly employed to trap Cys-SOH. Results obtained by electrospray ionization-based mass spectrometric immunoassay reveal the optimal type of probe for such analyses as well as the reproducible relative quantification of Cys-SOH within albumin and transthyretin extracted from human plasma--the latter as a protein previously unknown to be modified by Cys-SOH.</p> <p>Conclusions</p> <p>The relative quantification of Cys-SOH within specific proteins in a complex biological setting can be accomplished, but several analytical precautions related to trapping, detecting, and quantifying Cys-SOH must be taken into account prior to pursuing its study in such matrices.</p

Induced magnetism of carbon atoms at the graphene/Ni(111) interface

We report an element-specific investigation of electronic and magnetic properties of the graphene/Ni(111) system. Using magnetic circular dichroism, the occurrence of an induced magnetic moment of the carbon atoms in the graphene layer aligned parallel to the Ni 3d magnetization is observed. We attribute this magnetic moment to the strong hybridization between C $\pi$ and Ni 3d valence band states. The net magnetic moment of carbon in the graphene layer is estimated to be in the range of $0.05-0.1 \mu_B$ per atom.Comment: 10 pages, 3 figure

One year of continuous measurements constraining methane emissions from the Baltic Sea to the atmosphere using a ship of opportunity

Methane and carbon dioxide were measured with an autonomous and continuous running system on a ferry line crossing the Baltic Sea on a 2–3 day interval from the Mecklenburg Bight to the Gulf of Finland in 2010. Surface methane saturations show great seasonal differences in shallow regions like the Mecklenburg Bight (103–507 %) compared to deeper regions like the Gotland Basin (96–161 %). The influence of controlling parameters like temperature, wind, mixing depth and processes like upwelling, mixing of the water column and sedimentary methane emissions on methane oversaturation and emission to the atmosphere are investigated. Upwelling was found to influence methane surface concentrations in the area of Gotland significantly during the summer period. In February 2010, an event of elevated methane concentrations in the surface water and water column of the Arkona Basin was observed, which could be linked to a wind-derived water level change as a potential triggering mechanism. The Baltic Sea is a source of methane to the atmosphere throughout the year, with highest fluxes occurring during the winter season. Stratification was found to promote the formation of a methane reservoir in deeper regions like Gulf of Finland or Bornholm Basin, which leads to long lasting elevated methane concentrations and enhanced methane fluxes, when mixed to the surface during mixed layer deepening in autumn and winter. Methane concentrations and fluxes from shallow regions like the Mecklenburg Bight are predominantly controlled by sedimentary production and consumption of methane, wind events and the change in temperature-dependent solubility of methane in the surface water. Methane fluxes vary significantly in shallow regions (e.g. Mecklenburg Bight) and regions with a temporal stratification (e.g. Bornholm Basin, Gulf of Finland). On the contrary, areas with a permanent stratification like the Gotland Basin show only small seasonal fluctuations in methane fluxes

Effects of the 2014 major Baltic inflow on methane and nitrous oxide dynamics in the water column of the Central Baltic Sea

Peer reviewe

Characterization of Atmospheric Turbulence Effects Over 149 km Propagation Path Using Multi-Wavelength Laser Beacons

We describe preliminary results of a set of laser beam propagation experiments performed over a long (149 km) near-horizontal propagation path between Mauna Loa (Hawaii Island) and Haleakala (Island of Maui) mountains in February 2010. The distinctive feature of the experimental campaign referred to here as the Coherent Multi-Beam Atmospheric Transceiver (COMBAT) experiments is that the measurements of the atmospheric-turbulence induced laser beam intensity scintillations at the receiver telescope aperture were obtained simultaneously using three laser sources (laser beacons) with different wavelengths (λ1 = 0.53 μm, λ2 = 1.06 μm, and λ3 = 1.55 μm). The presented experimental results on intensity scintillation characteristics reveal complexity of the observed phenomena that cannot be fully explained based on the existing atmospheric turbulence models